共查询到20条相似文献,搜索用时 250 毫秒
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SnO2:Zr薄膜对SO2气体的光学气敏特性研究 总被引:1,自引:1,他引:0
采用双靶反应溅射制得SnO2:Zr薄膜,并对它作了150°C下SO2气敏光学特性试验,首次发现在适当工艺条件下制得的SnO2:Zr薄膜在近红外波段(1.7~3μm)对SO2气体具有明显的光学气敏特性,在2.65μm附近透过率上升幅度达10%左右.Zr的引入增强了SnO2薄膜对SO2的吸附能力.用二次离子质谱对吸附SO2前后的薄膜作了组分相对含量分析.本实验结果对今后研究高性能SO2气敏传感器有一定的价值. 相似文献
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色散SiO2/TiO2薄膜组成的Fibonacci序列一维光子晶体在可见光波段的传输特性 总被引:1,自引:0,他引:1
用特征矩阵法研究了由正常色散SiO2/TiO2薄膜组成的Fibonacci序列一维光子晶体在可见光波段的传输特性,并与无色散时的传输特性做了对比。结果表明,随序列项数的增加,相应的前一序列的透射谱中透射率较低的凹带逐渐变成禁带,禁带数增加;初始介质是低折射率的SiO2薄膜时比高折射率的TiO2薄膜时各序列的透射谱中的禁带数多,各禁带的宽度和中心波长基本相同;在总厚度一定的条件下,随SiO2薄膜的厚度增大(TiO2薄膜的厚度减小),禁带的宽度减小,禁带的中心波长基本不变;随入射角增大,禁带的中心波长向短波方向移动,禁带宽度变小。在其它相同条件下,无色散时的最宽禁带和最宽禁带的中心波长比有色散时的最宽禁带和最宽禁带的中心波长都有增加。 相似文献
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研究基片温度(120~300 ℃)和热处理温度(400℃)对电子束蒸发TiO2薄膜的结构和光学性能的影响.XRD分析表明,在120 ℃, 200 ℃和300 ℃的普通玻璃基片上采用电子枪加热蒸发制备的TiO2薄膜具有非晶态结构,沉积态薄膜经过400 ℃保温1 h的热处理后得到的相为具有(004)取向的锐钛矿相,晶粒大小在3.6~8.1 nm之间.透射谱分析表明,薄膜的折射率随着基片温度的升高而增加;热处理后,薄膜的折射率也相应提高,其原因来自于薄膜的晶化. 相似文献
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Er3+/Yb3+共掺TeO2-Li2O-B2O3-GeO2玻璃系统的光谱性质和热稳定性研究 总被引:6,自引:6,他引:0
制备了Er3+/Yb3+共掺的70TeO2-5Li2O-(25-x)B2O3-xGeO2(x=0,5,10,15,20 mol%)系列玻璃, 研究了玻璃的热稳定性能, 测试了玻璃的吸收光谱、荧光光谱以及Er3+离子4I13/2能级荧光寿命, 并根据McCumber理论计算了Er3+离子4I13/2→4I15/2跃迁的受激发射截面. 结果表明:随着GeO2含量的增加, 玻璃的热稳定性逐渐提高, 荧光谱线半高宽(FWHM)保持在70 nm左右, 而荧光强度和Er3+离子4I13/2能级荧光寿命逐渐提高, 研究表明这种玻璃系统是一种具有应用潜能的宽带光纤放大器用的基质材料. 相似文献
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Sol-gel法制备Er3+-Yb3+共掺杂Al2O3粉末光致发光特性 总被引:8,自引:7,他引:1
采用异丙醇铝[Al(OC3H7)3]为前驱体,溶胶-凝胶(Sol-gel)法制备Er3+-Yb3+共掺杂Al2O3粉末.实验结果表明:900 ℃烧结的粉末为固溶Er3+、Yb3+的γ-(Al,Er,Yb)2O3相和少量θ-(Al,Er,Yb)2O3相的混合物.Er3+-Yb3+共掺杂Al2O3粉末具有中心波长为1.533 μm的光致发光(PL)特性.1 mol % Er3+和1 mol% Yb3+共掺杂的Al2O3粉末的PL强度较1 mol % Er3+掺杂提高2倍,半峰宽从53 nm增加到63 nm.随泵浦功率的提高,PL强度呈线性增加后渐呈饱和趋势. 相似文献
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温度对PSⅡCP4 7/D1/D2/Cytb559复合物荧光光谱特性的影响 总被引:3,自引:3,他引:0
采用激励光源为514.5 nm的分幅扫描单光子计数荧光光谱装置对经20℃、42℃和48℃不同温度处理后的反应中心复合物CP47/D1/D2/Cyt b559的荧光光谱特性进行了研究.经解析,获得不同温度处理后,CP47/D1/D2/Cyt b559复合物最大峰值未发生变化,均在682 nm,说明Chla670的能量都由Chla682接收,但损耗愈来愈小,在48℃时,损耗程度最小,而其荧光百分比未发生多大变化.振动副带~700 nm和~740 nm的中心波长都发生蓝移,在不同温度下分别为:20℃ 703 nm,749 nm;42℃ 697 nm,744 nm;48℃ 694 nm,740 nm.因此可以推测温度的升高,影响了CP47/D1/D2/Cyt b559色素蛋白的二级结构以及色素分子的空间位置,使最大峰值处的荧光强度逐渐降低,振动副带逐渐蓝移.42℃的温度已造成影响,48℃影响较大. 相似文献
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利用电子束热蒸发镀膜的方式,以高纯度的ZnO和TiO2颗粒为原料,以Si为基底在有氧的气氛中制备ZnO/TiO2复合薄膜。研究制备温度对ZnO/TiO2薄膜的结构以及发光性能的影响。通过拉曼(Raman)谱和X射线衍射(XRD)谱分析了ZnO/TiO2薄膜的结构,表明所制备的ZnO薄膜为非晶态。用光致发光 (PL) 谱表征了它的发光特性,数据表明在250℃时制备的非晶态ZnO薄膜在波长389nm处具有极强的紫外光发射,在波长431nm处发出很强的紫光,在波长519nm处发出较强的黄绿光。 相似文献
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Working Pressure Dependence of Properties of Al2O3 Thin Films Prepared by Electron Beam Evaporation 下载免费PDF全文
The effects of working pressure on properties of Al2O3 thin films are investigated. Transmittance of the Al2O3 thin film is measured by a Lambda 900 spectrometer. Laser-induced damage threshold (LIDT) is measured by a Nd:YAG laser at 355 nm with a pulse width of 7ns. Microdefects were observed under a Nomarski microscope. The samples are characterized by optical properties and defect, as well as LIDT under the 355 nm Nd:YAG laser radiation. It is found that the working pressure has fundamental effect on the LIDT. It is the absorption rather than the microdefect that plays an important role on the LIDT of Al2O3 thin film. 相似文献
