排序方式: 共有114条查询结果,搜索用时 15 毫秒
71.
1,3,5,7-四甲基-2,6,8-三乙基吡咯甲川-BF2络合物的合成及晶体结构 总被引:1,自引:1,他引:0
合成了标题化合物 ,借助于元素分析、红外光谱、核磁共振氢谱、质谱以及X 射线单晶衍射等分析方法确定了它的结构。该化合物属于三斜晶系 ,空间群为P-1(No 2 ) ,化学式 :C19H2 7BF2 N2 。晶胞参数 :a =1 2 2 5 7( 2 ) ,b=1 7830 ( 8) ,c=0 8877( 2 )nm ,α =10 0 2 6 ( 2 ) ,β =10 7 5 7( 1) ,γ =76 96 ( 2 )°,V =1 7892( 9)nm3 ,Mr=332 2 4,Z =4,Dc=1 2 33g·cm-3 ,μ(MoKα) =0 86cm-1,F( 0 0 0 ) =712 0 0 ,R =0 0 5 1,Rw=0 0 6 0。化合物中除 2 ,6 ,8位的三个甲基 (C( 12 ) ,C( 15 ) ,C( 18) )和氟原子 (F( 1) ,F( 2 ) )外 ,其余非氢原子近似组成一个大平面结构。在对其晶体结构进行详细分析的基础上 ,我们还初步讨论了它的分子结构与光谱及激光性能的关系。 相似文献
72.
73.
Optical waveguides are fabricated in Nd3^+:y3^+:SrF2 crystals by a 1-kHz femtosecond laser using the double-line approach. Waveguides with different separations (10, 15, and 20 μm) between two consecutive optical breakdown tracks are produced, and their optical performances are explored by end-fire coupling to 780-and 532-nm lasers. Propagation loss of the waveguide with 20-pro separation is estimated. The micro- photohmlinescence and micro-Raman spectra indicate that the original fluorescence and lattice structure of the Nd3^+:y3^+:SrF2 crystals are well preserved in the waveguide. Therefore, the obtained waveguide structures are promising candidate for application in integrated waveguidc lasers. 相似文献
74.
75.
Six novel pyrromethene BF2 complexes,of which five compounds have not been reported,were synthesized and characterized.Their relationships between st ructure and photophysical behavior were studied with the aid of fluorescence and triplet state absorption spectra.The results indicate that,compared to 8 alkyl pyrromethene BF2 complexes,the compounds containing 8 aryl exhibit high fluore scence quantum yield and rather low triplet state absorption. 相似文献
76.
掺杂在晶体Y2 SiO5(YSO)中的Pr3 ,运用脉冲激光激发 3H4 → 1 D2 跃迁 ,粒子通过非辐射能量转移从能级 1 D2 转移到能级 3P0 ,测得了对应于 3P0 → 3H4 跃迁的反斯托克斯荧光光谱 ,由此可确定 3H4 的Stark分裂能级以及 3P0 能级的能量高度。与运用激光激发 3H4 → 1 D2 跃迁 ,通过观察 1 D2 → 3H4 斯托克斯荧光光谱确定3H4 的Stark分裂能级方法相比 ,该过程避免了不同晶点位置中 (Crystallographicsite)Pr3 的 1 D2 能级间的能量转移影响 ,从而具有较高的确定性。同时 ,我们观察了反斯托克斯荧光的时间特性 相似文献
77.
We study theoretically intense terahertz radiation from multi-color laser pulse with uncommon frequency ratios. Comparing the two-color laser scheme, of which the uncommon frequency ratio should be set to be a specific value, we show that by using multi-color harmonic laser pulses as the first pump component, the lasers as the second pump component can be adjusted in a continuous frequency range. Moreover, these multi-color laser pulses can effectively modulate and enhance the terahertz radiation, and the terahertz yield increases with the increase of the wavelength of the uncommon pump component and is stable to the laser relative phase. Finally, we utilize the electron densities and velocities of ionization events to illustrate the physical mechanism of the intense terahertz generation. 相似文献
78.
79.
自行搭建的自锁模钛宝石激光器工作在下稳区的上边界附近,采用熔融石英棱镜对在激光器谐振腔的腔内和腔外同时进行群速度色散补偿.随着腔内棱镜对提供色散补偿的变化,输出激光脉冲的频谱会突然展宽至664—840nm,其空间模式也由基横模变化至衍射环状结构,这是受激拉曼散射和四波混频效应导致锁模激光脉冲频谱进一步展宽的结果.在此状态下自锁模钛宝石激光器可实现670—865nm范围的波长调谐.如此宽的频谱为钛宝石激光器产生亚10fs激光脉冲提供了必要的条件.
关键词:
飞秒激光脉冲
受激拉曼散射
四波混频
群速度色散 相似文献
80.
Selective excitation and suppression of coherent anti-Stokes Raman scattering by shaping femtosecond pulses 下载免费PDF全文
Femtosecond coherent anti-Stokes Raman scattering (CARS)
suffers from poor selectivity between neighbouring Raman levels
due to the large bandwidth of the femtosecond pulses. This paper
provides a new method to realize the selective excitation and
suppression of femtosecond CARS by manipulating both the probe and
pump (or Stokes) spectra. These theoretical results indicate that
the CARS signals between neighbouring Raman levels are
differentiated from their indistinguishable femtosecond CARS spectra
by tailoring the probe spectrum, and then their selective excitation
and suppression can be realized by supplementally manipulating the
pump (or Stokes) spectrum with the $\pi $ spectral phase step. 相似文献