共查询到19条相似文献,搜索用时 250 毫秒
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固相法合成系列名义组成为Bi2-xNbxSr2Ca2Cu3Oy(x=0—1.0)的样品,电学和磁学测量表明,当掺入x=0.2—0.3的Nb有明显加强2223相生成的作用,配比为Bi1.7Nb0.3Sr2Ca2Cu3Oy时最佳;当掺Ba以部分取代Sr后有明显协同Nb促进2223相生成的作用,比单掺Nb效果更为显著,其中以Bi1.7Nb0.3Sr1.8Ba0.2Ca2Cu3Oy为最优组成。热重分析(TGA)实验显示,掺Nb(Ba)后样品在~600°C出现吸氧增重;XPS中的O1s峰显示掺Nb(Ba)后除~531eV的主峰外,在~529eV的肩峰更加明显;讨论了Nb(Ba)对晶体结构的可能影响。
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测量了Bi1.8Pb0.4Sr2Ca2Cu3Oy银夹板厚膜的应力与应变、应变和临界电流密度关系,及其在不同应变下的Jc(H)特性.结果表明,在应力-应变曲线上存在两个应变转变,分别对应于Bi1.8Pb0.4Sr2Ca2Cu3Oy关键词: 相似文献
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研究了掺Ba对Bi2Sr2-xBaxCaCu2Oy(0≤x≤0.15,0.3)单晶和多晶样品超导电性的影响,结果表明,有少量Ba2+离子进入了超导相,且有固溶度极限.对于2212相单晶,c轴参数和Tc均随Ba含量增加而增加;对于慢冷多晶样品,掺Ba可明显提高Tc;然而对于淬大多晶样品,Tc没有明显变化,用掺Ba
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采用固相反应法合成了名义组份为Bi2-xPbxSr2Ca2Cu3Oy (x=0.30;0.35;0.40;0.45)的样品。对样品进行了物相和结构分析,同时测量了电阻-温度关系和直流磁化率。结果表明:x=0.35的样品为单相材料,X射线相分析和电子衍射表明其相结构类似2223相,为四方结构,其晶格常数为a=b=5.414?,c=37.106?,且沿a,b两个方向都观察到调制结构。电阻和直流磁化率测量结果显示:在温度高于50K以上,仅存在一个107K超导相。此外,单相材料的制备条件(组分、烧结温度、室温下淬火及淬火速率)非常苛刻。如同1-2-3相材料一样,氧含量不仅影响样品的成相规律、零电阻温度,而且还严重影响其正常态的输运性质。
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Vilas Shelke H. S. Tewari N. K. Gaur R. K. Singh 《Physica C: Superconductivity and its Applications》1998,300(3-4):217-224
We have investigated the effect of Hg addition on the superconducting properties of BiSrCaCuO system. Polycrystalline samples with nominal composition Bi2Sr2−xHgxCa1Cu2Oy and Bi2Sr2−xHgxCa2Cu3Oy (x=0.3) were synthesized and used to investigate the phase evolution by XRD, superconducting behaviour by R–T measurement and the structural grain boundary effects by SEM. From these measurements, it has been noticed that the phases obtained with both types of compositions are the same as Bi2212 but the Tc values are different. With additional annealing, Tc zero values were raised from 60 to 72 K in Bi2Sr2−xHgxCa1Cu2Oy and 64 to 92 K in Bi2Sr2−xHgxCa2Cu3Oy. Also, an improved grain boundary linkage has been observed by SEM for the 92 K sample. 相似文献
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P.K. Ummat R.K. Nkum W.R. Datars 《Physica C: Superconductivity and its Applications》1991,180(5-6):407-410
Magnetic susceptibility, X-ray diffraction and resistivity measurements of the system Bi1.4Pb0.6Sr2Ca2−xGaxCu3Oy are reported for 0 x 2. The high-Tc 2223 phase with a Tc of 107 K for x = 0 exists for x 0.3. The low-Tc 2212 phase with a Tc of 75 K for x = 0 exists for the full range of x. The highest values of the critical temperature and the largest volume fraction of the low-Tc phase in compounds with Ga occur for x = 0.5 ± 0.1. The identification of CaO by X-ray diffraction for x 0.6 indicates that Ga replaces Ca in the compound. 相似文献
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J. J. Lin W. Y. Lin R. F. Tsui 《Physica C: Superconductivity and its Applications》1993,210(3-4):455-462
We have measured the resistivities of Al2O3-Bi2Sr1.8Ca1.2Cu2Oy and MgO-Bi2Sr1.8Ca1.2Cu2Oy composites with the nominal Bi2Sr1.8Ca1.2Cu2Oy volume fraction, 2212, ranging from 0.15 to 1.00. For the Al2O3-Bi2Sr1.8Ca1.2Cu 2Oy composites, we find for the samples with 2212≥0.6 that the superconducting transition temperature, Tc, is not disturbed by the addition of Al2O3. For 2212<0.3, no zero-resistivity state is observed. For the MgO-Bi2Sr1.8Ca1.2Cu2Oy composites, Tc is barely disturbed for the samples with ρ2212≥0.7. No superconducting state is observed for the samples with ρ2212<0.35. The variation of (300 K) with ρ2212 indicates a three-dimensional percolating Bi-Sr-Ca-Cu-O matrix occurring at ρ2212≈0.19 and ≈0.15 in Al2O3-Bi2Sr1.8Ca1.2 Cu2Oy and MgO-Bi2Sr1.8Ca1.2Cu2Oy, respectively. Both resistivity and magnetization measurements suggest that the reactions of Bi2Sr1.8Ca1.2Cu2Oy with MgO are weaker than with Al2O3. 相似文献
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F. Munakata T. Kawano H. Yamauchi
Y. Inoue
《Physica C: Superconductivity and its Applications》1992,190(4):471-476The X-ray diffraction patterns for Bi2Sr2Ca1−xYxCu2O8+y sintered in air or Ar indicated that the reduction in the number of excess oxygen ions induced a structural change from orthorhombic to pseudotetragonal. When the oxygen contents decreased with the reducing treatment, the period of modulation in Bi2Sr2Ca1−xYxCu2O8+y increased. This result supported the model of excess oxygen ions in the Bi---O sheet. However, it was difficult to understand the change of modulation period with increasing Y contents using the model of excess oxygen ions in the Bi---O layers. Also, it is included that the Y substitution for Ca and La substitution for Sr in the Bi2Sr2CaCu2O8+y system result in parallel effects for the modulation structure. 相似文献
