Realization of Ultraviolet Electroluminescence from ZnO Homojunction Fabricated on Silicon Substrate with p-Type ZnO:N Layer Formed by Radical N2O Doping

ZnO homojunction light-emitting diodes are fabricated on Si（100） substrates by plasma assisted metal organic chemical vapour deposition. A p-type layer of nitrogen-doped ZnO film is formed using radical N2O as the acceptor precursor. The n-type ZnO layer is composed of un-doped ZnO film. The device exhibits desirable rectifying behaviour with a turn-on voltage of 3.3 V and a reverse breakdown voltage higher than 6 V. Distinct electrolumineseence emissions centred at 395nm and 490nm are detected from this device at forward current higher than 20mA at room temperature.     

基于CdSe@ZnS量子点水溶性纳米粒子的制备及荧光性能

作为一种新型的荧光探针,量子点（QD）已经受到越来越多的重视,制备工艺也显得格外重要。水相中合成的量子点效率低,油相中的量子点经过转相以后效率也大大衰减。本论文利用再沉淀包覆的方法制备了具有良好的水溶性的掺杂绿光CdSe@ZnS的纳米颗粒G-NPs（534 nm）和掺杂红光CdSe@ZnS的纳米颗粒R-NPs（610 nm）,具有窄的半峰宽（G-NPs~29 nm,R-NPs~31 nm）,较小的粒径（45 nm）,并在此基础上通过发射光谱与荧光衰减研究了量子点之间的能量传递现象。该方法保留了量子点原来的性质,基于其优良的光学性质,对人类肝细胞肝癌细胞株（HepG2）进行了荧光标记,从共聚焦成像实验结果看出,纳米颗粒得到了良好的吞噬效果。     

聚甲基丙烯酸甲酯/苯乙烯-丙烯腈无规共聚物薄膜表面原位原子力显微镜相图

采用原位原子力显微镜在线跟踪方法,研究了聚甲基丙烯酸甲酯/苯乙烯 丙烯腈无规共聚物共混体系表面相分离行为,得到了具有下临界共溶温度（临界温度约为175 ℃）原位相图。 与文献报道的用离位方法所得结果的主要差别是原位的临界相分离温度稍有提高,以及离位结果中存在的组成对称性。 这些差别主要来源于离位和原位实验方法上的差别,薄膜厚度减小导致的相容性,热力学历史的变化以及基底效应的加剧。     

超高温、大热流、非线性气动热环境试验模拟及测试技术研究

超高温、大热流、非线性气动热环境试验模拟技术及相应的极端高温环境力学测试技术,是高超声速飞行器防热材料和结构安全设计中事关研制成败的关键技术。本文介绍了自行研制的可实现高至210℃/s的极快非线性升温速率、能够生成高达2MW/m2的瞬态非线性热流密度、实现高达1500℃超高温氧化热环境的石英灯红外辐射式气动热环境试验模拟系统。基于这一性能优越的超高温气动热环境试验模拟系统,发展了如下超高温热环境力学测试技术:1)提出对环境光变化不敏感的主动成像数字图像相关方法,实现了C/SiC复合材料1550℃高温变形的非接触、全场光学测量;2)发展了1400℃超高温热/力联合试验环境下SiC/SiC复合材料结构的断裂特性试验测试技术。本文还简要介绍了高速巡航导弹翼面结构900℃高温热振联合试验,950℃高温非线性热环境下的蜂窝结构隔热性试验等研究内容。本文所发展的超高温气动热环境试验模拟技术和高温热环境力学测试技术,对航天航空领域高超声速飞行器的研制具有重要的军事工程应用价值。     

外围缩合四个1,10-啡啰啉单元的新氮杂酞菁的表面光伏响应及电场作用研究

通过电场诱导表面光电压谱确定外围缩合4个1,10-啡啉单元的氮杂酞菁为p型有机半导体,并对各个谱带进行合理的归属.结果发现,Soret带长波侧光电压曲线在电场作用下轻微蓝移,根据电场对高极化度n轨道基态的影响,将其归属为n-π^*     

对硝基甲苯在多硫化钠溶液中氧化还原机理的质谱研究

采用高分辨质谱仪跟踪监测对硝基甲苯在多硫化钠存在下于乙醇-碱性水溶液中生成对氨基苯甲醛过程中反应中间体的变化及转变规律.结果显示,在80℃时反应进行到120min之内,有数种分子量较大的缩合中间体生成,表明对氨基苯甲醛可能是经类席夫碱的多聚体水解生成的.同时,对席夫碱多聚体的形成提出了与文献不同的机理.     

