首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   36306篇
  免费   6158篇
  国内免费   4780篇
化学   25468篇
晶体学   398篇
力学   2366篇
综合类   424篇
数学   4692篇
物理学   13896篇
  2024年   73篇
  2023年   653篇
  2022年   799篇
  2021年   1105篇
  2020年   1340篇
  2019年   1331篇
  2018年   1162篇
  2017年   1136篇
  2016年   1665篇
  2015年   1645篇
  2014年   1974篇
  2013年   2695篇
  2012年   3180篇
  2011年   3363篇
  2010年   2431篇
  2009年   2361篇
  2008年   2605篇
  2007年   2336篇
  2006年   2173篇
  2005年   1799篇
  2004年   1411篇
  2003年   1200篇
  2002年   1094篇
  2001年   898篇
  2000年   793篇
  1999年   838篇
  1998年   684篇
  1997年   620篇
  1996年   562篇
  1995年   538篇
  1994年   457篇
  1993年   406篇
  1992年   341篇
  1991年   298篇
  1990年   277篇
  1989年   208篇
  1988年   167篇
  1987年   147篇
  1986年   109篇
  1985年   111篇
  1984年   68篇
  1983年   63篇
  1982年   55篇
  1981年   24篇
  1980年   14篇
  1977年   5篇
  1973年   3篇
  1970年   3篇
  1959年   3篇
  1957年   8篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Zhang  Hongchi  Liu  Rui  Li  Hui  Yang  Yang  Zhou  Feng 《Chemistry of Natural Compounds》2022,58(3):541-544
Chemistry of Natural Compounds -  相似文献   
2.
The designs of efficient and inexpensive Pt-based catalysts for methanol oxidation reaction (MOR) are essential to boost the commercialization of direct methanol fuel cells. Here, the highly catalytic performance PtFe alloys supported on multiwalled carbon nanotubes (MWCNTs) decorating nitrogen-doped carbon (NC) have been successfully prepared via co-engineering of the surface composition and electronic structure. The Pt1Fe3@NC/MWCNTs catalyst with moderate Fe3+ feeding content (0.86 mA/mgPt) exhibits 2.26-fold enhancement in MOR mass activity compared to pristine Pt/C catalyst (0.38 mA/mgPt). Furthermore, the CO oxidation initial potential of Pt1Fe3@NC/MWCNTs catalyst is lower relative to Pt/C catalyst (0.71 V and 0.80 V). Benefited from the optimal surface compositions, the anti-corrosion ability of MWCNT, strong electron interaction between PtFe alloys and MWCNTs and the N-doped carbon (NC) layer, the Pt1Fe3@NC/MWCNTs catalyst presents an improved MOR performance and anti-CO poisoning ability. This study would open up new perspective for designing efficient electrocatalysts for the DMFCs field.  相似文献   
3.
Wang  Rong  Li  Xu  Zhou  Youshi  Cao  Shuxuan  Xu  Honghao  Han  Wenjuan  Zhang  Yuxia  Liu  Junhai 《Journal of Russian Laser Research》2022,43(4):476-481
Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The...  相似文献   
4.
International Journal of Theoretical Physics - A new quantum watermark algorithm is presented by combining maximum pixel difference partitioning with the least significant bit substitution...  相似文献   
5.
Designs, Codes and Cryptography - Large sets of combinatorial designs has always been a fascinating topic in design theory. These designs form a partition of the whole space into combinatorial...  相似文献   
6.
Zhou  Jiuru 《Archiv der Mathematik》2021,116(6):693-706

In this paper, we study vanishing and splitting results on a complete smooth metric measure space \((M^n,g,\mathrm {e}^{-f}\mathrm {d}v)\) with various negative m-Bakry-Émery Ricci curvature lower bounds in terms of the first eigenvalue \(\lambda _1(\Delta _f)\) of the weighted Laplacian \(\Delta _f\), i.e., \(\mathrm {Ric}_{m,n}\ge -a\lambda _1(\Delta _f)-b\) for \(0<a\le \dfrac{m}{m-1}, b\ge 0\). In particular, we consider three main cases for different a and b with or without conditions on \(\lambda _1(\Delta _f)\). These results are extensions of Dung and Vieira, and weighted generalizations of Li-Wang, Dung-Sung, and Vieira.

  相似文献   
7.
Wacker oxidation is an industry-adopted process to transform olefins into value-added epoxides and carbonyls. However, traditional Wacker oxidation involves the use of homogeneous palladium and copper catalysts for the olefin addition and reductive elimination. Here, we demonstrated an ultrahigh loading Cu single atom catalyst(14% Cu, mass fraction) for the palladium-free Wacker oxidation of 4-vinylanisole into the corresponding ketone with N-methylhydroxylamine hydrochloride as an additive under mild conditions. Mechanistic studies by 18O and deuterium isotope labelling revealed a hydrogen shift mechanism in this palladium-free process using N-methylhydroxylamine hydrochloride as the oxygen source. The reaction scope can be further extended to Kucherov oxidation. Our study paves the way to replace noble metal catalysts in the traditional homogeneous processes with single atom catalysts.  相似文献   
8.
Hu  Duo-Duo  Gao  Qian  Dai  Jing-Cheng  Cui  Ru  Li  Yuan-Bo  Li  Yuan-Ming  Zhou  Xiao-Guo  Bian  Kang-Jie  Wu  Bing-Bing  Zhang  Kai-Fan  Wang  Xi-Sheng  Li  Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,...  相似文献   
9.
For an integer s0, a graph G is s-hamiltonian if for any vertex subset S?V(G) with |S|s, G?S is hamiltonian, and G is s-hamiltonian connected if for any vertex subset S?V(G) with |S|s, G?S is hamiltonian connected. Thomassen in 1984 conjectured that every 4-connected line graph is hamiltonian (see Thomassen, 1986), and Ku?zel and Xiong in 2004 conjectured that every 4-connected line graph is hamiltonian connected (see Ryjá?ek and Vrána, 2011). In Broersma and Veldman (1987), Broersma and Veldman raised the characterization problem of s-hamiltonian line graphs. In Lai and Shao (2013), it is conjectured that for s2, a line graph L(G) is s-hamiltonian if and only if L(G) is (s+2)-connected. In this paper we prove the following.(i) For an integer s2, the line graph L(G) of a claw-free graph G is s-hamiltonian if and only if L(G) is (s+2)-connected.(ii) The line graph L(G) of a claw-free graph G is 1-hamiltonian connected if and only if L(G) is 4-connected.  相似文献   
10.
A novel plasmonic polarization filter based on the diamond-shape photonic crystal fiber(PCF) is proposed. The resonant coupling characteristics of the PCF polarization filter are investigated by the full-vector finite-element method. By optimizing the geometric parameters of the PCF, when the fiber length is 5 mm, the polarization filter has a bandwidth of 990 nm and an extinction ratio(ER) of lower than -20 dB. Moreover, a single wavelength polarization filter can also be achieved, along with an ER of -279.78 dB at wavelength 1.55 μm. It is believed that the proposed PCF polarization filter will be very useful in laser and optical communication systems.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号