微波辅助溶剂提取法对土壤中残留苯并咪唑类农药的测定

报道了微波辅助溶剂提取、液 液分配净化、反相液相色谱 荧光法测定土壤中苯并咪唑类农药多菌灵、噻菌灵残留量的方法。对微波辅助溶剂提取的功率、时间、提取溶剂等操作条件进行了研究。以2mol LNH4Cl溶液、乙醇为提取液,在240W微波功率,提取时间1min的优化操作条件下,方法的回收率为89%～99%,相对标准偏差为3%～10%,方法的最低检出质量浓度多菌灵为3 63×10-4mg L,噻菌灵为5.20×10-5mg L,最小检出量多菌灵为1.21×10-11g,噻菌灵为1.74×10-12g。     

Separation of chiral phosphorus compounds on the substituted P-cyclodextrin stationary phase in normal-phase liquid chromatog-raphy

The separation of enantiomers of a series of eighteen novel nitrogen mustard linked phosphoryl diamide derivatives was investigated on the prepared phenyl carbamate derivative β-cy-clodextrin bonded phase in normal-phase HPLC. Some of the enantiomers could be separated in baseline. The chiral recognition mechanism was also suggested for the separation of chiral phosphorus organic compounds.     

Synthesis and electroluminescent properties of naphthalimide derivatives

Naphthalimide derivatives, N-ethyl-4-acetylamino-l ,8-naphthalimide (EAAN) and polymer with N-propyl-4-acetylamino-l,8-naphthalimide (PAAN) side-chain (P-PAAN) were successfully synthesized. Electroluminescent devices of ITO/PVK(120nm)/EAAN(50nm)/Al(150nm) (Ⅰ) and ITO/PVK P-PAAN( 10:1) (50nm)/Al(150nm) (Ⅱ) constructed with EAAN and P-PAAN as the emitting layer were investigated, whereas the single-layer devices of ITO/EAAN or P-PAAN(50nm)/Al(l50nm) (Ⅲ) were not observed to have any e-mission light. The emission results revealed that the exciton recombination formed by positive and negative charge carriers injected from electrodes of devices Ⅰ and Ⅱ was much more balanced than that of devices Ⅲ, which implied that naphthalimide derivatives are a new type of electron-transporting materials with high performance. The electron-transporting properties of naphthalimide derivatives were also elucidated by investigation of the electroluminescent behaviors from both devices of ITO/PPV (80nm)/Al and ITO/P     

An efficient Jacobian scaling method for time-domain optical mammography

<正>Time-domain diffuse optical tomography can efficiently reconstruct optical parameters which can be further applied in diagnosing early breast cancer.Nevertheless,the performances of reconstructed imaging are badly influenced by different Jacobian magnitudes of absorption coefficient and reduced scattering coefficient.With the introudction of a relative data type based on generalized pulse spectrum technique, an efficient Jacobian scaling method is proposed.The interrelated simulated validation is also revealed for the enhancing performances.     

Core-shell fibrous vascular grafts with the nitric oxide releasing property

Small-diameter vascular grafts with the nitric oxide(NO) releasing property were designed and prepared.Diazeniumdiolated N,N'-dibutyl-1,6-hexanediamine(DBHD/N2O2) was first synthesized as the NO donor and doped into the biocompatible polymer poly(ε-caprolactone)(PCL).The fibrous vascular grafts were fabricated by electrospinning.Despite the reduced platelet adhesion observed on the NO releasing grafts,the cytotoxicity and burst release were apparent,especially at a higher loading level of the NO donor.In or...     

作用在有限线性空间上基柱为F_4(q)的几乎单群

线传递线性空间可以分为非点本原和点本原两种情形,而点本原的情况又可以分成基柱为初等交换群或非交换单群两种情形.本文考虑后一种情形,即T是非交换单群,T≤G≤Aut(T)且G线传递,点本原作用在有限线性空间上的情形.证明了当T同构于F_4(q)时,若T_L不是~2F_4(q),B_4(q),D_4(q).S_3,~3D_4(q).3,F_4(q~(1/2))和T的抛物子群的子群时,T也是线传递的,这里q是素数p的方幂.     

谐衍射/折射双波段系统设计

将谐衍射透镜成功地引入红外凝视阵列探测器双波段系统的设计中,使系统在3．7～4．3μm的中波红外和8．7～11．5μm的长波红外波段同时较好的完成了像差校正。光学传递函数在两个波段范围内,在18lp／mm时的归一化值均大于0．5,接近衍射极限。该系统具有100％冷光栏效率。设计结果表明,谐衍射透镜的光谱特性介于折射透镜与衍射透镜之间,色散大小可以控制,降低了对工艺水平的要求,使红外双波段系统结构紧凑,透镜组片数少、分辨率高。为红外光学设计提供了一种全新的器件。     

利用普通色散位移光纤得到的超宽带超连续谱

对实验中观察到的超连续谱（SC）演变过程进行了理论分析.在泵浦光平均功率55 mW时,利用普通色散位移光纤得到SC谱从1311 nm到1780 nm的展宽.其中泵浦波长右侧196 nm范围内的光谱不平坦度＜±1 dB.利用F-P进行谱切片,在泵浦波长右侧和左侧分别得到92个和46个顶部平坦的信道.将色散位移光纤长度缩短到100 m时,还得到了SC谱20 dB带宽453.3 nm的实验结果,实现了无缝覆盖S带、C带、和L带.     

溶液近红外光谱分析中温度影响的修正

作为一种快速、无损的分析技术,近红外光谱分析在许多领域中被广泛应用,其中液体样品是其应用最为广泛的分析对象之一.由于水等常用溶剂在近红外波段的温度敏感性极高,因而不能忽视温度对溶液的近红外光谱测量带来的影响.文章以朗伯-比尔定律为基础,在理论上推导出了温度变化对溶液透射光谱的影响,并提出利用纯溶剂在不同温度下的吸光度变化量作为温度校正量,对样品光谱进行修正.文章还在不同温度下,对葡萄糖水溶液和白蛋白水溶液进行了光谱测量,建立了30℃下的校正模型,并以纯水的吸光度变化量为温度校正量,将不同温度下的预测样品光谱修正至对应于30℃的光谱.实验结果表明,对光谱进行温度修正后,有效消除了温度对光谱的影响,葡萄糖和白蛋白的浓度预测误差得到了明显的降低.     

新型单分散血清白蛋白印迹微球的制备

以猪血清白蛋白（PSA）为模板,采用分级印迹方法,制备了新型单分散多孔蛋白质表面印迹微球．将PSA吸附在5gm粒径、1000A孔径的球形硅胶表面及孔内后,将甲基丙烯酰胺、甲基丙烯酸为功能单体、甲又双丙烯酰胺为交联剂的聚合物溶液,通过真空负压引入到硅胶孔内,并在室温下聚合24h．反应完成后,用3mol／L NH4HF2刻蚀硅胶,获得形状和结构与硅胶颗粒互补的PSA印迹聚合物微球．竞争吸附实验结果表明,在非模板蛋白质存在的情况下,实现印迹颗粒对模板蛋白的高选择性吸附,选择因子达到3．6,说明该印迹聚合物材料有望成为一种可以同生物抗体相媲美的新型亲和材料．