铌酸锶钠锂单晶电光、热电、介电和压电性能

文本研究了用提拉法生长的铌酸锶钠锂(Sr₄NaLiNb₁₀O₃₀)晶体的电光、热电、介电和压电性能。其半波电压与温度的关系与晶体中锂含量密切相关。测得其室温下的热电系数与Ba～0.5的Sr_1-xBa_xNb₂O₆晶体相当,～7×10^-8C/cm²·K。已极化的晶体几乎检测不到退极化现象。将其作成热电器件,其探测度D^*不小于1.7×10⁷Hz^1/2·cm/W。文中还描述了其介电和某些压电性能。 关键词：     

发光二极管用红色荧光粉Sr0.8-xBaxEu0.2WO4的制备和性质研究

采用化学共沉淀法制备了不同Ba²⁺掺杂浓度、 不同煅烧温度的Sr_0.8-xBa_xEu_0.2WO₄红色荧光粉. 研究了样品的晶体取向和晶格 畸变对发光性质的影响, 实验结果表明: 合成的Sr_0.8-xBa_xEu_0.2WO₄红色荧光粉为四方相, 样品中Eu³⁺的⁵D₀–⁷F₂跃迁的红光能被近紫外光和蓝光有效激发. 适量的Ba²⁺离子取代部分的Sr²⁺提高了Sr_0.8Eu_0.2WO₄荧光粉的发光强度, Ba²⁺掺杂浓度的改变对基质的晶格参数、晶体对称性和发光性能影响较大, Ba²⁺的最佳掺杂量为30%.     

Sr位Nd掺杂对SrBi$lt;sub$gt;2$lt;/sub$gt;Nb$lt;sub$gt;2$lt;/sub$gt;O$lt;sub$gt;9$lt;/sub$gt;性能的影响及机理研究

采用传统固相法制备了（Sr_1-3x/2A_x/2Nd_x）Bi₂Nb₂O₉（x=0,0.05,0.1和0.2）陶瓷,并系统研究了Nd离子取代Sr离子对SrBi₂Nb₂O₉性能的影响及其作用机理.研究结果表明：Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉的介电常数和介电损耗随温度变化的行为具有明显的离子松弛极化特征.Nd³⁺对Sr²⁺的部分取代,导致Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉剩余极化强度P_r稍有下降,但其压电系数d₃₃却有所增加,根据铁电热力学理论,这是Nd³⁺对Sr²⁺取代导致材料介电常数增大所致.Sr_1-3x/2A_x/2Nd_xBi₂Nb₂O₉的居里温度（T_C）没有随Nd含量的增加而变化,拉曼光谱技术分析表明这是其NbO₆八面体畸变程度没有发生变化所致.Nd³⁺取代Sr²⁺提高了材料的介电常数ε_r、压电系数d₃₃、机电耦合系数K_p,同时降低了机械品质因数Q_m,但是谐振频率温度系数C值没有改变. 关键词： 压电陶瓷 介电性能 压电性能 拉曼光谱     

铁电-顺电扩散相转变的实验和统计模型

制备了扩散相转变铁电陶瓷系列(Ba_1-xLa_x)(Ti_1-yZr_y)O₃和扩散-非扩散相变铁电单晶系列K_0.2Na_0.2(Sr_pBa_1-p)_0.8Nb₂O₆。陶瓷采用一般铁电陶瓷制备工艺,单晶采用提拉法生长。测量了所有样品在-50—100℃范围内 关键词：     

