共查询到19条相似文献,搜索用时 62 毫秒
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苯丙共聚物-聚硅氧烷复合固相微萃取涂层的制备及性能研究 总被引:4,自引:0,他引:4
合成了苯乙烯-丙烯酸乙酯共聚物,以此聚合物与甲基聚硅氧烷色谱固定液混合作为固相微萃取头涂层。通过热分析手段考察了该涂层的热稳定性,涂层使用温度可达280℃。使用微量进样器和不锈钢毛细管,自制了SPME装置。使用该涂层萃取分析了水中氯苯系化合物,各标准样品质量浓度在0—20μg/L内与色谱峰面积呈良好线性关系(r=0.9674—0.9934),检出限为0.28—0.64ng/L,相对标准偏差为5.4%-7.7%,加标回收率为91%-99%。将自制涂层与商品涂层(PDMS、PA)进行了比较,结果表明苯丙聚合物-甲基聚硅氧烷复合涂层对氯苯系化合物具有优良的吸附特性。在固相微萃取研究和应用中,提供了新的吸附物质和色谱固定液与石英纤维结合的新途径。 相似文献
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合成了几种新型的含氯丙基的取代聚硅氧烷,其热稳定性可达300~325℃,能较好地分离非极性和中等极性化合物。当固定相的苯基含量高达50%时,用8%的DCP能使其有效交联。 相似文献
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四-(对甲基苯基)-卟啉柱前衍生固相萃取富集高效液相色谱法测定烟草中痕量铅、镉、汞 总被引:13,自引:0,他引:13
研究了用四-(对甲基苯基)-卟啉柱前衍生、固相萃取富集、高效液相色谱法测定烟草中痕量Pb、Cd、Hg的方法。烟草样品用微波消化后,用四-(对甲基苯基)-卟啉(T4MPP)柱前衍生,用Waters Sep-Park-C18固相萃取微柱萃取富集Pb、Cd、Hg的T4MPP络合物,富集倍数为50倍;然后用甲醇(内含0.01mol/L四氢吡咯-醋酸缓冲盐(pH=10))和四氢呋喃(内含0.01mol/L四氢吡咯-醋酸缓冲盐(pH=10))梯度洗脱为流动相,Waters Xterra TM RP18(3.9(150)色谱柱为固定相分离,用二极管矩阵检测器检测;Pb、Cd、Hg的含量在1-120ug/L范围内与峰面积呈线性关系,根据信噪比(S/N=3),方法检测限为:Pd0.3ug/L,Cd0.5ug/L和Hg0.3ug/L,方法相对标准偏差为2.6%-4.1%,标准回收率为91%-107%,该方法用于测定烟草中的Pb、Cd、Hg,结果令人满意。 相似文献
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Dipika Debnath Sarkar Rahul Deb Nirmalangshu Chakraborty Golam Mohiuddin Rahul Kanti Nath 《Liquid crystals》2013,40(4):468-481
Chiral unsymmetrical dimeric liquid crystals consisting of a cholesterol moiety as chiral entity and a substituted salicylidene imine core (with the substituent being butyl or fluoro or chloro group) interconnected through an even methylene spacer have been synthesised and their mesomorphic properties are characterised. All the dimers exhibit enantiotropic mesophases. The butyl homologue exhibited N* phase only, the fluoro- and chloro-substituted compound exhibited frustrated blue phases (BPs), N* phase and SmC* or twisted grain boundary (TGB) phases. The occurrence of a fluid frustrated phase, the BP, in particular, observed in compounds with a polar moiety and bent optimised conformation by density functional theory (DFT) study, indicates the importance of polar structures and bent shape of the compounds. Theoretical calculation was performed in order to study the optimised conformation, polarity and electron density distribution of the synthesised cholesterol derivatives using DFT. Time-dependent density functional theory (TD-DFT) calculation also had been carried out to investigate the absorption spectra and HOMO–LUMO energies. The experimental and theoretical absorption spectra are also presented. 相似文献
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Elian M. Masnada Grégoire Julien Didier R. Long 《Journal of Polymer Science.Polymer Physics》2014,52(6):419-443
We study a Gibbs free energy model for describing the thermodynamics of compressible polymer blends in the case of nonpolar polymers. This model is a mean field model equivalent to the cell model of Prigogine et al. and close also to the model by Flory‐Orvoll and Vrij. The model is expressed as a function of the interaction energies between monomer pairs (a, b, and c), the degrees of polymerization (XA and XB), a close packing parameter ρ0, the temperature, and the pressure. We derive an analytical expression regarding blend miscibility. All the already observed phase behaviors are recovered: the occurrence of two kinds of upper critical solution transition (UCST): case‐I and case‐II UCST for which the pressure has a destabilizing or stabilizing effect, respectively, and lower critical solution transition; cases where the pressure have a non‐monotonous effect on the UCST temperature; cases where the spinodal lines close up under high pressures; and the so‐called hour‐glass transition. The model allows for making explicit the effect of the different physical parameters on phase behavior. We calculate complete miscibility maps regarding the occurrence of the various possible kinds of transitions in the 2D space b/a and XA, for different values of , applied pressure P, and chain length ratios. This approach may come as a complement to already existing, more quantitative and elaborated approaches. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2014 , 52, 419–443 相似文献
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本文通过共沉淀工艺合成了系列陶瓷化合物Nd0.67M0.33MnO3(M=Mg,Ca,Sr,Ba)。与传统的陶瓷法相比,其成相温度降低了400℃。经X射线衍射分析表明,所得化合物为立方钙钛矿结构,各化合物的成相温度范围受碱土二价金属离子(M2+)的影响。样品的四极法电阻率测试结果表明:M2+的离子半径对样品的导电性起决定作用,并提出了反铁磁性(AF)与铁磁性(AF)等磁性结构假设,解释了该系列化合物的导电性。 相似文献
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Hassen-Chehimi Dalila Ben Kbir-Ariguib Najia Trabelsi-Ayedi Malika 《Journal of Thermal Analysis and Calorimetry》1998,53(3):871-882
A previously established equation of a stoichiometric phase liquidus curve was applied to determination of the phase diagrams
of the systems MIPO3-Pr(PO3)3 (with MI=Na, Rb, Cs or Ag).
