共查询到20条相似文献,搜索用时 62 毫秒
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对[μ-CF_3CO_2)_2Ln(μ-CF_3HCO_2)Al(i-Bu)_2·THFl_2(Ln=Nd,Y)配合物单晶结构的X-射线分析指出,配合物具有中心对称性,配位中心由两个稀土和两个Al离子组成,稀土由两个THF和6个TFA分子配位形成畸变的三盖三棱柱结构,Al由两个TFAG和两个i-Bu配位形成四面体结构。桥连Al与两个稀土的TFA分子的羧基发生歧化加氢,其碳原子由SP ̄2型转变为SP ̄3型.NMR研究表明,在THF溶液中,该配合物保持了它在单晶中的配位结构,所不同的是两个i-Bu在溶液中有两种异构形成,二者间为慢交换过程。 相似文献
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采用经验紧束缚理论,以类似闪锌矿结构的晶体模型模拟Ge_xSi_(1-x)合金,根据总能最小原则计算了Ge_xSi_(1-x)合金中的键长及点阵常数.同时以紧束缚方法计算了原子位置发生弛豫前后的电子能带结构,并与虚晶近似下的计算结果进行了比较.计算结果表明,Ge_xSi_(1-x)合金中的键长基本上与合金组分无关,各自接近于Ge,Si晶体中的键长,与广延x射线吸收精细结构(EXAFS)测量结果符合得很好.原子位置的弛豫对合金的电子能带结构影响很小,对合金的电子能带结构起主要作用的是合金的化学组分无序. 相似文献
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本文综述了R-Ba-Cu-O体系,Bi-Sr-Ca-Cu-O体系,T1-Ba-Ca-Cu-O #系,T1-Sr-Ca-R-Cu-O体系以及Pb-Sr-R(Ca)Cu-O体系超导相的相关系和晶体结构,并讨论了超导相的结构特点和它们之间的相互关系. 相似文献
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用标准固相反应法,我们制备了Bi1.6Pb0.4Sr2Ca2Cu3Oy和Bi2CaCu2Oy纯相样品,在液氮温度下测量了Cu-NQR和B-NQR静态谱,发现NQR谱都为大宽包,Cu-NQR谱线位置反映铜原子所处的氧环境,Bi2Sr2Cu2Oy的NQR谱宽反映其调制结构,Bi1.6Pb0.4Sr2Ca2Cu3OyNQR谱宽取决于其掺杂浓度。由于电场梯度弥散很大,Bi-NQR谱很难观察。 相似文献
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研究了Gd_(1-x)Ca_xBa_2Cu_3O_(7-y)(0.0≤X≤0.20)高温超导体在常压和高压下的超导电性在1-300K温度范围内,利用Bridgman对顶砧获得压力达9.0GPa,测量了(X=0.10,0.15,0.20)样品的dT_c/dp分别为7.68,7.8和4.46K/GPa。发现T_c的压力导数随着ca ̄(2+)含量的增加而下降,分析了氧含量对T_c和dT_c/dP的影响.利用常压下晶格参数精修值和阳离子与氧离子间距随压力的改变,说明CuO_2面在超导电性上的作用,用CuO_2面之间耦合解释T_c(P)曲线的非线性关系。 相似文献
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采用固相外延的方法在Si(100)衬底上生长了C组分为0.5atT的Si1-yCy合金,并对合金的质量及特性进行了测试分析。 相似文献
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Cyclic competition game models, particularly the “rock–paper–scissors” model, play important roles in exploring the problem of multi-species coexistence in spatially ecological systems. We propose an extended “rock–paper–scissors” game to model cyclic interactions among five species, and find that two of the five can coexistent when biodiversity disappears, which is different from the “rock–paper–scissors” game. As the number of fingers is five, we named the new model the “fingers” game, where the thumb, forefinger, middle finger, ring finger, and little finger cyclically dominate their subsequent species and are dominated by their former species. We investigate the “fingers” model in two ways: direct simulations and nonlinear partial differential equations. An important finding is that the number of species in a cyclic competition game has an influence on the emergence of biodiversity. To be specific, the “rock–paper–scissors” model is in favor of maintaining biodiversity in comparison with the “fingers” model when the variables (population size, reproduction rate, selection rate, and migration rate) are the same. It is also shown that the mobility and reproduction rate can promote or jeopardize biodiversity. 相似文献
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The differences of the pitch and duration of Chinese syllables between Putonghua (PTH) and Taiwan Mandarin (TM) were studied. The speech materials to be used are not only isolated syllables, but also sentences. The results reveal that: For the isolated syllables, T1 and T2 in TM are influenced by Minnan dialect, therefore their pitch are lower than those in PTH. T3 is fall-rise in PTH, while it is fall in TM. Moreover, the syllable duration sequence for different tone is T3〉T2〉T1〉T4 in PTH, while it is T1〉T2〉T3〉T4 in TM. For the syllables in sentences, T2 is mid-rise in PTH, while it is mid-level in TM. And the T3 is longer than T4 but shorter than T1 or T2 in PTH, while it is the shortest in TM. Furthermore the effects of prosodic phrase boundary on duration for different tones are almost the same in PTH, but the lengthening part of T1 or T2 is longer than that of T3 or T4 in TM. 相似文献