光谱线型的遗传学算法模拟

采用遗传算法模拟了D_α 的光谱轮廓, 模拟曲线与实验中观察到的轮廓符合得非常好。分析模拟的结果表明, 在HL- 1M 装置边缘等离子体中, 存在一种H 粒子群和三种D 粒子群, 它们有各自的温度和粒子数比例。     

The aerosol penetration through an electret fibrous filter

The aim of this paper is to present a theoretical study of the aerosol penetration through an electret fibrous filter, using a numerical approach. The aerosol sizes considered in this study were in the submicron range, and in the numerical model, the conventional mechanical mechanisms (impaction, interception, diffusion and gravitationally settling) were taken into consideration along with the electrostatic mechanisms, including the Coulombic and dielectrophoretic effects. The aerosol penetration through an electret fibrous filter is heavily dependent on the aerosol penetration of a single fibre. The aerosol penetration through a single electret fibre under various filtration conditions was calculated. The effects of aerosol diameter, aerosol and fibre charge state, face velocity, packing density and aerosol dielectric constant on the aerosol penetration were investigated.     

X-ray observations of tungsten wire array Z-pinch implosions on QiangGuang-1 facility

Z-pinch experiments with two arrays consisting, respectively, of 32 4-μm- and 6-μm-diameter tungsten wires have been carried out on QiangGuang-1 facility with a current rising up to 1.5MA in 80ns. At early time of implosion, x-ray framing images show that the initial emission comes from the central part of arrays, and double clear emission rings, drifting to the anode and the cathode at 5×10⁶cm/s and 2.4×10⁷cm/s respectively, are often produced near the electrodes. Later, in a 4-μm-diameter tungsten wire array, filamentation caused by ohmic heating is prominent, and more than ten filaments have been observed. A radial inward shift of arrays starts at about 30\,ns earlier than the occurrence of the x-ray peak power for both kinds of arrays, and the shrinkage rate of emission region is as high as 1.7×10⁷cm/s in a 4-μm-diameter tungsten wire array, which is two times higher than that in a 6-μm one. Emission from precursor plasmas is observed in implosion of 6-μm-diameter tungsten wire arrays, but not in implosion of a 4-μm-diameter tungsten wire array. Whereas, in a 4-μm-diameter tungsten wire array, the soft x-ray emission shows the growth of m=1 instability in the plasma column, which is caused by current. The reasons for the discrepancy between implosions of 4-μm- and 6-μm-diameter tungsten wire arrays are explained.     

钙镁硅酸盐溶度积常数的测定

借助高频等离子体发射光谱分别测定了一定温度下钙镁硅酸盐(CaO.mSiO2、MgO.mSiO2,其中m为模数)饱和溶液中Ca2 、Mg2 的平衡浓度,从而计算该温度下钙镁硅酸盐的溶度积常数,并研究了温度及水玻璃模数对钙镁硅酸盐溶度积常数的影响。结果表明,在同一温度下钙硅酸盐溶度积常数比镁硅酸盐溶度积常数小,在30℃下,水玻璃模数m为3.29时,钙硅酸盐的溶度积常数为1.14×10-8,而镁硅酸盐的溶度积常数为2.29×10-5;随着温度升高钙镁硅酸盐溶度积常数减小,当温度升高至90℃时,钙硅酸盐的溶度积常数减小至0.92×10-8,而镁硅酸盐的溶度积常数减小至1.68×10-5;在同一温度下随着水玻璃模数的增加,与其对应钙镁硅酸盐溶度积常数减小,由于模数的增加使沉淀中硅酸根离子直径变大,与钙镁离子反应生成钙镁硅酸盐晶体更易于沉淀,且更不易溶解,从而使钙镁硅酸盐的溶度积常数减小。