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Diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate content in lube base oils in terahertz regime
Authors:Lu Tian    Kun Zhao  Qingli Zhou  Yulei Shi  Dongmei Zhao  Cunlin Zhang  Songqing Zhao State Key Laboratory of Heavy Oil Processing  China University of Petroleum  Beijing  China Laboratory of Optical Sensing  Detecting Technology  China Beijing Key Laboratory for Terahertz Spectroscopy  Imaging  Key Laboratory of Terahertz Optoelectronics  Ministry of Education
Institution:Lu Tian 1,2,Kun Zhao 2,Qingli Zhou 3,Yulei Shi 3,Dongmei Zhao 3,Cunlin Zhang 3,and Songqing Zhao 2 1 State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China 2 Laboratory of Optical Sensing and Detecting Technology,China 3 Beijing Key Laboratory for Terahertz Spectroscopy and Imaging,Key Laboratory of Terahertz Optoelectronics,Ministry of Education,Department of Physics,Capital Normal University,Beijing 100048,China
Abstract:We investigate the diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate (ZDDP) mixed with lube base oil (LBO) at different concentrations using terahertz time-domain spectroscopy (THzTDS).When the concentration exceeds 6.78%,the characteristic absorption peaks exhibit significantly shift,and the absorption coefficient peak value is nonlinear against concentration.Moreover,the absorption coefficients of mixed samples follow the Beer's law at a concentration below 6.78%.The quantitat...
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