Structural Study of Inclusion Complex of Andrographolide with β-Cyclodextrin Prepared under Microwave Irradiation

Andrographolide (Andro) (Figure 1) is a diterpene lactone isolated from Andrographis paniculate Nees1. It has showed several biological activities including analgesic, antipyretic and anti-inflammatory effects2. However, its poor water solubility and unstability towards oxygen restrained its application. In pharmaceutics, b-CD is used to increase solubility and stability3. We have prepared the inclusion compound of Andro/b-CD (Figure 2) under microwave irradiation4. It has been found…     

晶体Sr_2Cu（HCOO）_6·8H_2O作为先驱物制备Sr_2CuO_2（C

应用ＳｒＣＯ３和ＣＵ（ＮＯ３）·３Ｈ２Ｏ从甲酸溶液中制备出晶体Ｓｒ２Ｃｕ（ＨＣＯＯ）６·８Ｈ２Ｏ，用这一晶体作为先驱物，石英管式炉中，８２５℃烧结六小时，得到单相的Ｓｒ２ＣｕＯ２（ＣＯ３）．通Ｎ２气体，８５０℃烧结十小时，得到Ｓｒ２ＣｕＯ３．Ｓｒ２ＣｕＯ２（ＣＯ３）是形成Ｓｒ２ＣｕＯ３的一种中间相．     

高纯度超导氧化物RuSr2GdCu2O8的合成与超导电性

RuSr2GdCu2O8据报道是转变温度为30－40K的超导体，其合成的主要问题是，在合成过程中有相当多的铁磁性的SrRuO3杂相伴随着主相一起生成，本文报道了合成RuSr2GdCu2O8（Ru-1212相）纯相的新方法，即在O2和水蒸气气氛中首先合成纯相的Sr2GdRuO6(Ru-211相）先驱物，然后Sr2GcRuO6与CuO高温烧结，生成RuSr2GdCu2O8。合成的RuSr2GdCu2O8电阻为半导体温度行为，该体系的超导转变与生成的杂相有关。     

γ——射线辐照从水溶液环境中制得金属超细粉的晶粒度和磁学性质

报道γ－射线辐照相应金属盐溶液制得金属镍超细粉及其晶粒度和磁学性质，所得产物的矫顽力和磁饱和强度比一般镍和其它方法制得的超细镍粉状或文献报道值大多得，进一步讨论了其磁学性质和晶业度与辐照剂量的关系。     

Bi2Sr2CaCu2-xLixOy体系的光电子能谱研究

采用X射线光电子能谱对Bi₂Sr₂CaCu_2-xLi_xO_y体系在真空中获得的清洁表面进行了研究。结果表明:Li的掺入对Bi和Sr的化学键性质几乎没有影响,而Ca,Cu,O的化学键性质有较大的变化,其结合能随着Li含量x的增加向高能方向移动。同时对真空中获得的清洁表面和普通表面样品O1s进行了比较,结果发现真空中获得的清洁样品O1s有一个峰(528.4eV),而普通表面样品O1s有两个峰(528.4eV)和(531eV),这表明O1s的高能峰是由污染产生的。 关键词：     

A Novel Synthesis of (-)-10-epi-α-Cyperone

The eudesmane derivative, (-)-10-epi-α-cyperone 1, is widely used as a chiral starting material for the synthesis of other fused-ring sesquiterpenes1. The first synthetic work was reported by Howe and co-workers via condensation of (+)-dihydrocarvone 2 with 1-diethylaminopentan-3-one methiodide in 32% yield2. Previously, our group reported the synthesis of compound 1 by treating ketone 2 with ethyl vinyl ketone (EVK) directly under different conditions1a, but the yields were not satisfacto…     

The Inclusion Interval of Basic Coneigenvalues of a Matrix

In this paper,a compound-type inclusion interval of basic coneigenvalues of(com- plex)matrix is obtained.The corresponding boundary theorem and isolating theorem are given.     

Gd掺杂的Bi系2212相单晶电子状态的X射线光电子能谱研究

利用X射线光电子能谱(XPS)研究了Bi系纯2212相超导单晶和Gd掺杂的2212相绝缘体单晶的电子状态的区别。实验结果表明Gd掺杂引起超导电性的变化是由于D_2p轨道空穴填充引起。本文还对Cu2p_3/2XPS卫星峰与主峰强度之比(I_s/I_m),Bi-O层性质以及Bi系Fermi能级附近态密度的来源等问题进行了讨论。 关键词：     

CONSTRUCTION OF SOLUTIONS TO M-D RIEMANN PROBLEMS FOR A2×2 QUASILINEAR HYPERBOLIC SYSTEM

ＣＯＮＳＴＲＵＣＴＩＯＮＯＦＳＯＬＵＴＩＯＮＳＴＯＭ－ＤＲＩＥＭＡＮＮＰＲＯＢＬＥＭＳＦＯＲＡ２×２ＱＵＡＳＩＬＩＮＥＡＲＨＹＰＥＲＢＯＬＩＣＳＹＳＴＥＭＣＨＥＮＳＨＵＸＩＮＧＭａｎｕｓｃｒｉｐｔｒｅｃｅｉｖｅｄＤｅｃｅｍｂｅｒ２６，１９９４．...     

Study on Phase-Formation Mechanism and Intergrowth for Bi(Pb)-Sr-Ca-Cu-O System

In this paper, the phase-formation mechanism of Bi-based superconductors was systematically investigated by using high-temperature X-ray diffraction, differential thermal analysis (DTA) and crystallization of amorphous state. The transformations among Bi-based 2201, 2212 and 2223 phases were observed, and the intergrown phenomenon of the 2201, 2212 and 2223 phases was explained. It was proposed that there exist a composition equilibrium between 2212 phase and Ca2CuO3 and a competition of thermody-namic stability among Ca2CuO3, 2212 and 2223 phases. This is why it is difficult to prepare the 2223 phase. After Pb was doped in Bi-Sr-Ca-Cu-O system, Ca2CuO3 phase in the Bi-Sr-Ca-Cu-O system was replaced by Ca2PbO4, so that the composition equilibrium and competition of thermodynamic stability mentioned above were avoided.