Sr2+掺杂荧光粉Ca2Nb2O7：Eu3+的发光特性

采用高温固相法制备出Ca_1.97-xSr_xNb₂O₇：3%Eu³⁺（x=0.10,0.50,1.0,1.5,1.97）红色荧光粉,研究了Ca_1.97-xSr_xNb₂O₇：3%Eu³⁺的发光特性及Sr²⁺的浓度对该荧光粉发光性质的影响。随着Sr²⁺浓度的改变,Ca_2-xSr_xNb₂O₇：Eu³⁺的XRD呈现不同的相。Ca_1.97Nb₂O₇：3%Eu³⁺（x=0）的激发光谱中,302 nm附近的强宽带来自于O^2-→Eu³⁺电荷转移跃迁,272 nm附近的肩峰来自于NbO^7-₆基团的电荷转移跃迁,350~600 nm范围内的锐锋属于Eu³⁺的特征4f-4f组内跃迁。在398 nm激发下,发射光谱的最强峰位于616 nm,属于Eu³⁺的⁵D₀→⁷F₂电偶极跃迁,发射出强烈的红光。当Ca²⁺逐渐被Sr²⁺取代时,Ca_2-xSr_xNb₂O₇：Eu³⁺的各激发峰的强度先提高后降低,且O^2-→Eu³⁺电荷转移跃迁发生明显红移。少量Sr²⁺的掺杂可以有效提高Ca_2-xSr_xNb₂O₇：Eu³⁺ 的红光发射强度,当x=0.01时该荧光粉的红光发射达到最强,可以被紫外LED芯片激发。     

Sr1-xBaxAl2O4：Eu2+ , Dy3+磷光体的 制备及其发光特性

采用高温固相法在1 350 ℃弱还原气氛下制备了Sr_1-xBa_xAl₂O₄ : Eu²⁺ ,Dy³⁺ (x=0,0.2,0.4,0.6,0.8,1.0)长余辉材料,并对其微观结构和发光特性进行了分析。X射线衍射结果表明,当钡的掺杂摩尔分数x＜0.4时,样品晶体结构为SrAl₂O₄单斜晶系结构;当x≥0.4时,样品晶体结构为BaAl₂O₄六角晶系结构;而且随着钡对锶的取代,两种晶体结构的晶格常数都发生了一定程度的膨胀。光致发光测试结果表明,当x从0增大到1.0时,样品发射波长峰值也相应由515 nm逐渐蓝移到494 nm。通过热释光谱测试表明, SrAl₂O₄结构的样品的热释光峰所对应的温度比BaAl₂O₄ 结构的要高,且对应SrAl₂O₄结构的样品的余辉时间更长,初始亮度更高。     

高气压反射式高能电子衍射仪监控脉冲激光外延氧化物薄膜

在超高真空分子束外延（MBE）生长技术中，反射式高能电子衍射仪（RHEED）能实时显示半导体和金属外延生长过程，给出薄膜表面结构和平整度的信息，成为MBE必备的原位表面分 析仪.为了研究氧化物薄膜如高温超导（YBa₂Cu₃O₇） 、铁电薄膜（Sr_1-xBa_x TiO₃）及它们的同质和异质外延结构的生长机理，获得高质量的符合各种应用 需要的氧化 物多层薄膜结构，在常规的制备氧化 关键词： 高温超导薄膜 RHEED     

铌酸锶钡钠系统X射线衍射数据的测定

用衍射仪和Guinier聚焦照相机收集了铌酸锶钡钠系统一系列化合物的X射线粉末衍射图谱(CuK_α辐射)。给出了Ba₂NaNb₅O₁₅,SrBaNaNb₅O₁₅和Sr_2.05Na_0.90Nb₅O₁₅详细指标化了的粉末衍射数据,可代替原有的JCPDSX射线粉末衍射标准数据卡(卡片号为23-654,27-1408,27-1409和27-787)的数据。 关键词：     

Bi-Sr-Ca-Cu-O体系中的单斜相与掺Ba效应的研究

采用固相反应法合成名义组份为Bi₂Sr₂Ca_1-xBa_xCu₂O_y(A),Bi_1.7Pb_0.3Sr₂Ca_2-xBa_xCu₃O_y(B)的样品。此样品的物相和结构分析表明:在Bi系中存在着一种新的单斜相,其晶胞参量为a=24.8 关键词：     

