Light scattering of nanocrystalline TiO2 film used in dye-sensitized solar cells |
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Authors: | Xiong Bi-Tao Zhou Bao-Xue Bai Jing Zheng Qing Liu Yan-Biao Cai Wei-Min and Cai Jun |
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Institution: | School of Environmental Science and Engineering, Shanghai
Jiao Tong
University, Shanghai 200240, China |
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Abstract: | This paper studies the light scattering and adsorption of
nanocrystalline TiOlight scattering, modelling,
films, dye-sensitized solar cellsProject supported by the Program of
Science and Technology Commission of Shanghai Municipality (Grant No
03DZ12032) and the Program for New Century Excellent Talents in
University in China (Grant No NCET-04-0406).4225F, 61463/7/2008 12:00:00 AMThis paper studies the light scattering and adsorption of
nanocrystalline TiOlight scattering, modelling,
films, dye-sensitized solar cellsProject supported by the Program of
Science and Technology Commission of Shanghai Municipality (Grant No
03DZ12032) and the Program for New Century Excellent Talents in
University in China (Grant No NCET-04-0406).4225F, 61463/7/2008 12:00:00 AMThis paper studies the light scattering and adsorption of
nanocrystalline TiOlight scattering, modelling,
films, dye-sensitized solar cellsProject supported by the Program of
Science and Technology Commission of Shanghai Municipality (Grant No
03DZ12032) and the Program for New Century Excellent Talents in
University in China (Grant No NCET-04-0406).4225F, 61463/7/2008 12:00:00 AMThis paper studies the light scattering and adsorption of
nanocrystalline TiO$_2$ porous films used in dye-sensitized solar
cells composed of anatase and/or rutile particles by using an
optical four-flux radiative transfer model. These light properties
are difficult to measure directly on the functioning solar cells and
they can not be calculated easily from the first-principle
computational or quantitative theoretical evaluations. These
simulation results indicate that the light scattering of 1--25\,nm
TiO$_{2}$ particles is negligible, but it is effective in the range
of 80 and 180\,nm. A suitable mixture of small particles (10\,nm
radius), which are resulted in a large effective surface, and of
larger particles (150\,nm radius), which are effective light
scatterers, have the potential to enhance solar absorption
significantly. The rutile crystals have a larger refractive index
and thus the light harvest of the mixtures of such larger rutile and
relatively small anatase particles is improved in comparison with
that of pure anatase films. The light absorption of the 10\,$\mu$m
double-layered films is also examined. A maximal light absorption of
double-layered film is gotten when the thickness of the first layer
of 10\,nm-sized anatase particles is comparable to that of the
second larger rutile layer. |
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Keywords: | light scattering modelling films dye-sensitized solar cells |
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