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Javed Ahmad Hidetoshi Minami Sher Alam Jianding Yu Yasutomo Arai Hiromoto Uwe 《中国物理快报》2008,25(12):4421-4424
Optical transmittance and reflectance on ferroelectric BaTi2O5 glasses prepared recently by a containerless synthesis technique are measured at room temperature in the wavelength range 190-800nm. The fundamental absorption edge located around 340nm demonstrates the colourless and transparent character of the glass. The optical band gap of 3.32eV has been estimated. The tail of the optical absorption near the fundamental absorption edge is found to follow the Urbach rule. Our analysis of the experimental spectra supports an indirect allowed interband transition between the valence band formed by O-2p orbitals and the conduction band formed by Ti-3d orbitals. 相似文献
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We report on the ultrafast third-order optical nonlinearity in multilayer Au/TiO2 composite films fabricated on quartz substrates by pulsed laser deposition technique. The linear optical properties of the films are determined and optical absorption peaks due to surface plasmon resonance of Au particles are observed at about 590hm. The third-order optical nonlinearities of the films are investigated by z-scan method using a femtosecond laser (50 fs) at the wavelength of 800 nm. The sample showed fast nonlinear optical responses with nonlinear absorption coefficient and nonlinear refractive index being -3.66 × 10^-10 m/W and -2.95 × 10^-17 m^2/W, respectively. The results also show that the nonlinear optical effects increase with the increasing Au concentration in the composite films. 相似文献
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The optical properties of monolayer Ge2Sb2Te5 thin films with three different thicknesses prepared by dc magnetron sputtering method at the range of 400 - 800 nm were studied. The optical absorption coefficients and the optical energy gap (Eg) were calculated. The results gave values for the absorption coefficients in the range of (1.3 - 7.5) × 105 cm-1 which were in the high absorption wavelength region of 400 - 800 nm. The optical energy gaps were 0.684, 0.753 and 0.810 eV corresponding the films thicknesses of 57, 88 and 127 nm, respectively, showing the characteristic of increasing with the increase of the film thickness. 相似文献
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酞菁铜薄膜的光记录特性 总被引:11,自引:3,他引:8
研究了有机染料酞菁铜(CuPc)真空蒸镀薄膜在可见及近红外区域的吸收光谱和光学常数,发现酞菁铜薄膜在550-750nm波长范围内具有较强的吸收,在静态测试仪上测试了酞菁铜薄膜的光存储记录特性,发现用低功率氦氖激光照样品时薄膜反射率变化较大,在酞菁记录层上覆盖金属反射层将提高写入激光的阈值能量并且增大反射率的对比度。 相似文献
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Ultrafast third-order optical nonlinearities of the as-deposited and annealed Au:Bi2O3 nanocomposite films deposited by magnetron cosputtering are investigated by using femtosecond time-resolved optical Kerr effect (OKE) and pump probe techniques. The third-order optical nonlinear susceptibility is estimated to be 2.6Ф×10^- 10 esu and 1.8 × 10.9 esu at wavelength of 800nm, for the as-deposited and the annealed film, respectively. The OKE signal of the as-deposited film is nearly temporally symmetrical with a peak centred at zero delay time, which indicates the dominant contribution from intraband transition of conduction electrons. For the annealed film, the existence of a decay process in OKE signal implies the important contribution of hot electrons. These characteristics are in agreement with the hot electron dynamics observed in pump probe measurement. 相似文献