Co和Cr掺杂对层状钙钛矿锰氧化物La1.2Sr1.8Mn2O7磁性的影响

研究了层状钙钛矿锰氧化物La_1.2Sr_1.8Mn₂O₇中Mn被Co和Cr替代对磁性能的影响.Co替代Mn后,长程铁磁序被破坏,铁磁性减弱,出现团簇玻璃态和自旋玻璃态,表明Co离子和Mn离子之间不存在双交换作用.而Mn被Cr替代后长程铁磁序仍然保持,证实Cr³⁺和Mn³⁺之间存在铁磁性交换作用. 关键词：     

钙钛矿锰氧化物(La1-xGdx)4/3Sr5/3Mn2O7 (x=0, 0.025) 磁性和输运性质研究

采用传统的高温固相烧结法制备了双层钙钛矿锰氧化物(La_1-xGd_x)_4/3Sr_5/3Mn₂ O₇ (x=0, 0.025)多晶样品. 通过X射线衍射仪研究发现样品为Sr₃Ti₂O₇型四方结构, 空间群为I4/mmm; 磁性测量表明, Gd³⁺掺杂后的样品(La_0.975Gd_0.025)_4/3Sr_5/3Mn₂O₇的三维磁有序转变温度(T_C1^3D)、磁化强度(M)均降低, 这是由于Gd³⁺的掺杂引起晶格的畸变, 从而使得晶格常数发生改变, 减弱了铁磁耦合而导致的; 通过电子自旋共振谱测量发现, 在T_C^3D<T<300 K温度范围内, 两样品在顺磁的基体上均有短程的铁磁团簇存在, 出现了相分离现象. 电性测量表明: 两样品分别在T_C1^3D (La_4/3Sr_5/3Mn₂O₇ 样品的三维磁有序转变温度, T_C0^3D)<T<300 K温度范围内均以三维变程跳跃的方式导电, 分析得出Gd³⁺的掺杂使得载流子局域长度的减小. 这表明载流子需要吸收更多的能量才能克服晶格的束缚进行跳跃, 因此(La_0.975Gd_0.025)_4/3Sr_5/3Mn₂ O₇ 样品的电阻较高.     

自旋梯状化合物Sr14(Cu1-yFey)24O41的拉曼散射谱研究

利用常规的固相合成法制备了三种Sr₁₄(Cu_1-yFe_y)₂₄O₄₁(y=0,0.03,0.05)多晶样品,其中y=0.03是单纯Fe³⁺掺杂,y=0.05是Fe³⁺和Fe²⁺混合掺杂.在100—1500cm^-1频移范围内测量了这三种样品的偏 关键词： 拉曼散射 电输运性质 自旋梯状化合物     

锰位铁掺杂La0.67Sr0.33FexMn1-xO3薄膜的光诱导效应

分别采用溶胶-凝胶法和脉冲激光沉积的方法制备了La_067Sr_033Fe_xMn_1-xO₃(x=0, 005, 010, 015)系列块材和薄膜,研究了Fe部分替代对La_067Sr_033Fe_xMn_1-xO₃薄膜 关键词： 光诱导 Fｅ掺杂 晶格效应     

La0.7Sr0.3-x□xCoO3(0≤x≤0.2)钴氧化物中锶空位诱导的自旋态转变效应

研究了锶空位对La_0.7Sr_0.3-x_xCoO₃ (0≤x≤0.2)多晶钴氧化物结构、磁性和输运性质的影响.结果表明：随着锶空位浓度x的增大,A位阳离子无序度增大,导致铁磁双交换作用减弱及反铁磁超交换作用增强,两者相互竞争,出现团簇自旋玻璃态;空位浓度超过10%后,Co—O键长迅速减小,导致晶体场劈裂能加大,大部分三价钴离子以低自旋态出现,系统基态为类超顺磁态, 关键词： 空位掺杂 钴氧化物 自旋转变     

