全文获取类型
收费全文 | 3674篇 |
免费 | 1191篇 |
国内免费 | 429篇 |
专业分类
化学 | 2623篇 |
晶体学 | 268篇 |
力学 | 84篇 |
综合类 | 43篇 |
数学 | 7篇 |
物理学 | 2269篇 |
出版年
2024年 | 8篇 |
2023年 | 30篇 |
2022年 | 70篇 |
2021年 | 102篇 |
2020年 | 139篇 |
2019年 | 121篇 |
2018年 | 109篇 |
2017年 | 163篇 |
2016年 | 258篇 |
2015年 | 218篇 |
2014年 | 287篇 |
2013年 | 428篇 |
2012年 | 336篇 |
2011年 | 339篇 |
2010年 | 252篇 |
2009年 | 237篇 |
2008年 | 219篇 |
2007年 | 263篇 |
2006年 | 233篇 |
2005年 | 199篇 |
2004年 | 175篇 |
2003年 | 172篇 |
2002年 | 180篇 |
2001年 | 82篇 |
2000年 | 80篇 |
1999年 | 73篇 |
1998年 | 98篇 |
1997年 | 93篇 |
1996年 | 69篇 |
1995年 | 74篇 |
1994年 | 42篇 |
1993年 | 31篇 |
1992年 | 17篇 |
1991年 | 14篇 |
1990年 | 20篇 |
1989年 | 11篇 |
1988年 | 14篇 |
1987年 | 5篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
排序方式: 共有5294条查询结果,搜索用时 15 毫秒
1.
2.
Comparative study on transport properties of N-, P-, and As-doped SiC nanowires: Calculated based on first principles
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
According to the one-dimensional quantum state distribution, carrier scattering, and fixed range hopping model, the structural stability and electron transport properties of N-, P-, and As-doped SiC nanowires(N-SiCNWs, P-SiCNWs, and As-SiCNWs) are simulated by using the first principles calculations. The results show that the lattice structure of NSiCNWs is the most stable in the lattice structures of the above three kinds of doped SiCNWs. At room temperature,for unpassivated SiCNWs, the doping effect of P and As are better than that of N. After passivation, the conductivities of all doped SiCNWs increase by approximately two orders of magnitude. The N-SiCNW has the lowest conductivity. In addition, the N-, P-, As-doped SiCNWs before and after passivation have the same conductivity–temperature characteristics,that is, above room temperature, the conductivity values of the doped SiCNWs all increase with temperature increasing.These results contribute to the electronic application of nanodevices. 相似文献
3.
We present the design and study of waveguide structures based on porous silicon where the light confinement is not due to the usual total reflection effect but to the use of photonic crystals (PCs) as confining walls. These PC are omnidirectional mirrors (OMs), consisting of the periodic repetition of two porous silicon layers with different refractive indices and thicknesses. They reflect the radiation for all angles of incidence within a frequency range called the omnidirectional band gap (OBG). We have followed the PC formalism to investigate the properties of the OM as a multimode waveguide: the number of modes within the band gap, their field spatial distribution and their confinement as a function of the frequency and the core thickness. 相似文献
4.
采用甚高频等离子体增强化学气相沉积技术制备了系列微晶硅薄膜太阳电池,指出了气体总流量和背反射电极的类型对电池性能参数的影响.电池的I-V测试结果表明:随反应气体总流量的增加,对应电池的短路电流密度、开路电压和填充因子都有很大程度的提高,结果使得电池的光电转换效率得以提高.另外,ZnO/Ag/Al背反射电极能明显提高电池的短路电流密度,进而也提高了电池的光电转换效率.对气体总流量和背反射电极类型影响电池效率的原因进行了分析.
关键词:
微晶硅薄膜太阳电池
气体流量
ZnO/Ag/Al背反射电极 相似文献
5.
6.
7.
Chemical bonding in isolated molecules and crystals of zwitterionic pentacoordinate silicon chelates
The electronic structures of a number of zwitterionic pentacoordinate silicon chelates were investigated using the results of X-ray diffraction studies and quantum-chemical calculatoins by the MPW1PW91/6-311G(d) method. The topological analysis of the electron density distribution function and the study in the framework of the natural bond orbital partitioning scheme showed that the character of chemical bonding in the axial fragments of the molecules under consideration changes from dative to three-center, four-electron as the silicon atom assumes a trigonal-bipyramidal coordination. 相似文献
8.
《Journal of Chemical Sciences》2005,117(5):525-531
The silicon atom may increase its coordination number to values greater than four, to form pentacoordinated compounds. It
has been observed experimentally that, in general, pentacoordinated compounds show greater reactivity than tetracoordinated
compounds. In this work, density functional theory is used to calculate the global softness and the condensed softness of
the silicon atom for SiH
n
F4−n
and SiH
n
F
5−n
1−
. The values obtained show that the global and condensed softness are greater in the pentacoordinated compounds than in the
tetracoordinated compounds, a result that explains the enhanced reactivity. If the results are analysed through a local version
of the hard and soft acids and bases principle, it is possible to suggest that in nucleophilic substitution reactions, soft
nucleophiles preferably react with SiH
n
F
5−n
1−
, and hard nucleophiles with SiH
n
F4−n
. 相似文献
9.
10.
对经过阴极还原处理后的多孔硅样片进行了光致发光测试和稳定性测试.实验结果表明这种处理能明显改善多孔硅的发光稳定性,使其表面结构更加稳定.利用原子力显微镜对不同还原时间的多孔硅微结构及形貌进行了比较,在一定范围内随着还原时间的增长多孔硅表面粗糙度增大,PL谱增强. 相似文献