排序方式: 共有114条查询结果,搜索用时 250 毫秒
71.
通过HgX2 (X=I,Br)与4,4’-二吡啶基二硫化物(dpds)在乙腈中的溶剂热反应,得到二个含1-(4-吡啶基)-吡啶铵-4-硫醇盐(ppt)的-维配位聚合物:[Hg2I4(ppt)]n(1)和[Hg2Br4(ppt)]n(2).在化合物1和2结构中ppt配体是由dpds在溶剂热反应条件下通过dpds的S-S键和S-C键切断然后进行重排在原位形成的.化合物1具有非中心对称的-维Z字型链状结构,化合物2则具有中心对称的-维Z字型链状结构.用飞秒简并四波混频法测定了1和2溶液的三阶非线性光学性质,化合物1具有较强的非线性光学响应,而化合物2却没有非线性光学响应,这种性质的差异可能由于碘离子是较溴离子更好的电子授体,化合物1有较小的HOMO-LUMO能级,更易发生电子在体系间跃迁,更有效使用三线激发态吸收. 相似文献
72.
90年代以来 ,人们先后发现了吡咯甲川- BF2化合物在许多领域的重要应用价值 ,如染料激光领域 ,与传统的香豆素、罗丹明及多甲川菁类化合物相比 ,它们具有激光效率高、光稳定性好、溶解度合适等无可比拟的优点 [1~ 3],目前已有数种商品染料问世 .在有机固体激光领域 ,将它们和以 PMMA等为基质的高分子材料掺杂后,得到的固体激光材料拥有相当高的能量转换效率和使用寿命 [4~ 6],经过合理的结构改造 ,在激光医学领域也获得了一类极具开发潜力的用于肿瘤的激光光动力疗法( photodynamic therapy)的吡咯甲川- BF2型新型光敏药物 ,据… 相似文献
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1,3,5,7-四甲基-2,6,8-三乙基吡咯甲川-BF2络合物的合成及晶体结构 总被引:1,自引:1,他引:0
合成了标题化合物 ,借助于元素分析、红外光谱、核磁共振氢谱、质谱以及X 射线单晶衍射等分析方法确定了它的结构。该化合物属于三斜晶系 ,空间群为P-1(No 2 ) ,化学式 :C19H2 7BF2 N2 。晶胞参数 :a =1 2 2 5 7( 2 ) ,b=1 7830 ( 8) ,c=0 8877( 2 )nm ,α =10 0 2 6 ( 2 ) ,β =10 7 5 7( 1) ,γ =76 96 ( 2 )°,V =1 7892( 9)nm3 ,Mr=332 2 4,Z =4,Dc=1 2 33g·cm-3 ,μ(MoKα) =0 86cm-1,F( 0 0 0 ) =712 0 0 ,R =0 0 5 1,Rw=0 0 6 0。化合物中除 2 ,6 ,8位的三个甲基 (C( 12 ) ,C( 15 ) ,C( 18) )和氟原子 (F( 1) ,F( 2 ) )外 ,其余非氢原子近似组成一个大平面结构。在对其晶体结构进行详细分析的基础上 ,我们还初步讨论了它的分子结构与光谱及激光性能的关系。 相似文献
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自行搭建的自锁模钛宝石激光器工作在下稳区的上边界附近,采用熔融石英棱镜对在激光器谐振腔的腔内和腔外同时进行群速度色散补偿.随着腔内棱镜对提供色散补偿的变化,输出激光脉冲的频谱会突然展宽至664—840nm,其空间模式也由基横模变化至衍射环状结构,这是受激拉曼散射和四波混频效应导致锁模激光脉冲频谱进一步展宽的结果.在此状态下自锁模钛宝石激光器可实现670—865nm范围的波长调谐.如此宽的频谱为钛宝石激光器产生亚10fs激光脉冲提供了必要的条件.
关键词:
飞秒激光脉冲
受激拉曼散射
四波混频
群速度色散 相似文献
76.
掺杂在晶体Y2 SiO5(YSO)中的Pr3 ,运用脉冲激光激发 3H4 → 1 D2 跃迁 ,粒子通过非辐射能量转移从能级 1 D2 转移到能级 3P0 ,测得了对应于 3P0 → 3H4 跃迁的反斯托克斯荧光光谱 ,由此可确定 3H4 的Stark分裂能级以及 3P0 能级的能量高度。与运用激光激发 3H4 → 1 D2 跃迁 ,通过观察 1 D2 → 3H4 斯托克斯荧光光谱确定3H4 的Stark分裂能级方法相比 ,该过程避免了不同晶点位置中 (Crystallographicsite)Pr3 的 1 D2 能级间的能量转移影响 ,从而具有较高的确定性。同时 ,我们观察了反斯托克斯荧光的时间特性 相似文献
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We study theoretically intense terahertz radiation from multi-color laser pulse with uncommon frequency ratios. Comparing the two-color laser scheme, of which the uncommon frequency ratio should be set to be a specific value, we show that by using multi-color harmonic laser pulses as the first pump component, the lasers as the second pump component can be adjusted in a continuous frequency range. Moreover, these multi-color laser pulses can effectively modulate and enhance the terahertz radiation, and the terahertz yield increases with the increase of the wavelength of the uncommon pump component and is stable to the laser relative phase. Finally, we utilize the electron densities and velocities of ionization events to illustrate the physical mechanism of the intense terahertz generation. 相似文献
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Six novel pyrromethene BF2 complexes,of which five compounds have not been reported,were synthesized and characterized.Their relationships between st ructure and photophysical behavior were studied with the aid of fluorescence and triplet state absorption spectra.The results indicate that,compared to 8 alkyl pyrromethene BF2 complexes,the compounds containing 8 aryl exhibit high fluore scence quantum yield and rather low triplet state absorption. 相似文献
80.
Selective excitation and suppression of coherent anti-Stokes Raman scattering by shaping femtosecond pulses 下载免费PDF全文
Femtosecond coherent anti-Stokes Raman scattering (CARS)
suffers from poor selectivity between neighbouring Raman levels
due to the large bandwidth of the femtosecond pulses. This paper
provides a new method to realize the selective excitation and
suppression of femtosecond CARS by manipulating both the probe and
pump (or Stokes) spectra. These theoretical results indicate that
the CARS signals between neighbouring Raman levels are
differentiated from their indistinguishable femtosecond CARS spectra
by tailoring the probe spectrum, and then their selective excitation
and suppression can be realized by supplementally manipulating the
pump (or Stokes) spectrum with the $\pi $ spectral phase step. 相似文献