Dy,Co共掺杂对BiFeO3陶瓷磁特性和磁相变温度Tc的影响

采用快速液相烧结法制备BiFeO₃和Bi_0.95Dy_0.05Fe_1-xCo_xO₃ (x=0, 0.05, 0.1, 0.15)陶瓷样品. 实验结果表明: 所有样品的主衍射峰与纯相BiFeO₃相符合且具有良好的晶体结构, 随着Co³⁺掺杂量的增大, Bi_0.95Dy_0.05Fe_1-xCo_xO₃样品的主 衍射峰由双峰(104)与(110)逐渐重叠为单峰(110), 当掺杂量x>0.05时, 样品呈现正方晶系结构; SEM形貌分析可知: Dy³⁺, Co³⁺共掺杂使BiFeO₃晶粒尺度由原来的3—5 μ减小到约1 μ. 室温下, BiFeO₃样品表现出较弱的铁磁性, 随着Dy³⁺和Co³⁺掺杂, BiFeO₃样品的铁磁性显著提高. 在外加磁场为30 kOe的作用下, Bi_0.95Dy_0.05Fe_1-xCo_xO₃ (x=0.05, 0.1, 0.15)的M_r分别为0.43, 0.489, 0.973 emu/g; M_S分别为0.77, 1.65, 3.08 emu/g. BiFeO₃和Bi_0.95Dy_0.05Fe_1-xCo_xO₃样品磁矩M随着温度T的升高而逐渐减小, Dy掺杂使BiFeO₃样品的T_N由644 K升高到648 K, 而T_C基本没有变化. Dy和Co共掺杂导致BiFeO₃样品磁相变温度T_C由870 K降低到780 K, 其T_C变化主要取决于Fe-O-Fe反铁磁超交换作用的强弱和磁结构的相对稳定性. 关键词： 铁磁电材料 磁滞回线 磁相变温度     

Mn的价态对La0.8Ba0.2MnO3电磁性能的影响

在2—390K温度之间研究了La_0.8Ba_0.2MnO₃的 磁矩、磁电阻与温度的关系.发 现以不同价态的Mn元素引入得到的La_0.8Ba_0．2MnO₃ ，性能虽然都存在金属 —绝缘体转变，以及在磁场作用下居里温度附近电阻率变化非常显著的特点，但是价态对磁 性转变温度T_C，金属—绝缘体转变温度T_mi，以及磁电阻极大 值温度T_MR的影 响都非常显著.三种价态相比较，使用二价Mn的电阻率最低以及磁性转变温度更接近室温.认 为影响材料性能的主要因素是材料制备时引进的Mn元素的价态，由于原料价态的不同而形成 的氧空位浓度变化，进而影响了Mn⁴⁺/Mn³⁺的比. 关键词： 价态 磁电阻 居里温度 金属—绝缘体转变     

层状钙钛矿La1.3Sr1.7Mn2-xCuxO7的磁性及电特性

通过固相反应烧结法成功制备了层状钙钛矿La_1.3Sr_1.7Mn_2-xCu_xO₇多晶,主要研究了其磁电特性.结果表明,样品为Sr₃Ti₂O₇型钙钛矿结构.随着温度的降低,其磁性经历了一个很复杂的转变过程.当x=0时,在T^*=231K出现二维短程铁磁有序,在< 关键词： 层状钙钛矿 磁性 电特性     

多自旋态离子Co替代诱导La2/3Ca1/3MnO3体系的输运反常

利用具有多自旋态的Co离子进行Mn位替代,制备了La_2/3Ca_1/3Mn_1-xCo_xO₃ (0≤x≤0.15) 系列样品并研究了体系的结构和输运特性.结果表明,在替代范围内,样品呈现很好的单相结构,各晶格参数随替代量的增大而减小;Co替代导致体系出现电输运反常,具体表现为在居里温度T_C以下电阻-温度曲线的二次金属-绝缘转 关键词： Mn位替代 双峰现象 自旋结构 磁电阻效应     

钙钛矿型稀土锰氧化合物Nd0.5Sr0.4Pb0.1Mn1-x FexO3中Mn位的Fe替代效应

对Nd_0.5Sr_0.4Pb_0.1Mn_1-xFe_x O₃系列多晶样品的结构，磁和转变特性进行了实验研究.在x=0.00—0.10的范围内获得了单相样品，Fe³⁺的替代并没有引起整个系列的结构变化，然而Mn位的掺杂却强烈地抑制了Nd _0.5Sr_0.4Pb_0.1MnO₃的铁 关键词： 磁结构 磁性 P')" href="#">磁转变温度T_P 双交换作用     

Fe掺杂La0．8Sr0．2Co1-xFexO3磁性的研究

利用溶胶-凝胶法制备了一系列的La0.8Sr0.2Co1-xFexO3样品.通过研究在不同外加磁场下磁化强度和温度变化的关系发现,在较高的外场下La0.8Sr0.2Co1-xFexO3样品的磁性反转现象没有被观察到;在低场下La0.8Sr0.2Co1-xFexO3系统磁性反转现象被实现.这说明Fe的掺杂引起了La0.8Sr0.2Co1-xFexO3样品中铁磁和反铁磁之间的竞争,导致了La0.8Sr0.2Co1-xFexO3样品磁性反转;同时外加磁场的强弱影响了La0.8Sr0.2Co1-xFexO3系统磁性反转现象的发生,外加磁场增大使得在La0.8Sr0.2Co1-xFexO3样品中Co离子的自旋平行趋势更强,在铁磁和反铁磁之间的竞争中铁磁耦合占主导优势,因此在较高的外场下磁性反转现象没有被观察到.     

