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1.
Teng GUO Zhen PENG Hui ZHU Li XU Jun-Guo DONG Zheng-Xu HUANG Ping CHENG Zhen ZHOU 《分析化学》2019,47(1):13-22
Ion funnel is a new-style ion guider which can reduce spatial divergence and energy dispersity of the transmission ions by using radio frequency (RF) electric field to confine the ions radially and the direct current (DC) axial electric field to move the ions toward the exit, and thus it can greatly increase the ion transmission efficiency and improve the sensitivity of the mass spectrometry. Since ion funnel was invented in 1997, it has attracted a close attention of mass spectrometry scientists all over the world. Ion funnel has been used in various kinds of mass spectrometry, and built a bridge with high efficiency ion transmission between low vacuum ionization source and high vacuum mass analyzer. In this paper, the principle, technology development, and application progress of ion funnel are reviewed, and the future prospects are prospected. 相似文献
2.
The National Natural Science Foundation of China (NSFC) is a vital government agency supporting basic research and people to create knowledge and meet major national needs, where a rigorous and objective merit-based peer review mechanism is the key to funding the most promising research proposals. This invited comment overviews some recent attempts aimed at bettering the academic evaluation environment at the Department of Chemical Science in 2019, through measures such as grouped panel committee meetings, standardized panel committee meeting procedures, and review process refinement to improve the project review at panel committee meeting levels. 相似文献
3.
Sunil K. Ghosh 《Helvetica chimica acta》2023,106(11):e202300141
Acrylates are well known electrophilic alkenes having multitude of applications in organic synthesis. They are very good acceptors in Michael addition reactions and are good enophile/dienophile/dipolarophile partners in cycloaddition reactions. Replacing the β-alkyl/aryl groups in acrylates by a silicon group would be interesting. In addition to the conventional reactions displayed by acrylates, β-silylacrylates (β-SAs) can show reactivity specifically related to the silicon group. Many conventional organic reactions such as hydrodimerization, organocatalytic asymmetric Michael additions, inter- and intra-molecular Diels–Alder reactions, and asymmetric 1,3-dipolar cycloadditions have been used to generate the complex chemical entities from β-SAs. Some of the reaction outcomes were vastly influenced by the silicon substituent. This review describes the practical synthesis β-SAs and their use as starting point in complex molecule generation including total synthesis of some natural products/bioactive molecules. 相似文献
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综述了国内外采用X射线荧光光谱法的各类标准,其中包括美国材料与试验协会(ASTM)标准、国际标准化组织(ISO)标准和我国国家标准,主要应用在石油及产品、合金和矿石中元素的含量测定(引用文献31篇)。 相似文献
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人造麝香的危害性及其残留检测方法研究进展 总被引:1,自引:0,他引:1
综述了近年来人造麝香的危害性及其残留检测方法的研究进展。对化妆品、水、大气、土壤和药物中人造麝香的前处理方法和检测方法进行了比较,同时对此领域的发展方向进行了展望(引用文献31篇)。 相似文献
6.
本文介绍了气体元素分析样品表面处理的最新研究成果,综述了热导法、红外吸收法、库仑滴定法、飞行时间质谱法和火花源原子发射光谱法等分析方法在无机固态材料气体分析中的应用现状,分析了各自的特点及存在的问题,并展望了气体分析的发展方向(引用文献85篇)。 相似文献
7.
DNA不只是遗传物质,还能通过折叠形成特定的二维、三维结构,作为一种天然纳米材料可参与各种功能结构和纳米器件的构造。DNA纳米技术从被提出到现在的三十多年间,得到了飞速发展,被应用于众多领域,对纳米科学产生了重大影响。本文将主要从三种典型的DNA纳米结构和DNA纳米技术的应用两个方面进行综述,并对DNA纳米技术的前景进行展望。 相似文献
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Cytokines are bioactive proteins produced by many different cells of the immune system. Due to their role in different inflammatory disease states and maintaining homeostasis, there is enormous clinical interest in the quantitation of cytokines. The typical standard methods for quantitation of cytokines are immunoassay-based techniques including enzyme-linked immusorbent assays (ELISA) and bead-based immunoassays read by either standard or modified flow cytometers. A review of recent developments in analytical methods for measurements of cytokine proteins is provided. This review briefly covers cytokine biology and the analysis challenges associated with measurement of these biomarker proteins for understanding both health and disease. New techniques applied to immunoassay-based assays are presented along with the uses of aptamers, electrochemistry, mass spectrometry, optical resonator-based methods. Methods used for elucidating the release of cytokines from single cells as well as in vivo collection methods are described. 相似文献