Graphene Saturable Absorber Mirror for Mode-Locked Orange Pulse Laser

Journal of Russian Laser Research - We demonstrate a passively-mode-locked Pr3+: LuLiF4 laser operated at the 604 nm orange wave-length, using monolayer graphene as a saturable absorber. The...     

Simulation of the wave-absorbing model of a carbonyl iron / silver-coated core–shell structure

The microwave-absorbing performances of carbonyl iron powder / silver core–shell composite particles are studied on the basis of the electromagnetic scattering theory and the energy conservation law. In addition, a calculation method for reflection loss of the carbonyl iron powder / silver core–shell composite particles with microwave is proposed. The calculated reflection loss of the carbonyl iron powder / silver core–shell composite particles is compared with the experimental results. The findings show that the trend of reflection loss of the carbonyl iron powder / silver composite particles can be predicted which can subsequently provide a relevant reference for future experiment and calculation of the absorbing mechanism of electromagnetic wave-microscopic carbonyl iron powder / silver core–shell composite particles.     

利用液体炸药爆轰制备石墨烯薄片

强氧化性酸的环境下,石墨易形成石墨层间化合物(GICs),利用石墨这一特性,将天然石墨置于发烟硝酸中,并加入硝基甲烷,配制成液体炸药,使用塑料容器盛装后放入爆轰反应釜中引爆。收集爆轰产物,并利用XRD、EDX、SEM、TEM、Raman光谱、比表面积与孔隙度分析仪进行分析,结果显示:制备出的石墨烯具有良好的晶体特性并呈现极薄的片状结构,其比表面积达到天然石墨的9.16倍,平均厚度约为14.73 nm。     

RDX基铝纤维炸药空中爆炸性能

将铝纤维炸药与传统铝粉炸药和RDX炸药进行空中爆炸实验并得到压力时程曲线,经过分析计算得到3种炸药的压力峰值、二次击波、正相持续时间以及冲量。结果表明:铝纤维炸药的压力峰值相对于RDX没有明显提高,但其压力时程曲线衰减速度慢于RDX的,使铝纤维炸药的正相持续时间大于RDX,铝纤维炸药的冲击波冲量相对于RDX的平均提高了18%,与铝粉炸药的相当。铝纤维炸药的二次击波超压幅值与到达时间与铝粉炸药的接近,而铝纤维炸药的二次击波到达时间早于RDX,说明二次击波的超压幅值与到达时间与炸药类型有关。     

水下爆炸非均熵二维定常流的三族特征线解法

针对二维定常可压缩超声速非等熵柱状流,提出一种特征线差分解法,通过在沿马赫线的相容方程中添加沿流线的熵变项以描述非等熵效应,得到等熵流和非等熵流均适用的三族特征线方程组。根据水下爆炸近场特点,建立无限长柱状装药的定常模型,将三族特征线方程组用有限差分法离散求解,通过构造合适的网格保证计算格式可以数值上收敛,由此编制程序并计算几种柱状炸药的水下爆炸近场冲击波。对比有限元模拟结果和实验结果发现,特征线差分法可以比较准确地捕捉冲击波形状并计算冲击波后流场,从而验证了所提出的三族特征线差分法的准确性。     

钛基纤维炸药水下爆炸性能的初步分析

通过爆炸压力时程曲线分析含钛纤维炸药的压力峰值、水下比冲击波能、比气泡能、质量能量及能量密度变化趋势,通过对所得能量结果分析钛纤维炸药的化学反应过程。结果表明:含钛纤维炸药的压力峰值、比冲击波能随钛纤维含量的提高而降低,比气泡能随钛纤维含量的提高而增大,质量能量及能量密度都随钛纤维含量的提高而增大。随距离的增大,钛纤维炸药压力峰值衰减比RDX的慢,而不同钛纤维含量的钛纤维炸药的比冲击波能、比气泡能在不同距离处随钛纤维含量变化趋势基本一致。根据炸药反应释放的总比能量进行理论分析,得出钛纤维炸药爆炸反应方程式。     

一种爆炸二极管机理研究及熄爆通道尺寸对其性能的影响

依据爆炸逻辑元件的工作原理设计了一种爆炸二极管。实验研究了元件内部结构,确定了关键参数为熄爆通道的长度、隔爆序列。隔爆序列内采用激发装置、一次PETN装药、两次PETN装药不同密度分层装药序列。在A、B端连接导爆索,改变熄爆通道尺寸, 确定分层装药参数,进行传爆可靠性、隔爆安全性实验。结果表明:爆轰信号由A端正向输入时,可以顺利通过10~35 mm的熄爆通道并且可靠引爆B端导爆索,满足可靠性功能;爆轰信号由B端反向输入,在熄爆通道长度为15~35 mm时,爆轰信号在通过隔爆序列、熄爆通道时被可靠阻断无法引爆A端导爆索,满足隔爆安全性功能。最终元件选取长度为15~35 mm的熄爆通道, 确定不同密度分层装药参数作为设计标准。应用于爆破网络设计中,使爆轰波信号在网络中单向传播,增加了网络的安全性。     

Phenylene vinylene‐based electroluminescent polymers with electron transport block in the main chain

We report a new route for the design of soluble phenylene vinylene (PV) based electroluminescent polymers bearing electron‐deficient oxadizole (OXD) and triazole (TZ) moieties in the main chains with the aryloxy linkage. Both series of the PV‐based polymers were prepared by Wittig reaction. By properly adjusting the OXD and/or TZ content through copolymerization, we can achieve an enhanced balance of hole‐ and electron injections, such that the device efficiency is significantly improved. Light‐emitting diodes fabricated from P1, P2, P3, P4, P5, P6, and P7 with the configuration of Indium–Tin Oxide (ITO)/Poly (styrene sulfonic acid) doped poly (ethylenedioxythiophene) (PEDOT)/polymer/Ca/Al, emit bright green light with the maximum peak around 500 nm. For the device using the optimal polymer (P4) as emitting layer, a maximum brightness of 1300 cd/m² at 20 V and a maximum luminance efficiency of 0.325 cd/A can be obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3469–3478, 2006     

卟啉酞菁模型化合物光致电子转移研究

本文采用时间相关单光子计数对卟啉酞菁ＴＴＰ－（ＣＨ２）ｎ－Ｐｃ模型化合物的光致电子转移进行了研究，发现激发Ｐｃ时，呈现单指数衰减，ｎ＝４时电子转移速率减小，活化能，重排能增加，电子转移效率下降，电子转移反应△ＧＣＳ与电荷分离活化络合物衰变速率ＫＣＴ，按以下规律：△Ｇ＾（５）ＣＳ〉△＾（３）ＣＳ〉△＾（４）ＣＳ〉△＾（２）ＣＳ，ｋ＾（２）ＣＳ〉ｋ＾（３）ＣＳ〉ｋ＾（４）ＣＳ〉ｋ＾（５）ｃｓ。其△Ｇ＾