Diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate content in lube base oils in terahertz regime

We investigate the diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate (ZDDP) mixed with lube base oil (LBO) at different concentrations using terahertz time-domain spectroscopy (THzTDS).When the concentration exceeds 6.78%,the characteristic absorption peaks exhibit significantly shift,and the absorption coefficient peak value is nonlinear against concentration.Moreover,the absorption coefficients of mixed samples follow the Beer’s law at a concentration below 6.78%.The quantitative analysis enables a strategy for monitoring the formulation of lubricating oil in real time.     

Mechanically tunable broadband terahertz modulator based on high-aligned Ni nanowire arrays

We present a mechanically tunable broadband terahertz(THz) modulator based on the high-aligned Ni nanowire(NW)arrays. The modulator is a sandwich structure consisting of two polydimethylsiloxane layers and a central layer of highaligned Ni NW arrays. Our experimental measurements reveal the transmittance of THz wave can be effectively modulated by mechanical stretching. The NW density in arrays increases with the strain increasing, which induced an enhancement in the absorption of THz wave. When the strain increases from 0 to 6.5%, a linear relationship is observed for the variation of modulation depth(MD) of THz wave regarding the strain, and the modulated range is from 0 to 85% in a frequency range from 0.3 THz to 1.8 THz. Moreover, the detectable MD is about 15% regarding the 1% strain change resolution. This flexible Ni NW-based modulator can be promised many applications, such as remote strain sensing, and wearable devices.     

基底对亚波长金属双环结构太赫兹透射性质的影响

太赫兹波通过人工金属亚波长结构开口共振环(SRRs)可以产生共振吸收, 目前普遍采用LC振荡电路和线性振子模型来解释. 利用太赫兹时域光谱系统测得并无开口的亚波长金属双环和反双环结构阵列透射的太赫兹波, 结果仍然观察到在太赫兹透射谱中存在吸收峰. 分析得出此吸收峰的出现可以用线性振子模型解释. 此外, 研究发现若将此结构制作到石英基底上, 当以样品表面法线方向为轴旋转样品时其太赫兹透射时域波形和频谱均会随旋转角度出现明显的周期性变化, 而以硅为基底并不出现此现象. 本文将其原因归结为石英基底的双折射效应对亚波长金属双环结构太赫兹透射性质的影响. 本文主要目的是分析造成这种影响的物理过程.     

金属Fe薄膜的PLD制备及其非线性光学性质研究

采用脉冲激光沉积（PLD）技术在MgO基片上制备了金属Fe薄膜.利用原子力显微镜研究了不同制备温度对薄膜表面形貌的影响.x射线衍射分析表明沉积温度大于500℃时，Fe薄膜在MgO基片上有很好的结晶性，并有单一取向.通过z扫描方法测量了超薄Fe膜的光学非线性，得到了Fe薄膜的非线性折射率n₂＝709×10^-5cm²/ kW，非线性吸收系数 β＝-552×10^-3cm/W. 关键词： Fe薄膜 非线性 脉冲激光沉积     

金属纳米团簇复合薄膜Au/BaTiO3与Fe/BaTiO3的PLD制备及其光吸收特征

用脉冲激光沉积技术制备了掺杂纳米金属颗粒Au或Fe的BaTiO3复合薄膜.用透射电子显微镜和x射线光电子能谱表征了金属颗粒的形态和化学态.330-800nm范围的吸收谱研究表明,掺Au颗粒的BaTiO3薄膜在580nm附近有一个明显的共振吸收峰,而掺Fe颗粒的BaTiO3薄膜没有这样的吸收峰.用Mie散射理论对结果进行了分析.     

激光热交联型CTP版材的改进

针对自制激光热交联型CTP版材存在的问题,在版材中添加了一种磺酸酯类化合物,用其作为酸增殖剂。由于把酸增殖剂引入到了CTP版材中,所以使版材的灵敏度和成像质量得到了明显地提高。     

Consistency-dependent optical properties of lubricating grease studied by terahertz spectroscopy

The optical properties of four kinds of lubricating greases (urea, lithium, extreme pressure lithium, molybdenum disulfide lithium greases) with different NLGL (National Lubricant Grease Institute of America) numbers were investigated using terahertz time-domain spectroscopy. Greases with different NLGL grades have unique spectral features in the terahertz range. Comparison of the experimental data with predictions based on Lorentz--Lorenz theory exhibited that the refractive indices of each kind of lubricating grease were dependent on the their consistency. In addition, molybdenum disulfide (MoS₂) as a libricant additive shows strong absorption from 0.2 to 1.4 THz, leading to higher absorption of MoS₂-lithium grease than that of lithium grease.     

用于电流传感的声表面波磁致伸缩效应

利用声表面波(SAW)磁致伸缩效应可以实现一种快速、高灵敏度的电流检测方法,但磁致伸缩薄膜内部矫顽力导致了明显的磁滞误差。磁致伸缩薄膜的栅阵化设计可以减小磁致伸缩时薄膜内部矫顽力,抑制磁滞现象,从而实现高灵敏和低迟滞误差的SAW电流检测。结合有限元和耦合模理论对沉积铁钴(FeCo)薄膜栅阵的声表面波电流传感器中的磁致伸缩效应进行分析,对传感响应进行仿真,确定优化的传感结构参数。为验证理论分析,实验研制了频率为150 MHz的声表面波电流传感器件,并结合差分振荡电路及亥姆霍兹线圈,建立传感器测试系统.实验结果表明,磁致伸缩薄膜的栅阵设计大幅降低了迟滞误差,并显著提升了传感器灵敏度。      

Ultrafast nonlinear optical response of Ag:BaTiO_3 composite films at the near-ultraviolet wavelengths

The ultrafast nonlinear optical response of Ag:BaTiO3 composite films synthesized by pulse laser deposition (PLD) is studied at the near-ultraviolet (400 nm) wavelength. The pulse duration of the laser used in the measurement is 200 fs. The real and imaginary parts of the third-order nonlinear susceptibility X(3) of the composite materials are measured. The composite films indicate self-focusing effect and nonlinear saturation, the values of ReX(3) and ImX(3) are measured to be 3.42 × 10-10 and -1.37 × 10-10 esu respectively, which are much lower than those reported before. It is mainly because that the duration of the laser used in the measurements is too short to induce the hot electron excitation and the thermal effect. The ultrafast nonlinear saturated absorption response of the Ag:BaTiO3 composite films may have potential applications for femtosecond laser mode locking.     

Simulation of Anisotropic Resistivity for Mixed-Phase Manganite La2／3Ca1／3MnO3 Thin Films

We utilize the random network model based on phase separation scenario to simulate the conductive behaviour and anisotropic characteristics of resistivity for La2/3Ca1/3MnO3 (LCMO) thin films. The simulated results agree well with our experimental data, showing a metal-to-insulator transition from a high-T paramagnetic (PM) insulating phase to a low-T ferromagnetic (FM) metallic phase in both the untilted film deposited on a (001) SrTiO3 (STO) substrate and the tilted film grown on a vicinal cut STO substrate. It is found that the resistivity of the tilted sample is higher than that of the untilted one, displaying prominent anisotropic characteristics. The studies reveal that the tilting not only decreases the conduction of the FM domains, but also increases the activation energy of the PM regions, inducing the enhancement of resistivity. All those results suggest that the intrinsic inhomogeneity in the phase separation system plays a significant role in the electrical conductivity and the resistive anisotropy is related to the structure of the crystal lattice.