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991.
This paper studies the light scattering and adsorption of nanocrystalline TiO2 porous films used in dye-sensitized solar cells composed of anatase and/or rutile particles by using an optical four-flux radiative transfer model. These light properties are difficult to measure directly on the functioning solar cells and they can not be calculated easily from the first-principle computational or quantitative theoretical evaluations. These simulation results indicate that the light scattering of 1 25 nm TiO2 particles is negligible, but it is effective in the range of 80 and 180 nm. A suitable mixture of small particles (10 nm radius), which are resulted in a large effective surface, and of larger particles (150 nm radius), which are effective light scatterers, have the potential to enhance solar absorption significantly. The futile crystals have a larger refractive index and thus the light harvest of the mixtures of such larger rutile and relatively small anatase particles is improved in comparison with that of pure anatase films. The light absorption of the 10μm double-layered films is also examined. A maximal light absorption of double-layered film is gotten when the thickness of the first layer of 10 urn-sized anatase particles is comparable to that of the second larger rutile layer. 相似文献
992.
993.
采用磁控溅射法制备金团簇纳米颗粒,用透射电镜(TEM)、X射线衍射(XRD)、紫外可见光分光光度计(UV-Vis)和X射线光电子能谱(XPS)等分析手段对其表征,研究了金团簇纳米颗粒的形貌、颗粒度、结构、光吸收性质及物质成份。研究结果表明:制备的金团簇纳米颗粒呈球形,平均粒径在10 nm左右,粒径分布均匀,无团聚、氧化现象,颗粒的结构为面心立方。在519 nm处出现团簇颗粒的表面等离子共振吸收峰,测试得到Au(4f7/2)和Au(4f5/2)电子的结合能分别为83.3 eV和86.9 eV,并且没有出现金的氧化产物。 相似文献
994.
流动注射分析在线研究Cr(Ⅵ)在纳米TiO2表面上的吸附 … 总被引:2,自引:1,他引:1
用溶胶-凝聚法在不同的水解和热处理条件下制备了纳米尺寸的TiO2微粉,所得的TiO2表面性质迥异,粒径从几个纳米到数百个纳米,晶型也由低温煅烧的锐钛型转成高温地的金红石型。利用流动注射微柱富集在线分析方法对Cr离子在纳米TiO2表面上的吸附动力学特性进行了原位表征。 相似文献
995.
The implementation of clean energy techniques, including clean hydrogen generation, use of solar-driven photovoltaic hybrid systems, photochemical heat generation as well as thermoelectric conversion, is crucial for the sustainable development of our society. Among these promising techniques, electrocatalysis has received significant attention for its ability to facilitate clean energy conversion because it promotes a higher rate of reaction and efficiency for the associated chemical transformations. Noble-metal-based electrocatalysts typically show high activity for electrochemical conversion processes. However, their scarcity and high cost limit their applications in electrocatalytic devices. To overcome this limitation, binary catalysts prepared by alloying with transition metals can be used. However, optimization of the activity of the binary catalysts is considerably limited because of the presence of the miscibility gap in the phase diagram of binary alloys. The activity of binary electrocatalysts can be attributed to the adsorption energy of molecules and intermediates on the surface. High-entropy alloys (HEAs), which consist of diverse elements in a single NP, typically exhibit better physical and/or chemical properties than their single-element counterparts, because of their tunable composition and inherent surface complexity. Further, HEAs can improve the performance of binary electrocatalysts because they exhibit a near-continuous distribution of adsorption energy. Recently, HEAs have gained considerable attention for their application in electrocatalytic reactions. This review summarizes recent research advances in HEA nanostructures and their application in the field of electrocatalysis. First, we introduce the concept, structure, and four core effects of HEAs. We believe that this part will provide the basic information about HEAs. Next, we discuss the reported top-down and bottom-up synthesis strategies, emphasizing on the carbothermal shock method, nanodroplet-mediated electrodeposition, fast moving bed pyrolysis, polyol process, and dealloying. Other methods such as combinatorial co-sputtering, ultrashort-pulsed laser ablation, ultrasonication-assisted wet chemistry, and scanning-probe block copolymer lithography are also highlighted. Among these methods, wet chemistry has been reported to be effective for the formation of nano-scale HEAs because it facilitates the concurrent reduction of all metal precursors to form solid-solution alloys. Next, we present the theoretical investigation of HEA nanocatalysts, including their thermodynamics, kinetic stability, and adsorption energy tuning for optimizing their catalytic activity and selectivity. To elucidate the structure–property relationship in HEAs, we summarize the research progress related to electrocatalytic reactions promoted by HEA nanocatalysts, including the oxygen reduction reaction, oxygen evolution reaction, hydrogen evolution reaction, methanol oxidation reaction, and CO2 reduction reaction. Finally, we discuss the challenges and various strategies toward the development of HEAs. 相似文献
996.
997.
Results of charge-transport and magnetic measurements of nanotubular polyaniline (PANI) composites containing Fe_3O_4 nanoparticles (~10nm) synthesized by a "template-free" method are reported. The T^{-1/2} resistivity has been observed, and dc magnetic susceptibility data are fitted to an equation χ=χ^*_P+C/T. With increasing weight ratio of Fe_3O_4, the electrical conductivity and temperature- independent susceptibility χ^*_P increase, and the Curie-type susceptibility is suppressed at low temperatures. Further discussions have been given. The PANI-H_3PO_4/Fe_3O_4 composite containing 27wt% of Fe_3O_4 nanoparticles is superparamagnetic, exhibiting very little hysteresis even at 5K. 相似文献
998.
利用射频磁控溅射系统在不同N2分压的条件下,制备了一系列ZrN/WN纳米多层膜.借助慢正电子湮没技术分析了样品的缺陷性质,采用纳米压痕仪研究了多层膜的力学性能.结果发现:N2分压为0.4Pa的多层膜具有最小的空位型缺陷浓度,其中心层和膜基结合层的平均S参数分别为0.4402和0.4641,而较低或较高的N2分压都可能导致空位型缺陷浓度的增加.随着空位型缺陷浓度的减小,多层膜的硬度和临界载荷增大.对于空位型缺陷浓度最小的多层膜,其硬度和临界载荷达到最大值,分别为34.8GPa和100mN,说明较低的缺陷浓度有利于提高多层膜的力学性能.
关键词:
ZrN/WN纳米多层膜
缺陷性质
力学性能
慢正电子湮没 相似文献
999.
1000.
以十六烷基三甲基溴化胺(CTAB)为软模板剂,采用种子法制备出三角形银纳米粒子,应用透射电镜、能量散射X射线谱仪、紫外 可见分光光度计研究了粒子的性能。结果表明:所得三角形银纳米粒子是面心立方单晶,边长随着种子加入量的减少而递增,可在20~100 nm范围内调节;CTAB以薄膜形式包覆于粒子表面阻止其氧化,粒子胶体的吸收光谱呈现典型的三角形粒子吸收峰。用扫描电镜观测到粒子在硅片上自组装成一定的2维阵列结构。 相似文献