新型N-甲氧基-N-苯基氨基甲酸酯类化合物的合成及生物活性研究

为了寻找高效、低毒的新农药,采用活性结构拼接法合成了含1H-1,2,4-三氮唑基的N-甲氧基-N-{2-[1-取代苯基-2-(1H-1,2,4-三氮唑-1-基)-1-丙酮]}苯基氨基甲酸甲酯化合物10个。所有的化合物都经^1H NMR、红外、LC／MS进行了表征。生测活性表明,部分化合物对小麦赤霉病、稻瘟病、黄瓜灰霉病、小麦白粉病有较好的抑菌活性。     

N-杂环甲基2-(4-杂芳氧基苯氧基)丙酰胺的合成及除草活性

以2-(4-羟基苯氧)丙酸为原料,设计合成了16个新的手性N-杂环甲基2-(4-杂芳氧基苯氧基)丙酰胺化合物,其化学结构经核磁共振、色谱-质谱、红外光谱及元素分析确证.初步生物活性测定结果表明,合成的化合物在2.25×103g/ha剂量时对单子叶杂草马唐(Digitaria sanguinalis)、稗草(Echinochloa crus-galli)及狗尾草(Setaria viridis)等均具有90%以上的活性;进一步活性及作物安全性测试表明,化合物(R)-(+)-N-[(6-氯吡啶-3-基)甲基]-2-[4-(3-氯-5-三氟甲基吡啶-2-基氧基)苯氧基]丙酰胺(2b)的除草活性高于噁唑酰草胺,且对水稻茎叶处理安全,同时对水稻田主要杂草千金子的活性远高于氰氟草酯;化合物的除草活性与立体构型有关,R构型为活性构型.     

基于不同核函数的非参数与参数利率模型的国债定价

以上海证券交易所的国债回购利率数据为样本,本文采用两种不同核函数:高斯核和抛物线核对非参数利率期限结构模型进行估计.结果显示:短期利率的密度函数是非正态的,扩散过程的漂移函数和扩散函数都是非线性的,高斯核比抛物线核对扩散函数拟合更平滑.然后,给出了基于非参数和参数利率模型的国债定价的方法,并对非参数利率模型、Vasicek模型、CIR模型、多项式样条静态模型进行国债定价预测比较与分析.     

Quantum Fisher information and spin squeezing in one-axis twisting model

We investigate the dependence of the average parameter estimation precision （APEP）, which is defined by the quantum Fisher information, on the polar angle of the initial coherent spin state ｜θ0,φ0〉 in a one-axis twisting model. Jin et al. [New J. Phys. 11 （2009） 073049] found that the spin squeezing sensitively depends on the polar angle θ0 of the initial coherent spin state. We show explicitly that the APEP is robust to the initial polar angle θ0 in the vicinity of π/2 and a near- Heisenberg limit 2IN in quantum single-parameter estimation may still be achieved for states created with the nonlinear evolution of the nonideal coherent spin states θ0- π/2. Based on this model, we also consider the effects of the collective dephasing on spin squeezing and the APEE     

Enhancement of Sensitivity by Initial Phase Matching in SU(1,1) Interferometers

We derive a general phase-matching condition(PMC) for enhancement of sensitivity in SU(1,1) interferometers. Under this condition, the quantum Fisher information(QFI) of two-mode SU(1,1) interferometry becomes maximal with respect to the relative phase of two modes, for the case of an arbitrary state in one input port and an even(odd) state in the other port, and the phase sensitivity is enhanced. We also find that optimal parameters can let the QFI in some areas achieve the Heisenberg limit for both pure and mixed initial states. As examples, we consider several input states: coherent and even coherent states, squeezed vacuum and even coherent states, squeezed thermal and even coherent states. Furthermore, in the realistic scenario of the photon loss channel, we investigate the effect of photon losses on QFI with numerical studies. We find the PMC remains unchanged and is not affected by the transmission coefficients for the above input states. Our results suggest that the PMC can exist in various kinds of interferometers and the phase-matching is robust to even strong photon losses.     

三元合金Ga0.52In0.48P的喇曼散射谱

采用室温下微区Raman散射方法,观测到了GaInP2的LO双模行为和禁戒的TO模,由于晶格有序导致晶体对称性从Td降低为C3v,从而使禁戒的TO模变为Raman活性。在所有的样品中都观测到了由晶格无序激活的DALA模。在有序样品中,除观测到二级Raman散射峰LO1＋LO2以外,还观测到了由超晶格效应所导致的FLA折叠模和LO模的分裂。对LO模峰谷b/a的分析表明,随着晶格有序度的增加,b/a值减小。这是因为：一方面主要是由于禁戒的TO模变为Raman活性所引起的,另一方面,还可能有LO1模和LO2模分裂的贡献。在实验上,可以用b/a值或FLA的强度来表示样品的有序度。     

Derivation of quantum Chernoff metric with perturbation expansion method

We investigate a measure of distinguishability defined by the quantum Chernoff bound, which naturally induces the quantum Chernoff metric over a manifold of quantum states. Based on a quantum statistical model, we alternatively derive this metric by means of perturbation expansion. Moreover, we show that the quantum Chernoff metric coincides with the infinitesimal form of the quantum Hellinger distance, and reduces to the variant version of the quantum Fisher information for the single-parameter case. We also give the exact form of the quantum Chernoff metric for a qubit system containing a single parameter.     

面积-容量-模不等式与填充Julia集的面积 献给杨乐教授80华诞

本文证明一般的面积-模不等式area(K)≤area(D)e~(-4π mod(A)),其中K是平面上满的正规紧集,D是包含K的有界单连通区域,区域A=D\K.上式等号成立当且仅当A是同心圆环区域.进一步,本文建立平面上满的正规紧集K的面积-容量-模不等式area(K)≤π cap(K)~2e~(2L-4π mod(Λ)),其中L是关于K的Green函数的最大临界值,Λ是K诱导的树(集合论中的树).上式等号成立当且仅当K是闭圆盘或mod(Λ)=∞.利用此不等式,本文得到d次首一复多项式f填充Julia集K(f)面积的最佳上界估计area(K(f))≤πe~(-(2qL)/(d-q-1)),其中L=max{G_f(c)|f′(c)=0},q为f在集合G_f~(-1)(L)\K(f)上的临界指数.     

XAFS研究Ni-P和Ni-Ce-P超细非晶合金的退火晶化

采用原子配位分布函数为Gaussian函数Ｐ_G和指数函数P_E直积的非 对称模型进行拟合计算,XAFS定量地研究化学还原法制备的Ni-P和Ni-Ce-P超细非晶合金大 无序度体系中Ni原子的局域环境结构随退火温度升高而产生的变化.结果表明Ni-P和Ni-Ce-P 原样的Ni-Ni配位的平均键长Ｒ_j、配位数N、热无序度σ_T、结构无 序度σ_S分别为0271nm,100,00060nm,0028n 关键词： XAFS Ni-P Ni-Ce-P 超细非晶合金 局域结构     

超几何光场态与二能级原子相互作用中原子反转的演化及光场的反聚束 …

研究作为二项式态单参数推广超几何态与二能级原子的强度耦合相互作用。讨论了原子反转的动力学演化以及光场的反聚束效应。