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Consistency-dependent optical properties of lubricating grease studied by terahertz spectroscopy 下载免费PDF全文
The optical properties of four kinds of lubricating greases (urea, lithium, extreme pressure lithium, molybdenum disulfide lithium greases) with different NLGL (National Lubricant Grease Institute of America) numbers were investigated using terahertz time-domain spectroscopy. Greases with different NLGL grades have unique spectral features in the terahertz range. Comparison of the experimental data with predictions based on Lorentz--Lorenz theory exhibited that the refractive indices of each kind of lubricating grease were dependent on the their consistency. In addition, molybdenum disulfide (MoS2) as a libricant additive shows strong absorption from 0.2 to 1.4 THz, leading to higher absorption of MoS2-lithium grease than that of lithium grease. 相似文献
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We investigate the diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate (ZDDP) mixed with lube base oil (LBO) at different concentrations using terahertz time-domain spectroscopy (THzTDS).When the concentration exceeds 6.78%,the characteristic absorption peaks exhibit significantly shift,and the absorption coefficient peak value is nonlinear against concentration.Moreover,the absorption coefficients of mixed samples follow the Beer’s law at a concentration below 6.78%.The quantitative analysis enables a strategy for monitoring the formulation of lubricating oil in real time. 相似文献
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太赫兹波通过人工金属亚波长结构开口共振环(SRRs)可以产生共振吸收, 目前普遍采用LC振荡电路和线性振子模型来解释. 利用太赫兹时域光谱系统测得并无开口的亚波长金属双环和反双环结构阵列透射的太赫兹波, 结果仍然观察到在太赫兹透射谱中存在吸收峰. 分析得出此吸收峰的出现可以用线性振子模型解释. 此外, 研究发现若将此结构制作到石英基底上, 当以样品表面法线方向为轴旋转样品时其太赫兹透射时域波形和频谱均会随旋转角度出现明显的周期性变化, 而以硅为基底并不出现此现象. 本文将其原因归结为石英基底的双折射效应对亚波长金属双环结构太赫兹透射性质的影响. 本文主要目的是分析造成这种影响的物理过程. 相似文献
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用太赫兹时域光谱技术研究了室温条件下的多晶天冬酰胺样品的光谱特征,得到了相应的吸收谱和折射率.这说明样品在这个波段存在光谱响应,可以用来探测分子的结构和振动情况.研究发现,天冬酰胺在实验测量有效光谱范围(0.5—2.4THz)内有两个吸收峰,一个是位于1.642—1.758THz的宽带峰,另一个是位于2.266THz的吸收峰.用密度泛函方法在B3LYP/6-31+G(d,p)基组下做了模拟计算,并对获得的频谱进行了解析,计算得到的峰位与实验结果符合较好.
关键词:
太赫兹
时域光谱技术
氨基酸
天冬酰胺 相似文献
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利用太赫兹时域光谱技术探测了室温条件下的酪氨酸样品的频谱响应,获得了酪氨酸的太赫兹频谱.实验结果表明,酪氨酸在太赫兹波段存在特征频谱响应,可以用来探测分子的结构和振动情况.在获得的太赫兹频谱中,首次观察到0.23和2.46 THz附近存在的吸收峰.用HF方法和DFT计算了酪氨酸单分子和酪氨酸二聚体的太赫兹频谱,对理论计算和实验测量的偏离进行了详细的分析.在0.23 THz处的吸收峰,初步标定为氢键连接的2个酪氨酸分子的面外摇摆振动. 相似文献
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通过对不同开口形状的太赫兹(THz)波段共振环(SRR)的有限时域差分(FDTD)模拟,发现了SRR不同开口形状在发生共振时对开口间距的平均值具有相同的透过率频谱分布的均值效应;并且观察到了在开口边缘很尖的特殊条件下,SRR开口将出现导通现象.此结果可为今后SRR开口工艺设计与质量控制提供参考,也可为SRR工作机理的进一步分析研究提供有关的依据.
关键词:
太赫兹
开口共振环
开口形状
FDTD 相似文献
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Utilizing a polarization sensitive terahertz detection method where the detector is rotated by either 0° or 90° to measure the electric field Ep, s (t) of each polarization component, we have characterized the properties of split ring resonators. The strong polarization dependence of the bianisotropic-circular-current-driven and linear-polarization-induced resonances is in excellent agreement with the simulation when the p-polarized terahertz transmission is measured. However, these electromagnetic responses vanish when the s-polarized terahertz transmission is measured. There is only a transmission minimum at 1.64 THz and the terahertz polarization rotation angle of about 90° is observed. The polarized terahertz transmission amplitudes and spectra detected at orthogonal orientations show that these behaviours are probably attributed to the birefringent effect of the sample. 相似文献