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Downstep in pitch contour of Chinese Putonghua is examined using subtly designed sentences by controlling tone combinations. The results show both automatic and nonautomatic downstep phenomena exist in Chinese. In non-automatic downstep, low tones compress downwards the pitch range of the following syllables. and the main influence of downstep is on topline. Low tone not only lower the topline behind it, but also raise the high tones before it, the effects are compatible with each other. In automatic downstep, the topline of pitch contour in intonational phrase is presented as a linear downtrend, but it differs among speakers due to the effect of personal stress practice. In comparison with downstep phenomenon in other tone or non-tone languages, the downstep ratio in Chinese is not constant, and the domain of downstep is not limited within the adjacent tones. 相似文献
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JIA Duojie 《中国物理C(英文版)》2008,32(7)
It is shown that SU(2) QCD admits an dual Abelian-Higgs phase, with a Higgs vacuum of a type-Ⅱ superconductor. This is done by using a connection decomposition for the gluon field and the random-direction approximation. Using a bag picture with soft wall, we presented a calculational procedure for the glueball energy based on the recent proof for wall-vortices [Nucl. Phys. B 741(2006)1]. 相似文献
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A multi-conjugate adaptive optics (MCAO) can offer a possibility of widening field of view (FOV) characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle's expressions of two deformable mirrors (DMs) MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance. 相似文献
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Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use. 相似文献
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Based on the research in Ref. [5][Materials Science and Engineering, 1989; A122: 57 63], an improved model of heat source is set up, the different modes of Lamb wave in an isotropic sample generated by a chopped electron beam at frequency f are obtained with integral transform and normal function expansion method, and the output signal of PZT coupled at the back surface of the sample is found out. The generation mechanism of SEAM (Scanning Electron Acoustic Microscopy) signal is discussed. It shows that the SEAM is a near field imaging technique with high spatial resolution and its best lateral spatial resolution is about 2√2α (α is the radius of the focused electron beam). Some of experimental results of SEAM images are presented in the paper and it shows that the spatial resolution of SEAM is better than 0.5 μm and smaller than the thermal diffusion length of the sample. Therefore the character of near field imaging in SEAM is also proved experimentally. 相似文献
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Transmission spectra of coupled cavity structures (CCSs) in two-dimensional (2D) photonic crystals (PCs) are investigated using a coupled mode theory, and an optical filter based on CCS is proposed. The performance of the filter is investigated using finite-difference time-domain (FDTD) method, and the results show that within a very short coupling distance of about 3λ, where λ is the wavelength of signal in vacuum, the incident signals with different frequencies are separated into different channels with a contrast ratio of 20 dB. The advantages of this kind of filter are small size and easily tunable operation frequencies. 相似文献