Site-specifically Hydrolytic Cleavage of Oxidized Insulin B Chain With Cu(II) Ion

Selectively chemical cleavage of peptides and proteins is one of the most important reactions in both chemical and biochemical processes. Over the past decade, the interaction of palladium(II) complexes with methionine, cysteine and histidine-containing peptides and proteins and the hydrolytic cleavage of the corresponding amide bond by Pd(II) complexes have been extensively studied1-13. However, reports concerning the directly selective hydrolysis of peptides and proteins with other simple …     

A New ent-Kaurane Diterpenoid from Isodon enanderianus

Isodon enanderianus (Hand. -Mazz.) H. W. Li, has been used in folk medicine as anti-inflammatory and detoxified agent1. The Isodon genus is known to be rich in ent-kaurane diterpenoids, a series of new ent-kaurane diterpenoids have been isolated from the dried leaves of I. enanderianus2-4. In order to find more biologically active substances, we have carefully investigated the chemical constituents of I. enanderianus collected in Shiping county of Yunnan province, and as a result, enanderi…     

Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N-dimethylbenzimidazoline

Reduction of C=N double bonds has been recognized as an important reaction both in organic chemistry and bio-chemistry1. Hantzsch 1,4-dihydropyridine (HEH, one of NADH model compounds) has been reported as a reductive reagent for imines2. However, application of dihydropyridines as practical reducing reagents in organic synthesis is limited because of their instability3. Like NADH models, 2-phenyl-N, N-dimethylbenzimidazoline (PDMBI) is an efficient electron and hydrogen donor (Eox = 0…     

Retention Behaviors of Uronic Acid-containing Polysaccharides and Neutral Polysaccharides in HPGPC

The determination of molecular weights (Mw) of polysaccharides has served as an important process since the physical properties of the polysaccharides are closely related to their Mw and/or molecular weights distribution (MWD). For Mw and MWD determinations, high performance gel permeation chromatography (HPGPC) has gained wide acceptance as a preferred method due to its high sensitivity, speed and reproducibility. In chromatography, it is well known that the molecular weights are determ…     

Si(111)分子束外延生长时RHEED强度振荡的观察

本文报道用反射式高能电子衍射的强度振荡测量来观察Si(111)衬底上分子束外延的生长行为,观察到了双原子层的振荡模式。振荡的衰减和恢复特性不同于Si(100)衬底上的生长行为,而同GaAs分子束外延时的特性非常相似。 关键词：     

成败型串联系统可靠性置信下限的近似解

成败型串联系统可靠性置信下限的经典精确解的求法早在1957年已由Buehler提出。但由于经典精确解的计算过于复杂,因此六十年代以来学者们相继提出了多种求近似解的方法。但他们在提出求近似解的方法时往往仅仅提出方法本身,给出个别的数字例子,而对方法所得结果的好坏很少评价。显然,正确地评价各种近似方法的好坏,通过比较,从中挑选一种在理论上较有依据,且在实际使用中又较为可取的近似方法是至为重要且有实际意义的。 本文通过大量的模拟计算,对近年来国内外学者们所推崇的和广为使用的六种近似方法(MMLI,LR,AWI,WOODS,AO,L-M法)作了多方面的比较,并着重对L-M法的计算结果进行了分析研究,在这一基础上,我们挑选出较为理想的近似方法—L-M法。     

New conversion of Friendlnder reaction of 3-amino-1H-benzo[f]chromene-2-carbonitriles with cyclohexanone

Two different skeletons of heterocyclic compounds,quinoline and quinazolinone analogs could be obtained by a novel one-pot synthesis from substituted 3-amino-1 H-benzo[f]chromene-2-carbonitrile derivatives and cyclohexanone in DMF in the catalyst of anhydrous zinc chloride under reflux.A plausible mechanism was proposed.     

三角级数属于Ba空间的充分必要条件

该文给出了正弦级数和余弦级数在系数满足NBV条件时属于Ba空间的充分必要条件,所得结论 为Ba空间中的首个此类结果,同时也是对L_p空间中已有结论的本质性推广.     

81Zr和85Mo的β延迟质子衰变

运用p-γ符合测量技术，详细研究了T     

Mntz有理逼近的点态估计

给定 M >0 ,设Λ ={λn} ∞n=1是一个实数序列 ,满足 0≤λ1<λ2 <… ,且对所有 n≥ 1,有λn+ 1-λn≥ Mn .本文得到了 Müntz系统 { xλn}有理逼近的一个点态估计 .