中学师生对化学实验认识的调查与思考

以问卷结合与部分师生个别座谈的方法,就山西省内中学师生对化学实验功能及学生实验能力的认识进行了调查,对调查结果进行了分析与研究,找出了存在问题,提出了改进建议,旨在为进一步搞好实验教学及其改革提供依据。     

邻香兰素甲硫氨酸席夫碱四核铜配合物的合成及结构表征

邻香兰素甲硫氨酸席夫碱四核铜配合物的合成及结构表征     

1,4-二咔唑基苯微米结构的可控制备及光波导性质

采用液相组装法通过改变组装条件制备了高结晶性、 宽度为2 μm、 长度为10~40 μm的1,4-二咔唑基苯一维微米线(BeCzMW). X射线衍射和选区电子衍射结果表明, BeCz分子沿着晶体[100]方向生长. 通过扫描近场光学显微镜进一步发现, BeCzMW被紫外激光激发后产生的荧光被限域在一维结构中, 并沿着一维方向进行传导. BeCzMW在420 nm处的光学损耗系数R=0.0628 dB/μm, 表明BeCzMW具有良好的光波导性能.     

16O+28Si全熔合激发函数

在50—90MeV的能量范围内,以1.0MeV为能量步长,测量了¹⁶O+²⁸Si的全熔合激发函数.用熔合模型分析了激发涵灵敏,提取了模型参数在质心系能量小于46MeV时,激发函数存在粗结构,其峰位分别在34.5、38.5和43MeV.能量在46MeV以上时,结构逐渐消失.     

硅微条探测器的研制

本文介绍了利用“平面工艺”新技术研制成功的硅微条探测器.该探测器所用的硅材料为n型硅,电阻率为3kΩ.cm,晶向<111>.探测器的厚度为400μm,灵敏面积为18mm×12mm,条宽为20μm,共有300个微条,在反向偏压为100V时,其漏电流为5×10^－9A.用电荷收集分布方法测得该探测器的位置分辨为5.3μm.     

Possible Experimental Evidence of a Moderate Proton Halo in ^29S

The total reaction cross sections (TRCSs) of^29S ^28Si have been measured at intermediate energies. An obvious enhancement in TRCS of ^29S is observed as compared with its neighbouring nuclei. The TRCSs of ^29S ^28Si arecal culated with the modified Glauber theory in the optical limit and few-body approaches. The different factor d as a possible measure of halo appearance is deduced from the experimental and theoretical data. It is well accepted that ^27p is a proton halo nucleus. Although not as anomalous as ^27p, the different factor d of ^29S is obviously larger than that of its neighbouring isotones of N = 13. This result indicates that a moderate proton halo may exist in ~9S nucleus. We calculate the total reaction cross sections for ~9S with the modified Glaubertheory as a function of incident energy and compare the results with those for 2rSi which is a core nucleus 0f29S.The measured TRCSs of 27Si4-2SSi can be described to be satisfactory by the modified Glauber theory of theoptical limit approach. Although a diffused nuclear density distribution is used, the theories still inadequatelypredict the experimental TRCSs of 29S4-2SSi, which further indicates the possibility of proton halo in 29S.     

路径积分方法计算聚合物溶液热力学性质

提出了把聚合物溶液的自由能分解为 3部分 ,平动部分、构象部分和热修正项部分 .其中后两部分具有相对于链段的可加性 ,在引入了“有效浓度”的概念后可以用路径积分方法计算 .当采用体积分数代替有效浓度时 ,就回到了李晓毅和赵得禄的溶液理论 .还利用本理论研究了不同分子量聚苯乙烯 环己烷体系的相分离曲线 ,同Flory Huggins(FH)理论相比 ,大大提高了同实验数据的符合程度     

A NEW POLYNOMIAL INVOLUTIVE SYSTEM AND A CLASSICAL COMPLETELY INTEGRABLE SYSTEM

Under the constrained condition induced by the eigenfunctions and the potentials, the Laxsystems of nonlinear evolution equations in relation to a matris eigenvalue problem are nonlin-earized to be a completely integrable system (R~(zN),dp∧dq, H), while the time part of it isnonlinearized to be its N-involutive system {F_m}. The involutive solution of the compatiblesystem (F_0), (F_m) is transformed into the solution of the m-th nonlinear evolution equation.     

SnO单晶纳米薄片的制备及其作为锂离子电池负极材料的研究

在超声波辅助下，采用简单的溶液化学方法合成了高宽厚比的SnO单晶纳米薄片，其尺寸和厚度可通过CTAB的量来进行调控。由于SnO单晶纳米薄片的{001}面低的表面原子密度和膨胀的晶格间距，将SnO单晶纳米薄片用作锂离子电池负极材料时，可获得接近理论值的可逆充放电容量。