Magnetic Anisotropy Induced by Orbital Occupation States in La_(0.67)Sr_(0.33)MnO_3 Films

Interface engineering is an effective and feasible method to regulate the magnetic anisotropy of films by altering interfacial states between films.Using the technique of pulsed laser deposition,we prepared La_(0.67)Sr_(0.33)MnO_3(LSMO) and La_(0.67)Sr_(0.33)MnO_3/SrCoO_(2.5)(LSMO/SCO) films on(110)-oriented La_(0.3)Sr_(0.7)Al_(0.65)Ta_(0.35)O_3 substrates.By covering the SCO film above the LSMO film,we transformed the easy magnetization axis of LSMO from the [001] axis to the [110] axis in the film plane.Based on statistical analyses,we find that the corresponding Mn-Mn ionic distances are different in the two types of LSMO films,causing different distortions of Mn-O octahedron in LSMO.In addition,it also induces diverse electronic occupation states in Mn~(3+) ions.The eg electron of Mn~(3+)occupies 3 z~2-r~2 and x~2-y~2 orbitals in the LSMO and LSMO/SCO,respectively.We conclude that the electronic spin reorientation leads to the transformation of the easy magnetization axis in the LSMO films.     

成分调制的La1－xSrxMnO3复合隧道结

利用磁控溅射和Sr成分的调制以及原位热处理方法，在10mm×10mm大小的(001) 取向SrTiO_３单晶衬底上制备出三明治结构为La_0.7Sr_0.3MnO３(100nm)/La_0.96Sr_0.04MnO_３ (5nm)/ La0.7Sr_0.3MnO_３ (100nm) 的隧道结外延薄膜，然后再次 利用磁控溅射方法，在三层单晶膜上方继续沉积Ir_２２Mn_７８(15n m)/Ni_７９Fe_２１(5nm)/Pt(20nm)等金属三层膜.最后利用深紫外曝 光和Ar离子束刻蚀等微加工技术，制备出长短轴分别为12和6μm或者8和4μm大小的椭圆形L a_１-xSr_xMnO_３成分调制的复合磁性隧道结.在4.2K和 外加磁场8 T的测试下，La_１-xSr_xMnO_３成分调制的复 合磁性隧道结其隧穿磁电阻(TMR)比值达到3270%, 直接从实验上证实了铁磁性La_{0.7Sr0.3MnO３金属氧化物的自旋极化率（97%）可接近100％，具 有很好的半金属性质. 关键词： １-x}Sr_xMnO_３')" href="#">La_１-xSr_xMnO_３ 半金属 成分调制 复合磁性隧道 结 隧穿磁电阻     

Effect of Terraces at the Interface on the Structural and Physical Properties of La_(0.8)Sr_(0.2)MnO_3 Thin Films

Employing atomic force microscopy,transmission electron microscopy and the second harmonic generation technique,we carefully explore the structural properties of 6-unit-cell-thick La_(0.8)Sr_(0.2)MnO_3 films grown on SrTiO_3 with atomically flat TiO_2-terminated terraces on the surface.The results clearly demonstrate that the terraces on the surface of TiO_2-terminated SrTiO_3 can improve the layer-by-layer epitaxial growth of the manganite films,which results in uniform film coverage at the beginning of growth and thus reduces the substrate-induced disorder at or near the interface.Comparing the magnetic and transport properties of La_(0.8)Sr_(0.2)MnO_3 films with the thicknesses varying from 6 unit cells to 80 unit cells grown respectively on as-received SrTiO_3 and TiO_2-terminated SrTiO_3,it is found that these atomically flat terraces on the surface of TiO_2-terminated SrTiO_3 can greatly enhance the Curie temperature and conductivities of the ultrathin La_(0.8)Sr_(0.2)MnO_3 films with thickness less than 50 unit cells,while no obvious difference is detected in the magnetic and transport properties of the 80unit-cell thick films.     

