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建立了测定肉制品中甘草抗氧化物含量的方法。样品经流动相提取,采用C.8色谱柱分离,以甲醇-0.2mol/L乙酸铵-冰乙酸(体积比70:29:1)为流动相,流速为1.0mL/min,波长为250nm,以保留时间进行定性,峰面积进行定量。甘草酸在1.0-80.0μg/mL范围内线性关系良好,回归方程为y=8.55×10^-5x-0.599(r=0.9997),检出限为1.0mg/kg,定量限为3.0mg/kg,加标回收率为95.7%-103.4%,测定结果的相对标准偏差为1.57%-3.53%(n=6)。该方法适用于检验机构日常检验中大批量肉制品中甘草抗氧化物含量的测定。 相似文献
75.
以硝酸作为消解液,采用湿消解-电感耦合等离子体发射光谱法(ICP-AES)测定药用胶囊中的铬含量.在0~80 ng/mL范围内,铬的浓度与发射光强度呈良好的线性关系,相关系数r=0.999 98,检出限为1.42 ng/mL.对3个浓度水平的铬标准溶液进行平行测定,测定结果的相对标准偏差为1.43%~1.79%(n=6),加标回收率为93.1% ~110.0%.该方法可以用于药用胶囊中铬的日常检测. 相似文献
76.
浙北富硒土壤地球化学特征与生物学效应 总被引:2,自引:0,他引:2
通过对杭嘉湖平原富硒区研究,发现区内富硒土壤主要分布在环湖平原区,土壤具有特殊的地球化学性质,表现为土壤酸性,土壤硒全量0.3~0.5 mg/kg,有机质含量高、重金属含量低,土壤质地较黏重,土壤硒与有机质关系密切,而与土壤pH相关性不明显等特点。在土壤有机质丰富和氧化条件下,农产品中硒含量较高,重金属低于限量标准,具有较好的开发远景。 相似文献
77.
A new complex, [Ni3(L)2(BTA)2]·2H2O (1, L=1,4-di(1H-imidazol-4-yl)benzene, H3BTA=benzene-1,3,5-triacetic acid), has been hydrothermally prepared and characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, TG and PXRD. The complex crystallizes in monoclinic, space group P1 with a=9.0303(12), b=10.0796(13), c=12.7966(17) , α=99.268(2), β=94.490(2), γ=103.722(3)o, V=1108.5(3) 3 , Z=2, C48H38N8O14Ni3 , Mr=1126.99, Dc=1.688 g/cm3 , μ=1.344 mm-1 , S=1.001, F(000)=578, the final R=0.0389 and wR=0.0895 for 3083 observed reflections (I > 2σ(I)). In the title complex, the flexible BTA3- ligands utilize oxygen atoms of carboxylate groups to coordinate with Ni(II) ions to form two-dimensional double-layer networks which are further pillared into a three-dimension framework via the rigid ditopic ligand L. Topological analysis revealed that complex 1 is a typical (3,8)-connected tfz-d 3D network based on the trinuclear [Ni3(CO2)6N4] subunits. 相似文献
78.
建立了山茶油中黄曲霉毒素B1含量的高效液相色谱-串联质谱分析方法。通过对前处理方法的优化,选择了甲醇和水作为山茶油中黄曲霉毒素B1的提取溶剂,经免疫亲和柱富集浓缩后,采用高效液相色谱-串联质谱进行分析,经C18色谱柱分离,在电喷雾离子化正离子模式(ESI+)及多反应监测模式(MRM)下进行测定,基质匹配标准溶液外标法定量。在优化条件下,该方法线性范围为0.4~6.4μg/L,相关系数r2>0.998,最低检出限为0.026μg/kg,在添加水平为0.008,0.016和0.032μg时,方法回收率在85.9%~93.8%之间;相对标准偏差为1.8%~5.0%。方法可满足山茶油中黄曲霉毒素B1的检测要求。 相似文献
79.
In this paper, an extremely accurate numerical algorithm, namely the “clean numerical simulation” (CNS), is proposed to accurately simulate the propagation of micro-level inherent physical uncertainty of chaotic dynamic systems. The chaotic Hamiltonian Hénon–Heiles system for motion of stars orbiting in a plane about the galactic center is used as an example to show its basic ideas and validity. Based on Taylor expansion at rather high-order and MP (multiple precision) data in very high accuracy, the CNS approach can provide reliable trajectories of the chaotic system in a finite interval t ∈ [0, Tc], together with an explicit estimation of the critical time Tc. Besides, the residual and round-off errors are verified and estimated carefully by means of different time-step Δt, different precision of data, and different order M of Taylor expansion. In this way, the numerical noises of the CNS can be reduced to a required level, i.e. the CNS is a rigorous algorithm. It is illustrated that, for the considered problem, the truncation and round-off errors of the CNS can be reduced even to the level of 10−1244 and 10−1000, respectively, so that the micro-level inherent physical uncertainty of the initial condition (in the level of 10−60) of the Hénon–Heiles system can be investigated accurately. It is found that, due to the sensitive dependence on initial condition (SDIC) of chaos, the micro-level inherent physical uncertainty of the position and velocity of a star transfers into the macroscopic randomness of motion. Thus, chaos might be a bridge from the micro-level inherent physical uncertainty to the macroscopic randomness in nature. This might provide us a new explanation to the SDIC of chaos from the physical viewpoint. 相似文献
80.
Let R be a ring and 𝒲 a self-orthogonal class of left R-modules which is closed under finite direct sums and direct summands. A complex C of left R-modules is called a 𝒲-complex if it is exact with each cycle Z n (C) ∈ 𝒲. The class of such complexes is denoted by 𝒞𝒲. A complex C is called completely 𝒲-resolved if there exists an exact sequence of complexes D · = … → D ?1 → D 0 → D 1 → … with each term D i in 𝒞𝒲 such that C = ker(D 0 → D 1) and D · is both Hom(𝒞𝒲, ?) and Hom(?, 𝒞𝒲) exact. In this article, we show that C = … → C ?1 → C 0 → C 1 → … is a completely 𝒲-resolved complex if and only if C n is a completely 𝒲-resolved module for all n ∈ ?. Some known results are obtained as corollaries. 相似文献