Corrosion behaviour of sintered NdFeB coated with Al/Al2O3 multilayers by magnetron sputtering

Al/Al₂O₃ multilayers were deposited on sintered NdFeB magnets to improve the corrosion resistance. The amorphous Al₂O₃ films were used to periodically interrupt the columnar growth of the Al layers. The structure of the multilayers was investigated by Scanning Electron Microscopy (SEM) and High Resolution Transmission Electron Microscopy (HRTEM). It was found that the columnar structure was effectively inhibited in the multilayers. Subsequent corrosion testing by potentiodynamic polarization in 3.5 wt.% NaCl and neutral salt spray test (NSS) revealed that the Al/Al₂O₃ multilayers had much better corrosion resistance than the Al single layer. Furthermore, for multilayers with similar thickness, the corrosion resistance was improved as the period decreased.     

铌和锆对(Nd,Pr)2Fe14B/α-Fe快淬合金晶化和磁性能的影响

研究了Nb和Zr添加对快淬纳米双相(Nd,Pr)2Fe14B/α-Fe合金晶化行为和磁性能的影响. 结果表明 (Nd0.4Pr0.6)8.5Fe85.5B6合金非晶晶化时, 在α-Fe相初始晶化后, 出现了(Nd,Pr)3Fe62B14亚稳相, 最终亚稳相分解形成(Nd,Pr)2Fe14B和α-Fe两相组织; (Nd0.4Pr0.6)8.5Fe84.5Nb0.5Zr0.5B6非晶晶化时, 同时析出α-Fe相和(Nd,Pr)2Fe14B相. 这说明添加Nb和Zr可避免亚稳相的形成并细化晶粒, 最大磁能积(BH)max从复合添加前的107.5上升到143.6 kJ·m-3. 而且, Nb和Zr原子在非晶晶化过程中可以部分取代Nd和Pr的晶位, 使稀土原子可以参与形成更多的硬磁相, 进一步提高了内禀矫顽力iHc. 合金(Nd0.4Pr0.6)8.5Fe84.5Zr0.5Nb0.5 B6经690 ℃退火10 min后磁性能最优, Br=1.10 T, iHc=534.2 kA·m-1, (BH)max=143.6 kJ·m-3.     

Nd-Fe-B永磁材料氢脆过程及Al+Al2O3阻氢涂层研究

从材料保护的角度出发，在分析了Nd-Fe-B永磁材料的氢脆过程及氢脆的特点后，用RF磁控溅射制备一定厚度的Al薄膜并在一定条件下进行氧化处理，得到了Al A12O3复合涂层。用SEM和XBD分析了涂层形貌和组成，并用高压气相充氢的方式测试了涂层的阻氢性能。研究表明，厚度为8．0μm复合涂层的阻氢性能为：在10MPa的H2环境中(25℃)，阻氢时间达65min，且对磁体的磁性能无不良影响。     

非晶Nd8Fe86B6合金快速晶化过程中的组织变化与磁性能

利用高频感应加热,对熔体快淬Nd8Fe86B6非晶薄带进行了快速晶化退火,并对退火后薄带的微观组织及磁学性能进行了分析.结果表明,快速加热可使非晶带迅速晶化.加热速度强烈地影响薄带的组织和磁性能.不同的加热速度下,都有一个最佳的得到较高磁学性能的加热时间与它相配合.当加热工艺为 加热电压5 kV,加热时间10 s时,晶化后的薄带磁性能可达(BH)max=105 kJ·m-3,Br=0.93 T,Hci=258 kA·m-1.     

添加Dy在快淬NdFeB永磁体中的作用

在之前研究Nb元素的添加对快淬(Nd,Dy)_11.5Fe_82.4-mNb_mB_6.1永磁体磁性能、温度特性及显微组织影响的基础上,进一步研究了Dy元素在Nd_11.5-nDy_nFe_81.4Nb₁B_6.1 (n＝0,0.5,1,1.5,2)永磁体中 关键词： NdFeB 磁性能 温度特性 显微组织 X-ray absorption fine structure     

Intergranular Melting of Ultrafine Grained Nd2Fe14B Studied by Means of Radiotracer Diffusion

Grain-boundary (Gb) diffusion was studied in ultrafine grained Nd₂Fe₁₄B-based permanent magnets below and above the melting transition of the Nd-enriched intergranular phase using the radiotracer technique with the isotope ⁵⁹Fe. The product D _Gb of interface diffusion coefficient and interface thickness shows a substantial increase above the intergranular melting transition. Assuming a volume self-diffusivity as in -Fe, an analysis in the framework of grain-boundary diffusion kinetic of type B yields an Arrhenius-type behaviour D _Gb = 1.53 × 10^–11 exp(–1.74 eV/kT) m³ s^–1 below the intergranular melting transition. Similar values D _Gb are observed for ultrafine grained Nd-Fe-B with reduced Nd excess in the grain boundaries. The diffusion characteristics are compared with the kinetics of the hot-deformation which is of technical relevance for the processing of high-performance permanent magnets.     

LECR2离子源的改造及初步运行结果

The Latest developed LECR2M (Lanzhou ECR No.2 Modified)source is the updated one of LECR2(Lanzhou ECR No.2)source at IMP.It has been assembled on the low energy ion beam experimental platform to produce MCI beams for atomic physics and material pllysics experimental research.In our updating program,the structure of injection and extraction components has been modified to make the source structure more simple and effective.The hexapole magnet has also been replaced by a new hexapole magnet with higher radial field and larger inner diameter.With this updating,stronger magnetic field confinement of the ECR plasma is possible and better base vacuum condition is also achieved.LECR2M was designed to be operated at 14.5GHz.During the preliminary test.1.3emA O6 beam was extracted with the injected rf power of 1.1kW.The source has been used to deliver intense MCI beams for different experiments.After some discussion of the main features of this newly updated source,some of the typical commissioning test results of LECR2M will be presented.     

Anisotropic powder from sintered NdFeB magnets by the HDDR processing route

Sintered NdFeB-based scrap magnets were recovered and processed using the HD and HDDR routes. The effects of varying the HDDR processing temperature were investigated (over the range 835-930 °C). The disproportion was carried out with a pressure ramp to a maximum of 1000 mbar hydrogen pressure with a 1 h hold time at each step and the optimum recombination conditions were set at 100 mbar with a 20 min hold time. Anisotropic NdFeB powder was produced in all cases with the best magnetic properties achieved at a processing temperature of 880 °C, producing powder with a remanence of 1.10(±0.02) T and an intrinsic coercivity of 800 (±16) kA m⁻¹ and giving a (BH)_max of 129(±2.5) kJ m⁻³.     

氢爆工艺对NdFeAlB磁体的微结构和永磁性能的影响

研究了氢爆工艺（HD）对烧结NdFeAlB的微观结构与永磁性能的影响,用HD工艺制备的NdFeAlB烧结磁体（HD磁体）的矫顽力比传统球磨（BM）的工艺的高,但剩磁及磁能积较低;微观分析发现HD磁体的晶粒边界上存在着未烧结完全的磁粉;X射线衍射测试表明HD磁体易磁化的聚向度较低,还提出了一些对通常的HD工艺进行改进的方法。