铁电单晶(KxNa1-x)0.4(SryBa1-y)0.8Nb2O6的光学性质和线性电光效应

本文介绍铁电单晶(K_xNa_1-x)_0.4(Sr_yBa_1-y)_0.8Nb₂O₆的光学性质和线性电光效应的测量。实验结果表明,这种晶体具有较大的光学双折射,透光范围由4000?到5.6μm。晶体具有低的线性电光调制的半波电压,其电光调制价值指数n₀³·γ_c高达730×10 关键词：     

Light-induced charge transport processes in photorefractive crystals II: Materials

3 , LiTaO₃, BaTiO₃, Ba_1-xSr_xTiO₃ (, BST), Ba_1-xCa_xTiO₃ (, BCT), KNbO₃, KTa_1-xNb_xO₃ (, KTN), Sr_1-xBa_xNb₂O₆ (, SBN) and Bi₁₂(Si,Ti,Ge)O₂₀ (BSO, BTO, BGO) are discussed. Utilizing the knowledge on the charge transport processes, consequences for applications are deduced; improved techniques for nondestructive readout of holograms with light of the recording wavelength are described. Received: 14. October 1996     

铁电钾钠铌酸锶钡薄膜电光性能的研究

采用溶胶-凝胶法在氧化镁单晶衬底上制备了符合化学计量比的完全填充型铁电钾钠铌酸锶钡(KNSBN)薄膜，通过X射线衍射，摇摆曲线，X射线Φ扫描，扫描电子显微镜等方法研究了薄膜的微结构，采用Adachi法研究了薄膜的电光特性. 实验发现，KNSBN薄膜在氧化镁(001)单晶衬底上沿c轴外延生长，K⁺，Na⁺的引入有效地提高了薄膜的横向电光系数r₅₁. 成分为K_0.2Na_0.2Sr_0.24Ba_0.56Nb₂O₆, K_0.2Na_0.2Sr_0.6Ba_0.2Nb₂O₆, K_0.2Na_0.2Sr_0.72Ba_0.08Nb₂O₆的三种KNSBN薄膜的r₅₁值分别为108.52pm/V, 119.98pm/V, 126.96pm/V，r₅₁的数值随Sr²⁺含量增加而增大. 关键词： 横向电光系数 钾钠铌酸锶钡 外延生长     

Photorefractive waveguides in oxide crystals: fabrication, properties, and applications

3 , LiTaO₃, BaTiO₃, KNbO₃, Sr_xBa_1-xNb₂O₆ (0.25≤x≤0.75, SBN), and Bi₁₂(Si,Ti,Ge)O₂₀ (BSO, BTO, BGO) waveguides are discussed. Furthermore, the suitability of photorefractive waveguides for nonlinear optical components is demonstrated in some examples. Received: 21 April 1998/Revised version: 28 May 1998     

Fabrication and characterization of epitaxial Sr0.6Ba0.4Nb2O6/La0.7Sr0.3CoO3 heterostructures

Epitaxial Sr_0.6Ba_0.4Nb₂O₆(SBN60)/La_0.7Sr_0.3CoO₃ heterostructures were fabricated on LAO(0 0 1) substrates using pulsed laser deposition (PLD). Their structural properties were investigated by X-ray diffraction. The θ-2θ scans showed single crystalline Sr_1−xBa_xNb₂O₆ (SBN) and La_xSr_1−xCoO₃ (LSCO) layers with a 〈0 0 1〉 orientations perpendicular to the substrate plane. Phi scans on the (2 2 1) plane of SBN layer indicated that the films have two in-plane orientations with respect to the substrate. The SBN unit cells were rotated in the plane of the film by ±18.4° as well as ±45° with respect to the LAO substrate. This rotation was explained by considering the lattice matching between films and substrate, and minimization of electrostatic energy. Spectroellipsometry (SE) was used to characterize the depth profile, the microstructural inhomogeneities, including voids and surface roughness, refractive indices and extinction coefficients of the films.     

Diffuse phase transition in rare earth ion doped SBN

The diffuse transition of a rare earth ion doped SBN (Ba_xSr_1?xNb₂O₆) was studied by measuring the spontaneous polarization P_s, and the dielectric constant ?. The phase transition of SBN can be regarded as a special case of a second order transition.     