The temperature, enthalpy and entropy of fusion were calculated for each solid phase with the exception of silver polyphosphate,
the crystallization field of which was very limited.
The enthalpy of fusion of the polyphosphate Pr(PO3)3 was determined from the DTA curve.
The melting enthalpy of Pr(PO3)3 calculated from the different binary systems was approximately equal to the measured value. The calculated temperatures and
compositions were in good agreement with those determined experimentally.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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The conditions of stability for weakly charged polyelectrolyte mixtures are analyzed from a scattering theory developed previously. In the thermodynamic limit of zero wave vector q = 0, it is found that electrostatic interaction induces a compatibility enhancement which is discussed for various cases of charge distributions. The condition of microphase separation transition at the wave vector for which the scattering is a maximum is also discussed. © 1993 John Wiley & Sons, Inc. 相似文献
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The synthesis is described of four new chiral liquid crystalline monomers (M2–M5 ) and their corresponding side‐chain homopolysiloxanes (P2–P5 ) containing menthyl groups. Chemical structures were characterised using FT‐IR or 1H NMR spectra, and specific optical rotations were evaluated with a polarimeter. The phase behaviour and mesomorphic properties of the new compounds were investigated by differential scanning calorimetry, thermogravimetric analysis, polarising optical microscopy, UV/visible/NIR spectrocopy and X‐ray diffraction. The monomers and homopolymers with more aryl segments showed noticeably lower specific optical rotation value. The monomers M2–M5 formed a cholesteric or blue phase when a flexible spacer was inserted between the rigid mesogenic core and the terminal menthyl groups by reducing the steric effect. M2–M5 revealed enantiotropic cholesteric phase. Moreover, M2 also exhibited a monotropic smectic A (SmA) phase, and M4 also exhibited a cubic blue phase on cooling. The selective reflection of light shifted to the long wavelength region with increasing rigidity of the mesogenic core for M2–M5 . P2–P5 exhibited SmA phases, and the mesogenic moieties were ordered in smectic orientation with their centres of gravity in planes. Melting or glass transition temperature and the clearing temperature increased, and the mesophase temperature range widened with increasing rigidity of the mesogenic core. 相似文献
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含薄荷基的手性液晶单体的合成、结构与性能研究 总被引:1,自引:0,他引:1
合成了五种新型含薄荷基的手性单体(M1~M5), 它们的结构、纯度及旋光性质通过了1H NMR, FT-IR、元素分析仪及旋光仪等手段的表征, 采用DSC, POM, UV/Vis/NIR等研究了单体的介晶性能、相行为及选择反射性能. 结果表明: 单体的比旋光度值随苯环数目的增加而降低, 通过在薄荷基与液晶核之间引入柔性间隔基元, 实现了含薄荷基单体具有液晶性能的目的. 除M1外, 其余四种单体均呈现手性近晶C (SC*)相和胆甾(Ch)相, 此外M5还出现了蓝相织构. M2~M4只在SC*相区能观察到选择反射现象, 而M5在SC*相区和Ch相区均出现明显的选择反射现象, 且随温度的升高, SC*相区的反射波长发生“红移”, 而Ch相区的反射波长则发生“蓝移”. 随着液晶核刚性的增加, 对应单体的熔点和清亮点增大, 液晶相范围变宽. 液晶核中的酯基桥键与组合方式也对单体的熔点和清亮点具有一定的影响. 相似文献
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Hayriye Aral Duygu Haşimi Abdulkadir Levent Berrin Ziyadanoğullari 《液相色谱法及相关技术杂志》2017,40(11):549-555
In this study, some plant growth regulators known as cytokinins [kinetin (K), zeatin (Z), thidiazuron (TDZ), benzylaminopurine (BAP), and dimethylallylaminopurine (AAP)] were separated by HPLC using an amide-embedded mixed-mode stationary phase which was synthesized by Aral et al. in recent years. The effect of mobile phase content, mobile phase pH, buffer concentration, and temperature on separation process was studied. In addition, a quantitative determination of cytokinins from Salvia limbata extract was studied, and some validation parameters such as limit of detection (LOD), limit of quantification (LOQ), and relative standard deviation (RSD) were calculated as a range of 0.03–0.1, 0.1–0.26?mg/L, and 0.03–0.08, respectively. 相似文献
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Simplicity, effectiveness, swiftness, and environmental friendliness – these are the typical requirements for the state of the art development of green analytical techniques. Liquid phase microextraction (LPME) stands for a family of elegant sample pretreatment and analyte preconcentration techniques preserving these principles in numerous applications. By using only fractions of solvent and sample compared to classical liquid–liquid extraction, the extraction kinetics, the preconcentration factor, and the cost efficiency can be increased. Moreover, significant improvements can be made by automation, which is still a hot topic in analytical chemistry. This review surveys comprehensively and in two parts the developments of automation of non-dispersive LPME methodologies performed in static and dynamic modes. Their advantages and limitations and the reported analytical performances are discussed and put into perspective with the corresponding manual procedures. The automation strategies, techniques, and their operation advantages as well as their potentials are further described and discussed. 相似文献