Dynamic Ni gettered by PSG from S-MIC poly-Si and its TFTs

A dynamic phosphor-silicate glass （PSG） gettering method is proposed in which the processes of the gettering of Ni by PSC and the crystallizing of α-Si into poly-Si by Ni take place simultaneously. The effects of PSC gettering process on the performances of solution-based metal induced crystallized （S-MIC） poly-Si materials and their thin film transistors （TFTs） are discussed. The crystallization rate is much reduced due to the fact that the Ni as a medium source of crystallization is extracted by the PSC during crystallization at the same time. The boundary between two neighbouring grains in S-MIC poly-Si with PSG looks blurrier than without PSG. Compared with the TFTs made from S-MIC poly-Si without PSC gettering, the TFTs made with PSC gettering has a reduced gate induced leakage current.     

透射电子显微术和高分辨X射线衍射技术研究AlN单晶生长习性

采用透射电子显微术和高分辨X射线衍射技术对氮化硼坩埚中自发成核的AIN单晶生长习性进行了研究.结果表明,在低温下,AIN单晶显露面为(0001)面,随着温度的升高,AIN单晶显露面转化为(1120)面.沟槽结构是高温下得到的AIN单晶共有的显著特征,其取向沿[0001]方向.     

The parameters of binary black hole system in PKS 1510-089

Observations of PKS 1510-089 indicate the existence of a deep flux minimum with a timescale of \sim 35 min and an interval of about 336±14 d. A binary black hole system is proposed to be at the nucleus of this object. The secondary black hole orbits around the primary black hole. The minimum is caused by the periodic eclipse of the primary black hole by the secondary black hole. Based on the observations of PKS 1510-089, we estimate the parameters of the binary black hole system. The masses for the primary and secondary black holes are 1. 37×10⁹M_{\odot} (M_{\odot} is the solar mass) and 1. 37 \times 10⁷M_{\odot} , and the major axis for this pair being about 0.1 parsec(pc).     

D-酒石酸正辛酯的合成

以D-酒石酸和正辛醇为原料合成了手性拆分剂D-酒石酸正辛酯,其结构经IR确证。通过正交实验得优化反应条件为：D-酒石酸100mmol,n(D-酒石酸)：n(正辛醇)=1．0：2．8,对甲苯磺酸0．5g,甲苯55mL,慢速搅拌,酯化率在98％以上,收率达90％。     

12-钨硼酸5-氟尿嘧啶盐的合成及抗癌活性研究

5-氟尿嘧啶(5-Fu)是一种阻止肿瘤细胞嘧啶类核苷酸合成的抗代谢药物,对多种肿瘤有较好的疗效.但该药首次代谢效应显著,毒副作用较大,且治疗剂量与中毒剂量接近,使其临床应用受到一定限制.为降低毒性,提高其活性,人们从多方面对5-Fu进行化学修饰,设计合成出许多新药^[1～4].近年来,多金属氧酸盐因结构独特,在抗病毒、抗肿瘤等方面的应用已引起人们的广泛重视^[5～7].王晓红等^[8,9]曾先后报道了杂多钨酸盐的体内、外抗肿瘤活性.多金属氧酸具有较强的接受电子的能力^[10],能与含有N,S和O原子的有机基质作用形成新型化合物^[11～14].     

锦灯笼中无机元素含量测定

采用ＩＣＰ－ＡＥＳ法检测了要笼果实及其干燥宿萼中无机元素含量。结果表明,锦灯笼含有丰富的对人体有益的无机元素,具较高的营养价值。     

Large-scale photonic crystals with inserted defects and their optical properties

Deliberately introducing defects into photonic crystals is an important way to functionalize the photonic crystals. We prepare a special large-scale three-dimensional(3D) photonic crystal(PC) with designed defects by an easy and low-cost method. The defect layer consists of photoresist strips or air-core strips. Field emission scanning electron microscopy(FESEM) shows that the 3D PC is of good quality and the defect layer is uniform. Different defect states shown in the ultraviolet-visible spectra are induced by the photoresist strip layer and air-core strip layer. The special large-scale 3D PC can be tested for integrated optical circuits, and the defects can act as optical waveguides.     

二茂铁修饰Aβ疏水段五肽的电化学性质及自组装研究

五肽Lys-Leu-Val-Phe-Phe(即KLVFF)是β-淀粉样肽(Aβ)疏水核心片段,其自组装方式对Aβ的聚集具有重要影响。在本文中,首先对二茂铁修饰的五肽,即Fc-Lys(Z)-Leu-Val-Phe-Phe-OMe(简称Fc-KLVFF)的电化学性质进行了研究,结果表明,在0.4~0.8 V范围内出现了一对可逆的氧化还原峰,氧化峰和还原峰电位分别为0.626和0.544 V,峰电位之差ΔEp为82 mV,峰电流密度之比Ipa/Ipc为1.08,扩散系数D0=1.784×10-6cm2.s-1。其次通过TEM观察到Fc-KLVFF在甲醇溶液中自组装成纳米管,傅里叶红外光谱分析表明纳米管的二级结构主要为β-折叠,紫外-可见和荧光光谱证实苯丙氨酸残基芳香环之间的π-π堆积作用在其自组装成纳米管时起着重要作用。最后提出了Fc-KLVFF的自组装机理模型。     

松香基甜菜碱两亲分子构筑多维Ni(OH)2/NiOOH微纳米复合材料

采用自制脱氢松香基甜菜碱功能性两亲分子构筑得到3种形貌均匀的Ni(OH)₂/NiOOH微纳米复合材料, 分别为孔径约2 μm的三维珊瑚状、花状空心微球和宽度约100 nm的二维纳米片, 对复合材料的物相组成和形貌结构采用X射线衍射(XRD)、扫描电镜(SEM)和透射电镜(TEM)等技术手段分析表征。结合自制松香基甜菜碱两亲分子红外光谱(FT-IR)、核磁(NMR)结构表征和优异的表面活性推测得到松香基甜菜碱两亲分子构筑3种不同形貌微纳米复合材料的机理;研究表明, 在松香基甜菜碱两亲分子稳定刚性结构的作用下, 通过反应温度控制其吸附能力可构筑出3种形貌分散性较好的氢氧化镍复合材料。     

气相色谱-质谱法测定大鼠血浆和肝匀浆中丙二醛含量

提出了用气相色谱-质谱法测定大鼠血浆和肝匀浆中丙二醛(MDA)含量。样品与1.0mol.L-1氢氧化钠溶液在60℃水浴中反应60min产生丙二醛,加入五氟苯肼(PFPH)衍生化试剂进行衍生化,所得衍生化产物通过HP-5MS色谱柱分离,采用电子轰击离子源选择离子监测模式进行质谱测定。丙二醛-五氟苯肼衍生物(MDA-PFPH)定量离子为m/z 234,内标物甲基丙二醛衍生物(Me-MDA-PFPH)定量离子为m/z248。血浆和肝匀浆中丙二醛的线性范围分别为1.0～50.0μmol.L-1和50～500μmol.L-1,加标回收率分别在94.6%～103%和93.2～106%之间。方法的日内、日间相对标准偏差(n=6)均小于5%。