Substitution priority of Eu~(2+) in multi-cation compound Sr_(0.8)Ca_(0.2)Al_2Si_2O_8 and energy transfer

A blue phosphor was obtained by doping Eu~(2+)into a multi-cation host Sr_(0.8)Ca_(0.2)Al_2Si_2O_8 through high temperature solid state reaction.The emission spectra show a continuous red-shift behavior from 413 nm to 435 nm with Eu~(2+)concentration increasing.The substitution priority of Eu~(2+)in Sr_(0.8)Ca_(0.2)Al_2Si_2O_8 was investigated via x-ray diffraction(XRD)and temperature properties in detail:the Ca~(2+)ions are preferentially substituted by Eu~(2+)at lower doping,and with the Eu~(2+)concentration increasing,the probability of substitution for Sr~(2+)is greater than that of replacing Ca~(2+).Accordingly,we propose the underlying method of thermal property to determine the substitution of Eu~(2+)in the multi-cation hosts.Moreover,the abnormal increase of emission intensity with increasing temperature was studied by the thermoluminescence spectra.The energy transfer mechanism between the Eu~(2+)ions occupying different cation sites was studied by the lifetime decay curves.A series of warm white light emitting diodes were successfully fabricated using the blue phosphors Sr~+_(0.8)Ca_(0.2)Al_2Si_2O_8:Eu~2 with commercial red phosphor (CaSr)SiAlN_3:Eu~(2+)and green phosphor(Y Lu)_3Al_5O_(12):Ce~(3+),and the luminescent efficiency can reach 45 lm/W.     

二维周期性多孔La_(0.83)Sr_(0.17)Mn_(0.9)Zn_(0.1)O_3发射率研究

基于麦克斯韦方程组,利用时域有限差分方法(FDTD)计算了二维周期性多孔钙钛矿型氧化物La_(0.83)Sr_(0.17)Mn_(0.9)Zn_(0.1)O_3(LSMZO)的光谱特性,讨论了结构尺寸对光谱特性的影响。计算结果表明,当孔径约比热辐射波长小一个量级时,周期性多孔LSMZO的发射率比块体材料有所提高,这对改善热致变色材料的性能具有一定的指导意义。     

过渡金属离子掺杂对La1.2Ca1.8Mn2O7输运性质的影响

研究了过渡金属元素掺杂对层状钙钛矿结构锰氧化物La1.2Ca1.8Mn2O7体系输运性质的影响.实验结果表明不同过渡金属离子掺杂均导致体系的金属-绝缘转变温度降低,电阻率与最大磁电阻值(Cr除外)增加.当掺杂量较高时,磁性Cr、Fe、Co、Ni离子对体系性质的影响与其磁性相互作用密切相关.     

钙钛矿结构La1-xSrxCoO3(x=0.7,0.8,0.9,1.0)样品的铁磁相变和绝缘-金属转变

利用固相反应法及溶胶凝胶法我们制备了多晶La1-xSrxCoO3(x=0.7,0.8,0.9,1.0)样品.X射线衍射谱表明,La1-xSrxCoO3样品呈ABO3型钙钛矿结构,晶格常数随着x的增加而增大.与钙钛矿结构的锰氧化物类似,电阻率随温度变化以及磁化强度随温度变化的关系强烈依赖于掺杂浓度.x=0.7和0.8的样品在低温下显示铁磁性,而x=0.9和1.0的样品磁化强度随温度变化没有显示铁磁转变.电阻率随温度的变化似乎与磁化率测量相对应,在x=0.8和0.9样品之间存在绝缘-金属转变.     

制备压力对La2/3Sr1/3MnO3的磁电阻效应的影响

 研究了制备压力对纳米块状样品La_2/3Sr_1/3MnO₃的结构、磁学和电学性质的影响。结果表明：样品的晶粒尺寸随制备压力的增加而变小，且不同样品的磁电阻效应不同。低场磁电阻效应在整个实验温区都随制备压力的升高而变弱，这主要是由制备压力使样品晶粒界面连接更紧密所导致；T<200 K时，高场磁电阻效应随制备压力的升高而变强，T>200 K时，高场磁电阻效应随制备压力的升高反而变弱，这主要是由制备压力改变样品的晶粒尺寸所引起。     

Photoluminescence properties of Ca_4La_6(SiO_4)_4(PO_4)_2O_2-based phosphors for wLEDs

The apatite compound Ca_4La_6(SiO_4)_4(PO_4)_2O_2(CLSPO) was explored as the host material for phosphors used in white light-emitting diodes(w LEDs). The crystal structure of the CLSPO host prepared by the solid-state reaction method was investigated with Rietveld refinement. The rare earth ions(Eu~(3+)/Tb~(3+)/Ce~(3+), Tb~(3+)/Tb~(3+), Mn~(2+))activated CLSPO phosphors were synthesized, and their photoluminescence properties, quantum yields, as well as thermal stabilities, were studied. Under near-ultraviolet excitations, the Eu~(3+) and Tb~(3+) -doped CLSPO compounds exhibited red and green emissions with high luminescence efficiencies. Besides, tunable emissions from green to orange were obtained by introducing Mn~(2+) ions into the Tb~(3+) -doped CLSPO samples. The results showed that the phosphors studied may have potential applications for w LEDs.