首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   101368篇
  免费   2147篇
  国内免费   1670篇
化学   35902篇
晶体学   1226篇
力学   8052篇
综合类   110篇
数学   34225篇
物理学   25670篇
  2023年   210篇
  2022年   366篇
  2021年   432篇
  2020年   435篇
  2019年   528篇
  2018年   10828篇
  2017年   10631篇
  2016年   6685篇
  2015年   1509篇
  2014年   1173篇
  2013年   1663篇
  2012年   5435篇
  2011年   12375篇
  2010年   7043篇
  2009年   7423篇
  2008年   8145篇
  2007年   10210篇
  2006年   1665篇
  2005年   2433篇
  2004年   2523篇
  2003年   2726篇
  2002年   1703篇
  2001年   1311篇
  2000年   991篇
  1999年   761篇
  1998年   599篇
  1997年   550篇
  1996年   546篇
  1995年   419篇
  1994年   350篇
  1993年   316篇
  1992年   285篇
  1991年   257篇
  1990年   231篇
  1989年   201篇
  1988年   185篇
  1987年   162篇
  1986年   146篇
  1985年   146篇
  1984年   108篇
  1983年   82篇
  1982年   72篇
  1981年   71篇
  1980年   64篇
  1979年   61篇
  1978年   51篇
  1976年   43篇
  1975年   43篇
  1973年   44篇
  1914年   45篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
通过引入参数,构造了一个全平面上的、含双曲函数的非齐次核函数。利用正切函数的有理分式展开,建立了最佳常数因子与正切函数高阶导数相关联的Hilbert型积分不等式。 作为应用,通过赋予参数不同的值,建立了一些有意义的特殊结果。  相似文献   
2.
Science China Mathematics - In this paper, we obtain a necessary and sufficient condition for a U(n)-invariant complex Finsler metric F on domains in ?n to be strongly convex, which also...  相似文献   
3.
Atopic dermatitis is characterized by leukocyte migration into the skin dermis and typically driven by excessive chemokine production at the site of inflammation. Conventional topical formulations such as gels, creams, and ointments are insufficient for this treatment because of low penetration of drug molecules into the targeted skin tissues. Herein, using a simple, green, sustainable strategy, we have developed novel primary zein nanoparticles embedded in curcumin (Cur) and coated with silk sericin (ZHSCs) for the topical delivery of Cur to penetrate into the dermis and exercise anti-dermatitis effects on the lesion with minimal side-effects. Transdermal delivery experiments and porcine skin fluorescence imaging indicated that ZHSCs facilitate the penetration of Cur across the epidermis layer of skin to reach deep-seated sites. Notably, ZHSCs = 1:0.25 (zein-to-silk sericin mass ratios of 1:0.25) markedly elevated the skin permeability and cumulative turnover of Cur transferred, which were provided a greater than a 3.8-fold increase relative to free Cur. The special nanoparticles of ZHS = 1:0.25 possessed the deepest localization depth and experience a transition of the particle structure and core-shell separation after penetrating into the dermis of skin. In a cell model of dermatitis induced by tumor necrosis factor α/interferon γ co-stimulation, compared with free Cur, Cur-loaded ZHS nanoparticles down-regulated the generation of inflammatory cytokines and chemokines in keratinocytes through suppression of the nuclear translocation of NF-κBp65 and hence exerted an anti-dermatitis effect. This strategy may provide new avenues and direction for the demanding issues of valid topical delivery systems.  相似文献   
4.
Liu  Wei  Li  Kehong  Deng  Hao  Wang  Jing  Zhao  Peng  Liao  Wei  Zhuo  Liangang  Wei  Hongyuan  Yang  Xia  Chen  Yue 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(2):747-754
Journal of Radioanalytical and Nuclear Chemistry - There is an urgent need to develop more specific targeted therapies for lung cancer treatment due to the its low survival rate. EGFR is a...  相似文献   
5.

In this paper, we study a category of restricted modules for the Ovsienko-Roger algebra, which is an extension of the Virasoro algebra of its tensor density module of degree one. We construct and characterize simple modules in this category and give natural free field realizations of certain restricted modules using the Weyl vertex algebra.

  相似文献   
6.
Yin  Qingqing  Xu  Fen  Sun  Lixian  Li  Yaying  Liao  Lumin  Wang  Tao  Guan  Yanxun  Xia  Yongpeng  Zhang  Chenchen  Wei  Sheng  Zhang  Huanzhi  Li  Bin 《Journal of Thermal Analysis and Calorimetry》2022,147(12):6583-6592
Journal of Thermal Analysis and Calorimetry - Polyethylene glycol (PEG) is widely used as phase change materials (PCMs). However, the leakage and low thermal conductivity issues restrict its...  相似文献   
7.
8.
Meng  Y.  Cai  B.  Lan  Q.  Niu  F.  Zhang  X.  Yang  Y. 《Crystallography Reports》2022,67(2):224-228
Crystallography Reports - A di-nuclear uranyl complex with the formula of [(UO2)2(L)4(H2O)2]?4H2O (1) (HL = quinoline-6-carboxylic acid) was synthesized hydrothermally and characterized by...  相似文献   
9.
Li  Y.  Shi  W. H.  Dong  L. M.  Xu  S. X.  Huang  H. J.  Yin  J. R. 《Journal of Applied Spectroscopy》2022,89(3):534-541
Journal of Applied Spectroscopy - Sr3B2O6:Dy3+, Eu3+ single-matrix white-light-emitting materials are prepared using the high-temperature solid-state method. The microstructure, emission spectrum,...  相似文献   
10.
Non-noble bifunctional electrocatalysts with robust activity and stability toward oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are greatly significant but challenging for Zn-air batteries. Here, in situ confinement of FeNx active sites in high porosity carbon framework (FeNx/CMCC) derived from chelate of carboxymethylcellulose (CMC) and iron ions were synthesized. Particularly, construction of FeNx within porous carbon framework accelerates the electron transfer and the sufficient utilization of active centers, and then expedites the reaction kinetics of ORR and OER. As expected, the optimized FeNx/CMCC exhibits superior ORR activity with a larger half-wave potential of 0.869 V. The rechargeable Zn-air battery delivers a higher power density of 99.6 mW/cm2 and a special capacity of 781.9 mA h/gZn at 10 mA/cm2, together with excellent durability of over 335 h. Remarkably, the as-assembled solid-state battery exhibits a higher open circuit voltage (OCV) of 1.5 V, a special capacity of 709.7 mA h/gZn, as well as prolonged cycling stability (90 h). Moreover, the flexible solid-state battery displays negligible loss of electrochemical performance under various bending angles, illustrating its potential application in flexible electronic devices.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号