SBN thin films growth by RF plasma beam assisted pulsed laser deposition

SBN thin films were grown on MgO and Silicon substrates by PLD and RF-PLD (radiofrequency assisted PLD) starting from single crystal Sr_0.6Ba_0.4Nb₂O₆ and ceramic Sr_0.5Ba_0.5Nb₂O₆ stoichiometric targets. Morphological and structural analyses were performed on the SBN layers by AFM and XRD and optical properties were measured by spectroellipsometry. The films composition was determined by Rutherford Backscattering Spectrometry. The best set of experimental conditions for obtaining crystalline, c-axis preferential texture and with dominant 31° in-plane orientation relative to the MgO (100) axis is identified.     

热释电效应对光折变全息光栅读出的影响

先用两束０.２７ｍＷ的６３２.８ｎｍＨｅ-Ｎｅ激光在掺Ｍｎ的ＫＮＳＢＮ晶体中记录光折变全息光栅，再用波长为６２１.８ｎｍ的准连续染料激光读出，观察到衍射光信号有一个从初始最大值衰减到稳定最小值的暂态过程．初始值对稳定值的比可达７.５以上．这一现象可用热释电效应的影响进行解释 关键词：     

Magnetic interaction in Mg, Ti, Nb doped manganites

An effect of Mn substitution with Me=Mg²⁺, Ti⁴⁺, Nb⁵⁺ in manganites has been investigated by preparing La_0.7Sr_0.3(Mn_1-xMe_x)O₃ and La_1-xSr_x(Mn_{1 - x/2}Nb_x/2)O₃ series. It was established that substitution of manganese with magnesium up to x = 0.16 leads to a collapse of a long-range ferromagnetic order whereas La_0.7Sr_0.3(Mn ^{3 +} _0.85Nb ^{5 +} _0.15)O₃ is ferromagnet with T _C = 123 K and exhibits a large magnetoresistance below Curie point despite an absence of four-valent manganese. Hypothetical magnetic phase diagrams are constructed for La_0.7Sr_0.3(Mn_1-xMe_x)O₃ and La_1-xSr_x(Mn_{1 - x/2}Nb_x/2)O₃. Our results show that Mn³⁺-O-Mn³⁺ exchange interaction is ferromagnetic in the orbitally disordered manganites as well as an increase of Mn⁴⁺ content above 50% from a total amount of manganese ions leads to formation of a spin glass state due to a competition between antiferromagnetic Mn⁴⁺-O-Mn⁴⁺ and ferromagnetic Mn³⁺-O-Mn⁴⁺(Mn³⁺) superexchange interactions. Received 24 January 2002 Published online 9 July 2002     

Effect of annealing on the pyroelectric properties of SBN crystals

Single crystals of barium strontium niobate Sr_0.61Ba_0.39Nb₂O₆ (SBN) subjected to high-temperature annealing are shown to be more uniformly polarized in a dc electric field than unannealed samples. The experiments are carried out with undoped SBN crystals and with chromium-and cerium-doped SBN crystals.     

Nb(Ba)加强Bi系中2223相生成作用研究

固相法合成系列名义组成为Bi_2-xNb_xSr₂Ca₂Cu₃O_y(x=0—1.0)的样品,电学和磁学测量表明,当掺入x=0.2—0.3的Nb有明显加强2223相生成的作用,配比为Bi_1.7Nb_0.3Sr₂Ca₂Cu₃O_y时最佳;当掺Ba以部分取代Sr后有明显协同Nb促进2223相生成的作用,比单掺Nb效果更为显著,其中以Bi_1.7Nb_0.3Sr_1.8Ba_0.2Ca₂Cu₃O_y为最优组成。热重分析(TGA)实验显示,掺Nb(Ba)后样品在～600°C出现吸氧增重;XPS中的O_1s峰显示掺Nb(Ba)后除～531eV的主峰外,在～529eV的肩峰更加明显;讨论了Nb(Ba)对晶体结构的可能影响。 关键词：