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用溶液共沉淀法(湿法)制备了Y_(0.6)Ba_(0.8)CuO_x超导体,其中点转变温度为94.1K,转变宽度为1.2K,对样品在二周时间内进行20次从液氮温度到室温、从液氮环境到空气环境的冷热循环,发现在1—3次冷热循环后,超导转变温度略有下降,然后稳定在91.5K左右。在正常态(室温)及超导态(77K)进行X射线分析,表明样品为两相的多晶体,有超导性的主相为正交缺氧的钙钛矿超结构。正常态与超导态的晶格结构没有变化。 相似文献
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在计算机控制的封闭式单晶生长炉内,采用自助熔剂法生长出最大尺寸2.0mm×2.0mm×O.3mm,典型尺寸1.0mm×1.0mm×O.1mm的TI-2223,TI-2212单晶,Tc分别达到119 K和110 K.TI的含量对晶体生长的大小、相的形成及Tc均有重要影响.TI-2212单晶的交流磁化率的虚部峰值温度 Tp和外场 HD 的关系为(1-Tp/Tc)∝HD0.71(HD//C轴)TI-2223单晶可见光区的光反射谱存在强烈的各向异性. 相似文献
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铊系超导单晶的低温生长 总被引:1,自引:0,他引:1
采用蠕爬型助熔剂CaO-CuO和蒸发型复合助熔剂CaO-CuO-NaCl来制备Tl-Ba-Ca-CU-O超导单晶,生长炉最高温度分别为890℃和850℃,因而实现了铊系单晶的低温生长.生长出的单晶分别是典型尺寸为2.0×1.5×0.2mm3,Tc在100K与119K之间的Tl-2212相单晶和尺寸为1.2×1.0×0.1mm3,Tc约为115K的Tl-2223相超导单晶.采用蠕爬型助熔剂可以降低熔点而不引进其它非组元杂质,但导致熔料蠕爬,对生长大块单晶不利.采用蒸发型复合助熔剂克服了熔料的蠕爬现象,减少了铊的损失,对生长多铜氧层的单晶有利. 相似文献
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Miedema method, which was proposed to calculate the heat of formation of binary alloy system, is extended for calculating the heat of formation of ternary system by using the Toop's model. The hypothetical metallic allotropes correspounding to the properties of nonmetallic elements are introduced. In our calculation, the structure-dependent energy contributions have not been taken into account. The heat of formation of GaAs1-x Px, GaAs1-xNx, and GaP1-xNx are obtained by projecting the heat of formation of ternary systems, P-Ga-As, N-Ga-As, and N-Ga-P onto the plane of the concentration of Ga, c2 = 0.5, respectively. The possibility of existence of ordered ternary compound was predicted. The dependence of direct band gap, EΓ, or indirect one, EX, for GaP1-xNx and GaAs1-xNx, on x, the concentration of N, is obtained by using the dielectric theory of electronegativity. 相似文献
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