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We have systematically investigated the doping effect on the Bi2Sr2Ca2Cu3Oy superconductive material. After entering into the crystal lattice, Pb and/or Sb atoms cause not only variations of the temperature condition during the sample preparation process, but also variations of structures and superconductivity. By analyzing the experimental results, we have come to the conclusion that the Pb and/or Sb atoms enter into the Bi-O planes, preferably occupy the sites of Bi ions, regulate the crystal structures and the distribution of oxygen ions in Bi-O planes and nearby lattice sites, thus benefiting the formation of the high-Tc phase and improving the superconductivity. 相似文献
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Joseph B. Schlenoff W. Jack Rink Lawrence Seger 《Physica C: Superconductivity and its Applications》1991,180(5-6):387-393
Single crystals and polycrystalline pellets of the high-temperature cuprate superconductor Bi2Sr2Ca1Cu2O8 were doped at room temperature by electrochemical reduction at > 95% Coulombic efficiency using lithium dopant ions in propylene carbonate electrolyte. Cyclic voltammetry and potential step measurements on single crystals suggest an unusual reduction mechanism, with a diffusion coefficient for Li+ in the c-axis direction of bulk superconductor of ca. 3 × 10−11 cm2s−1. Sintered pellets of polycrystalline powder could be doped more rapidly, with an apparent diffusion coefficient of 7 × 10−8 cm2s−1. X-ray susceptibility analysis show extensive disordering occurs on heavy Li doping, with a first-order transition from a crystalline/superconducting to an amorphous/non-superconducting phase. Single, crystals of Bi2Sr2Ca1Cu2O8 exhibited a color change on reduction from metallic gray to golden bronze. The reduced material was highly air-sensitive, forming a hydroxide surface film on exposure to ambient atmosphere. 相似文献
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T. Brousse G. Poullain J.F. Hamet H. Murray B. Raveau 《Physica C: Superconductivity and its Applications》1990,170(5-6):545-551
Thin films of Bi2Sr2CaCu2O8 and (Bi, Pb)2Sr2Ca2Cu3O10 have been prepared on monocrystalline (100) MgO substrates, using a laser ablation method with post annealing treatment. The influence of substrate temperature and oxygen pressure during deposition were investigated. SEM observations, EDS analysis, electric and magnetic measurements have been used to characterize the films. Superconducting “2212” films, with Tc(R = 0) at 80–83 K and Jc (50 K) up to 5 × 105 A/cm2, have been currently achieved, while Pb-doped “2223” films exhibit Tc as high as 110 K with Jc = 5 × 104 A/cm2 at 77 K. The effect of annealing at low temperature (350°C) in an argon flow has been studied for the 2212 phase, it shows the influence of the oxygen non-stoichiometry, i.e. of the hole carrier density upon Tc's which can be measured up to 89 K (zero resistance). 相似文献
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N. R. Khasanova A. L. Kharlanov E. V. Antipov L. M. Kovba A. A. Gippius V. V. Moshchalkov 《Physica C: Superconductivity and its Applications》1992,190(4):522-526
Bi-2222 phases were prepared by solid state reactions and were studied using X-ray diffraction, chemical and EDS-analysis. Compounds with composition Bi2Sr2R1.33Ce0.67Cu2O10+δ were obtained for R=Pr, Nd, Sm-Er. The phases Bi2Sr2Cu2O10+δ with similar structure but without Ce were prepared for R = Pr, Sm-Dy. For Bi2Sr2Eu2−xCexCu2O10+δ the solubility limit was determined and the effect of treatment under different oxygen pressures was investigated. Weak diamagnetic signals (<3%) were detected for some of these samples. 相似文献
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There was giant flux jumps in high Tc Bi1.7Pb0.3Sr2Ca2Cu3Oy bulk superconductor. The relaxation time, τ, decreased with both the increase of magnetic field and the rise of temperature. The maximum τ was about 40 min.. The average-dM/dt increased with both the increase of magnetic field and the rise of temperature. The minimum average-dM/dt was about 4.1×10−2G/min.. The flux jump weakened with time. It was dependent on the decrease of gradient of magnetic flux density dn/dx in the sample. 相似文献