GeSbTe与AglnSbTe体系相变光盘的研究进展

自Ovshinsky把相变材料用于光存储以来，一大批具有可逆光存储性能的材料不断出现，其中研究较多的是GeSbTe和AgInSbTe两种体系．文章着重介绍了利用这两种材料制成的相变光盘记录介质的微观结构特点，阐述了其晶化机理；同时，较详细地概述了光盘的堆栈结构及掺杂其他元素对相变光盘性能的影响，并对比说明了GeSbTe和AgInSbTe两种体系在蓝光记录方面的各自特点．     

Numerical Analysis and Comparison of Three Metal-Oxide-Type Super-Resolution Near Field Structures

Based on the Fresnel-Kirchhoff diffraction theory, we build up a Gaussian diffraction model of metal-oxide-type super-resolution near field structure （super-liENS）, which can describe far field optical properties. The spectral contrast induced by refractive index and the structural changes in AgOg, PtOx and PdOz thin films, which are the key functional layers in super-RENS, are studied by using this model. Comparison results indicate that the spectral contrast depends intensively on the laser-induced distribution and change of the refractive index in the metal-oxide films. The readout mechanism of the metal-oxide-type super-RENS optical disc is further clarified. This Gaussian diffraction model can be used as a simple and effective method for choosing proper active materials in super-RENS.     

镱钠共掺氟化钙锶混晶近红外光谱与激光参数

研究了15％Yb,20％Na:CaF2-SrF2混晶(Yb,Na:CaF2-SrF2,CaF2:SrF2=1:1)的近红外光谱和激光参数特性.研究显示,Yb,Na:CaF2-SrF2混晶在974 nm处吸收带宽为22 nm,吸收系数为13.09 cm-1,吸收截面为0.31×10-20 cm2.Yb3+离子在CaF2-...     

Digital synthesis of programmable photonic integrated circuits

Programmable photonic waveguide meshes can be programmed into many different circuit topologies and thereby provide a variety of functions.Due to the complexity of the signal routing in a general mesh,a particular synthesis algorithm often only accounts for a specific function with a specific cell configuration.In this paper,we try to synthesize the programmable waveguide mesh to support multiple configurations with a more general digital signal processing platform.To show the feasibility of this technique,photonic waveguide meshes in different configurations(square,triangular and hexagonal meshes)are designed to realize optical signal interleaving with arbitrary duty cycles.The digital signal processing(DSP)approach offers an effective pathway for the establishment of a general design platform for the software-defined programmable photonic integrated circuits.The use of well-developed DSP techniques and algorithms establishes a link between optical and electrical signals and makes it convenient to realize the computer-aided design of optics–electronics hybrid systems.     

Prediction and experimental measurement of the electromagnetic thrust generated by a microwave thruster system

A microwave thruster system that can convert microwave power directly to thrust without a gas propellant is developed. In the system, a cylindrical tapered resonance cavity and a magnetron microwave source are used respectively as the thruster cavity and the energy source to generate the electromagnetic wave. The wave is radiated into and then reflected from the cavity to form a pure standing wave with non-uniform electromagnetic pressure distribution. Consequently, a net electromagnetic thrust exerted on the axis of the thruster cavity appears, which is demonstrated through theoretical calculation based on the electromagnetic theory. The net electromagnetic thrust is also experimentally measured in the range from 70 mN to 720 mN when the microwave output power is from 80 W to 2500 W.     

Polarization readout analysis for multilevel phase change recording by crystallization degree modulation

Four different states of Si15Sb85 and Ge2Sb2Te5 phase change memory thin films are obtained by crystallization degree modulation through laser initialization at different powers or annealing at different temperatures. The polarization characteristics of these two four-level phase change recording media are analyzed systematically. A simple and effective readout scheme is then proposed, and the readout signal is numerically simulated. The results show that a high-contrast polarization readout can be obtained in an extensive wavelength range for the four-level phase change recording media using common phase change materials. This study will help in-depth understanding of the physical mechanisms and provide technical approaches to multilevel phase change recording.     

利用价键和周期密度泛函理论研究 MoVTeNbO 复合氧化物 (M1 相) 催化剂的活性中心

 采用价键分析和周期密度泛函理论相结合的方法, 研究了具有 M1 晶相结构的 MoVTeNbO 复合氧化物催化剂中各活性中心的 d 电子性质. 通过分析各活性中心配对出现的 d 电子和氧缺位的可能分布, 得到了最可能高效完成丙烷选择氧化反应的 M-M-Te(M = Mo 或 V) 活性中心组合. 此外, 根据各活性中心对骨架稳定的贡献, 说明了稳定的 M1 相骨架主要来自 MoO₆ 八面体中赤道面上的强共价 Mo–O 键, 而 VO₆ 八面体的贡献较小. 通常被认为稳定 M1 相的 Nb 物种主要以离子键的形式存在于五边形孔道中, 因而 Nb⁵⁺作为一种模板离子, 诱导五边形孔道乃至 M1 晶相结构的生成.     

近红外波段锑基铋掺杂薄膜厚度对光学常数与光学带隙的影响

采用磁控溅射法制备了不同厚度的锑基铋掺杂薄膜,用X射线衍射(XRD)和透射电子显微镜(TEM)研究了薄膜结构随厚度的变化。利用椭圆偏振法测定了样品薄膜在近红外波段的光学常数与光学带隙,研究了膜厚对样品薄膜光学常数和光学带隙的影响。结果表明,膜厚从7 nm增加至100 nm时,其结构由非晶态转变为晶态。在950～2200 nm波段,不同厚度薄膜样品的折射率在4.6～8.9范围,消光系数在0.6～5.8范围,光学带隙在0.32～0.16 eV范围。随着膜厚的增加,薄膜的折射率和光学带隙减小,而消光系数升高;光学常数在膜厚50 nm时存在临界值,其原因是临界值前后薄膜微观结构变化不同。     

Read-only memory disk with AgO_x super-resolution mask layer

A novel read-only memory (ROM) disk with an AgOx mask layer was proposed and studied in this letter. The AgOx films sputtered on the prernastered substrates, with pits depth of 50 nm and pits length of 380 nm, were studied by an atomic force microscopy. The transmittances of these AgOx films were also measured by a spectrophotometer. Disk measurement was carried out by a dynamic setup with a laser wavelength of 632.8 nm and a lens numerical aperture (NA) of 0.40. The readout resolution limit of this setup was λ/(4NA) (400 nm). Results showed that the super-resolution readout happened only when the oxygen flow ratios were at suitable values for these disks. The best super-resolution performance was achieved at the oxygen flow ratio of 0.5 with the smoothest film surface. The super-resolution readout mechanism of these ROM disks was analyzed as well.     

Cr掺杂的丙烷选择氧化制丙烯酸高效催化剂

在丙烷选择氧化制丙烯酸催化剂MoVTeNbOx的活性相M1基础上掺杂一定量的Cr,当Cr/Nb摩尔比为0.002时,催化剂具有很高的丙烯酸选择性(78.3%)和收率(50.7%);并采用X射线衍射、X射线光电子能谱、程序升温还原、O2程序升温脱附、NH3程序升温脱附和异丙醇氧化等手段对催化剂的构效关系进行了探讨.结果表明,适量Cr的添加可调节催化剂表面Mo6+,V5+和Te4+等物种含量,提高催化剂的氧化能力,使丙烷转化率增加.同时,适量Cr的添加使得催化剂表面酸强度下降,酸性位点数量减少,从而抑制丙烯酸的深度氧化,提高了丙烯酸选择性.