Pico-second photoelectric characteristic in manganite oxide La0.67Ca0.33MnO3 films

Ultrafast photoelectric characteristic has been observed in La_0.67Ca_0.33MnO₃ films on tilted SrTiO₃ substrates. A pico-second (ps) open-circuit photovoltage of the perovskite manganese oxide films has been obtained when the films were irradiated by a 1.064μm laser pulse of 25 ps duration. The rise time and full width at half-maximum of the photovoltage pulse are ～300 ps and ～700 ps, respectively. The photovoltaic sensitivity was as large as ～500 mV/mJ.     

Diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate content in lube base oils in terahertz regime

We investigate the diffusion interaction and quantitative analysis of zinc dialkyldithiophosphate (ZDDP) mixed with lube base oil (LBO) at different concentrations using terahertz time-domain spectroscopy (THzTDS).When the concentration exceeds 6.78%,the characteristic absorption peaks exhibit significantly shift,and the absorption coefficient peak value is nonlinear against concentration.Moreover,the absorption coefficients of mixed samples follow the Beer’s law at a concentration below 6.78%.The quantitative analysis enables a strategy for monitoring the formulation of lubricating oil in real time.     

加权p-Laplace方程解的整体分叉问题

该文利用指标理论，谱理论以及标准分叉定理，研究了加权索伯列夫空间中的p Laplace方程初值问题的解的整体分叉现象。     

多金核二氧化铈空心球用于硝基苯酚催化加氢

催化剂的微观结构在催化还原反应、有机物氧化反应及有机物转化反应中起着关键作用。本文利用无模板方法合成了多金核中空二氧化铈微球催化剂。将制备好的二氧化铈中空微球浸渍到一定浓度的氯金酸溶液中,然后多次洗涤除去表面吸附的氯金酸离子,最后通过硼氢化钠还原制成中空氧化铈微球包覆的多金核的核壳结构催化剂。将该核壳结构材料用于硝基苯酚加氢反应与金纳米粒子及氧化铈微球相比,多金核中空二氧化铈核壳结构表现出优越的活性和稳定性。通过这种浸渍洗涤再还原的简单方法合成的多金核二氧化铈催化剂有望应用于生物医药和能源环境等领域。     

投资者情绪、股票流动性与股价泡沫——基于GASDF检验法的分析

股价泡沫严重影响资本市场健康运行,而投资者情绪和市场流动性是影响泡沫膨胀和破灭的重要因素。为探究二者对股价泡沫的作用机制,本文选取上证行业指数,通过动态因子分析法,将百度指数等网络社交媒体数据与换手率等传统情绪代理变量相结合,构建多个行业的投资者情绪指标。随后基于广义右尾单位根(Generalized Sup-ADF, GSADF)检验法,检测了不同行业的泡沫,并运用面板Logit模型和中介效应检验方法,进一步分析了投资者情绪、流动性与行业股价泡沫之间的关系。实证分析及稳健性检验结果均表明,投资情绪与流动性对股价泡沫的存在性具有显著的正向作用,投资者情绪可以通过促进流动性的提升,导致股价泡沫产生的可能性的进一步提高。研究结论对于防范股价泡沫风险具有重要启示,为监管者对加强市场情绪监管提供相关理论依据。     

Monitoring the reaction between AlCl_3 and o-xylene by using terahertz spectroscopy

Terahertz time-domain spectroscopy(THz-TDS)is used to study the interaction between AlCl3and o-xylene in a temperature range from 300 K to 368 K.For comparison,the three isomers of o-,m-,and p-xylene are measured by using THz-TDS.The o-xylene carries out isomerization reaction in the presence of catalyst AlCl3.The absorption coefficient of the mixed reaction solution is extracted and analyzed in the frequency range from 0.2 THz to 1.4 THz.The temperature dependence of the absorption coefficient,which is influenced by both the dissolution of AlCl3and the production of the two other isomer resultants,is obtained,and it can indicate the process of the isomerization reaction.The results suggest that THz spectroscopy can be used to monitor the isomerization reaction and other reactions in chemical synthesis,petrochemical and biomedical fields.     

利用反射太赫兹时域强度分布定量检测沙粒中的微量原油

原油污染是海洋生物和环境安全的主要威胁之一,检测近海沙粒中的微量原油对于环境保护和原油勘探有着重要意义.本文采用反射式太赫兹时域波形对近海沙粒中的原油进行定量检测,详细地分析了延迟时间与沙粒中的原油浓度的关系.结果表明,原油浓度与延迟时间呈线性递减关系,反射式太赫兹时域波形是一种具有潜力的污染定量检测方法.     

半导体量子点中极化子的跃迁能量

研究了半导体量子点中极化子的激发态性质。采用Huybrechts线性组合算符和幺正变换方法,计算了量子点中极化子的振动频率、基态能量、第一激发态能量、由第一激发态向基态的跃迁能量和跃迁频率。分别讨论了电子-LO声子在强弱两种耦合情况下极化子的跃迁能量和跃迁频率。数值计算结果表明,跃迁能量ΔE和跃迁频率ω均随量子点有效受限长度l₀的增加而减少,且随电子-声子耦合强度α的增加而减少。     

Fast lateral photovoltaic effect in ferroelectric LiNbO_3 single crystals

We report the fast lateral photovoltaic effect in pure congruent LiNbO3 crystal induced by pulsed laser and continuous wave laser with wavelengths of 355, 532, and 1064 nm. A typical ultrafast photovoltage can be observed on the surface perpendicular to the c axis, With the rise time of 1.5 ns and the full-width at half-maximum of 1-2 ns, when the laser pulse inhomogeneously irradiates on the crystal. The peak open-circuit photovoltages show a linear dependence on the incident laser intensities. The mechanism of the photovoltaic characteristics is proposed.     

Consistency-dependent optical properties of lubricating grease studied by terahertz spectroscopy

The optical properties of four kinds of lubricating greases (urea, lithium, extreme pressure lithium, molybdenum disulfide lithium greases) with different NLGL (National Lubricant Grease Institute of America) numbers were investigated using terahertz time-domain spectroscopy. Greases with different NLGL grades have unique spectral features in the terahertz range. Comparison of the experimental data with predictions based on Lorentz--Lorenz theory exhibited that the refractive indices of each kind of lubricating grease were dependent on the their consistency. In addition, molybdenum disulfide (MoS₂) as a libricant additive shows strong absorption from 0.2 to 1.4 THz, leading to higher absorption of MoS₂-lithium grease than that of lithium grease.