首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   583篇
  免费   19篇
  国内免费   62篇
化学   259篇
力学   59篇
数学   139篇
物理学   207篇
  2022年   1篇
  2021年   3篇
  2019年   1篇
  2016年   1篇
  2015年   4篇
  2013年   6篇
  2012年   5篇
  2011年   88篇
  2010年   37篇
  2009年   23篇
  2008年   10篇
  2007年   11篇
  2006年   15篇
  2005年   27篇
  2004年   116篇
  2003年   42篇
  2002年   48篇
  2001年   59篇
  2000年   10篇
  1999年   13篇
  1998年   17篇
  1997年   10篇
  1996年   8篇
  1995年   6篇
  1994年   6篇
  1993年   29篇
  1992年   23篇
  1991年   17篇
  1990年   8篇
  1989年   14篇
  1988年   3篇
  1987年   1篇
  1986年   1篇
  1982年   1篇
排序方式: 共有664条查询结果,搜索用时 16 毫秒
1.
基于X射线管的X射线荧光计算机断层扫描术(CT)受多种因素影响,成像质量不佳,几何参数误差是制约其高质量图像重建的重要因素之一.本文分析成像二维平面模体与探测器相对位置偏移对投影数据的影响,并基于原始投影数据和原始重建图像再投影数据的局部线性关系实现几何偏移参数校正;利用Geant4模拟存在偏移参数的扇束X射线荧光CT系统,使用模拟投影数据验证校正方法.研究结果表明:该方法能计算出相对精确的几何偏移量,有效消除几何参数误差对重建图像的影响,校正后的重建图像信息熵降低,平均梯度和标准差提高,图像质量提升.  相似文献   
2.
纵向数据下广义估计方程估计   总被引:1,自引:0,他引:1  
广义估计方程方法是一种最一般的参数估计方法,广泛地应用于生物统计、经济计量、医疗保险等领域.在纵向数据下,由于组间数据是相关的,为了提高估计的效率,广义估计方程方法一般需要考虑个体组内相关性.因此,大多数文献对个体组内的协方差矩阵进行参数假设,但假设的合理性及协方差矩阵估计的好坏对参数估计效率产生很大影响,同时参数假设也可能导致模型误判.针对纵向数据下广义估计方程,本文提出了改进的GMM方法和经验似然方法,并对给出的估计量建立了大样本性质.其中分块的思想,避免了对个体组内相关性结构进行假设,从这种意义上说,这种方法具有一定的稳健性.我们还通过两个模拟的例子,考察了文中提出估计量的有限样本性质.  相似文献   
3.
Aiming at regional services,the space segment of COMPASS (Phase I) satellite navigation system is a constellation of Geostationary Earth Orbit (GEO),Inclined Geostationary Earth Orbit (IGSO) and Medium Earth Orbit (MEO) satellites.Precise orbit determination (POD) for the satellites is limited by the geographic distribution of regional tracking stations.Independent time synchronization (TS) system is developed to supplement the regional tracking network,and satellite clock errors and orbit data may be obtai...  相似文献   
4.
Three novel Zn(II) complexes,[Zn4L1Cl4]-3H2O(1),[Zn4L2Cl4]-2DMF(2) and[Zn4L3Cl4]H2O(3),have been synthesized and structurally characterized.In these complexes,interesting 32-membered dodecadentate macrocyclic ligands were generated in situ by ’2 + 2’ type condensation reactions between a tetraamine and various dialdehydes.All the complexes are isostructurally tetranuclear Zn(Ⅱ) complexes,containing endogenous alkoxo and phenoxo bridges.Applications of the macrocyclic ligands as Zn2+ sensors have been investigated.Take H4L1 for example,it exhibits a 4-fold fluorescence enhancement upon the addition of 2 equiv.of Zn2+ in MeOH.  相似文献   
5.
Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR(1H and 31P),CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.  相似文献   
6.
Cu-Fe composite oxides were prepared by co-precipitation method and tested for higher alcohol synthesis from syngas. The selectivity to C2+OH and C6+OH in alcohol distribution was very high while the methane product fraction in hydrocarbon distribution was rather low, demonstrating a promising potential in higher alcohols synthesis from syngas. The distribution of alcohols and hydrocarbons approximately obeyed Anderson-Schulz-Flory distribution with similar chain growth probability, indicating alcohols and hydrocarbons derived from the same intermediates. The effects of Cu/Fe molar ratio, reaction temperature and gas hourly space velocity (GHSV) on catalytic performance were studied in detail. The sample with a Cu/Fe molar ratio of 10/1 exhibited the best catalytic performance. Higher reaction temperature accelerated water-gas-shift reaction and led to lower total alcohols selectivity. GHSV showed great effect on catalytic performance and higher GHSV increased the total alcohol selectivity, indicating there existed visible dehydration reaction of alcohol into hydrocarbon.  相似文献   
7.
Output nonlocality and nonclassicality for the two modes are investigated in an entanglement laser sys-tem. Within the framework of a quantum theory of multiwave mixing,nonlocality and nonclassicality are discussed according to the violations of Bell inequality and Cauchy-Schwarz inequality. It is found that both nonlocality and nonclassicality can be fulfilled in the outside cavity fields under certain conditions. It is also shown that there are some nonclassical states that do not show nonlocality.  相似文献   
8.
Experimental results indicate three regimes for cracking in a ferroelectric double cantilever beam (DCB) under combined electromechanical loading. In the loading, the maximum amplitude of the applied electric field reaches almost twice the coercive field of ferroelectrics. Thus, the model of small scale domain switching is not applicable any more, which is dictated only by the singular term of the crack tip field. In the DCB test, a large or global scale domain switching takes place instead, which is driven...  相似文献   
9.
Aperiodic molybdenum/silicon (Mo/Si) multilayer designed as a broadband reflective mirror with mean reflectivity of 10% over a wide wavelength range of 12.5-28.5 nm at incidence angle of 5° is developed using a numerical optimized method. The multilayer is prepared using direct current magnetron sputtering technology. The reflectivity is measured using synchrotron radiation. The measured mean reflectivity is 7.0% in the design wavelength range of 12.5-28.5 nm. This multilayer broadband reflective mirror can be used in extreme ultraviolet measurements and will greatly simplify the experimental arrangements.  相似文献   
10.
The sloshing of inviscid liquid of stratified density in a rectangular tank is analyzed.As the flow is no longer irrotional,the governing equation is found to be quite different from the Laplace equation used for the liquid of constant density.In particular it contains terms of mixed temporal and spatial derivatives.The problem is solved based on the variable separation method and Laplace transform for the constant Vaisala-Brunt frequency.It is found that the stratification of density may have small effects...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号