排序方式: 共有13条查询结果,搜索用时 187 毫秒
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利用三聚氰胺甲醛预聚物中N原子与Pd2+的相互作用,将Pd2+化学锚定在预聚物中;并以二氧化硅水凝胶为造孔剂、2,4-二氨基苯磺酸为预聚物缩合促进剂,在水溶液中制备出锚定了Pd2+的胶体纳米球;再经摩尔分数5%氢气焙烧、HF腐蚀,得到Pd质量分数为1.37%、平均粒径为(2.4±0.87) nm的碳载高分散Pd纳米粒子催化剂Pd@C。 将其应用于Suzuki反应,在加入Pd与碘苯物质的量比为1:100的催化剂时,反应5 min收率为99.3%,且经8次循环后活性未降低,表现出良好的催化效果和重复使用性。 相似文献
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In this work, we demonstrate an in situ phase conversion from basic magnesium chloride(BMC) into magnesium hydroxide whisker by using polar organic solvent at low temperature. The morphology and phase composition of magnesium hydroxide whiskers prepared at different reaction temperature, alkali concentration and organic solvent were analyzed by X-ray diffraction(XRD) and scanning electronic microscope(SEM). It was found that when one of the organic solvents such as absolute ethyl alcohol, butanol, polyethylene glycol(PEG-400), acetone, et al. was selected as the template, the precursor BMC can transform into whisker-like magnesium hydroxide through precipitate transformation in low temperature and non-hydrothermal system. It can be reasonably explained that the regulation of Mg^2+ solubility by those organic solvents and the sustained release of Mg^2+ dissolution by organic adsorption played a significant role in the formation of magnesium hydroxide whisker via BMC whisker as the precursor. 相似文献
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考虑了雷达成像中的一个波形设计问题.基于匹配滤波,在Sobolev空间的框架下,使用Hermite多项式理论,并通过一种数值算法,实现了波形的优化设计.数值实验表明,该方法是有效的.相比于CW(continuous wave)脉冲和线性调频脉冲方法,该方法可以得到更高的分辨率. 相似文献
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在具有G-可微范数的Banach空间中证明非扩张映像的复合Halpern型迭代的强收敛定理.该结论不需要使用连续道路魂,证明方法更简单,条件比Qin x更弱. 相似文献
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