毛细现象演示器

玻璃毛细管插在水银槽中,管内水银面低于管周围的水银面。由于水银是不透明的物质,学生难于从正面很好地看清管内的水银面。如果能消除毛细管外正对于我们的前后两面的水银,而保留住管外两侧的水银。那么,我们既能看到管内的水银面,同时又可比较管内、外水银面的高度。为此,我们用3mm 厚的有机玻璃板割成条或块,用丙铜粘成如下二图所示的扁形液槽和毛细管合成装置,达到了预期的效果。     

GaP衬底上分子束外延Si时P偏析的抑制

用Si分子束外延技术在GaP(111)衬底上生长Si时,发现Si外延层表面存在P偏析,根据俄歇电子能谱(AES),反射式高能电子衍射(RHEED)在一系列不同实验条件下的结果,本文对P偏析产生的机制、外延层表面再构与P偏析之间的关系作了分析和讨论,得出偏析主要来自外延Si原子与衬底P元素之间的相互交换。在此基础上提出了一种能有效地抑制P偏析同时又改善外延层质量的新的Si/GaP(111)异质结制备方法。 关键词：     

用RHEED强度振荡锁相外延控制Ge/Si超晶格的生长

观察了Ge,Ge/Si交替外延时的反射式高能电子衍射(RHEED)强度振荡现象,并由此研究了Si(100)和Si(111)衬底上分子束外延Ge,Ge/Si超薄叠层的生长行为和生长特性。利用RHEED强度振荡,锁相控制生长了Ge(2ML)/Si(2ML),Ge(4ML)/Si(4ML)超薄超晶格。 关键词：     

激光径向偏振光栅反射镜的研究

径向偏振光是近些年引起广泛关注的一种新型偏振光,它在粒子操控、金属切割和提高显微镜分辨率方面具有广阔的应用前景。径向偏振光可以通过在激光器谐振腔内应用径向偏振光栅反射镜来获得。首先在顶层刻蚀光栅反射镜的模型上通过自编程序分析光栅反射镜各参数对光栅性能的影响,然后设计出光栅反射镜复合结构并结合微纳加工工艺进行了可行性分析。     

有理插值的基本特征

１　引　言 记 ｎ为次数不超过ｎ的一元多项式函数类,约定零多项式的次数为－∞,即ｄｅｅ（０）＝－∞;记 ｍ,ｎ为分子属于 ｍ,分母属于 ｎ＼｛０｝的一元有理函数类．我们约定：本文所采用的概念和记号将与文［１］保持一致,本文中“有理插值问题”系指文［１］中“有理插值问题（２．１）（２．２）”,并简记为ＲＩＰ． 文［１］在［２－８］的基础上引进了ＲＩＰ的　方程组,定义了　插值式,指出了其与经典结果的关系,这为我们分析ＲＩＰ提供了一个有力的工具．本文将在文［１］的基础上,深入讨论ＲＩＰ的基本特征．在本节和下…     

Hybrid Composite of Polyaniline Containing Carbon Nanotube

Among various conducting polymers, polyaniline (PANI) is a unique and promising candidate for practical applications because it is not only highly stable in air and in some solvents, but also exhibits dramatic changes in its electronic structure and physical properties in protoactivate state1,2,3. The carbon nanotubes (CNTs) have been proven to possess exotic properties, such as high mechanical strength, flexibility and electric conductivity. The study of carbon-based nanostructures and ma…     

One-Pot Synthesis of N-Boc-2, 5-bis(trimethylsilyl)pyrrolidine

Since Daly reported the structure of epibatidine and its potent analgesic activity in 19921, study on the synthesis of epibatidine and its derivatives and relationships between the structure and activity of epibatidine has received much attention2. During the course of our research for the synthesis of epibatidine derivatives, N-boc-2, 5-bis(trimethylsilyl)pyrrolidine 4 was used as the key intermediate to construct the skeleton of epibatidine via the 1, 3-dipolar cycloaddition (Scheme 1). Ac…     

Ni-B/TiO_2 Amorphous Catalyst Used in Heavy Arenes of Petrochemicals Hydrogenation

The various distillation of petroleum contains arenes. For environmental protection, the hydrogenation of arenes becomes important. The amorphous alloy is a new class of material with special catalytic properties for reduction arenes1-4. In this paper, we prepared the Ni-B/TiO2 and Ni-B/Al2O3 amorphous catalysts by impregnation and reduction by KBH4 solution. Their catalytic activities for hydrogenation arenes were tested by the hydrogenation of 1,3,5-trimethylbenzene (TMB) in the co…     

Molecular Arrangement of a Bolaamphiphilic Anthrancene Derivative in Langmuir-Blodgett Film

Langmuir monolayer at the air/water interface is the basis to understand the molecular arrangement and to fabricate the organized molecular films1. Bolaamphiphiles describes the molecules in which two head functional groups are linked by one or two hydrophobic chains2,3. In comparison with the one-headed amphiphile, abundant configurations of Langmuir monolayer are expected in bolaamphiphiles. Generally, three kinds of configurations of the Langmuir monolayers of bolaamphiphile at the air/w…     

Studies on the Interactions between Potassium oxalato-oxodiperoxovanadate and Histidine by NMR and MS

K3[VO(O2)2(C2O4)]2H2O, (abbr. BpV (ox)) pertains to peroxovanadium (abbr. pV) complexes, which have been attracted considerable attention nowadays, since they are inhibitors of tyrosine phosphatase and may be developed into a new kind of drugs for the treatment of diabetes1. According to the evidence on water-biperoxovanadium, the molecular mechanism of insulin-like effects of pV involves in irreversibly oxidizing the catalytic cysteine at the active site of the target enzyme2,3. However…