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41.
Synthesis and characterization of a single diamond crystal with a high nitrogen concentration 下载免费PDF全文
In this paper,we explore diamond synthesis with a series of experiments using an Fe-Ni catalyst and a P3N5 additive in the temperature range of 1250-1550 ℃ and the pressure range of 5.0-6.3 GPa.We also investigate the influence of nitrogen on diamond crystallization.Our results show that the synthesis conditions(temperature and pressure) increase with the amount of P3N5 additive increasing.The nitrogen impurity can significantly influence the diamond morphology.The diamonds stably grow into strip and lamellar shapes in the nitrogen-rich environment.The Fourier-transform infrared spectrum shows that the nitrogen concentration increases rapidly with the content of P3N5 additive increasing.By spectrum analysis,we find that with the increase of the nitrogen concentration,the Ib-type nitrogen atoms can aggregate in the A-centre form.The highest A-centre nitrogen concentration is approximately 840 ppm. 相似文献
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Synthesis of coarse-grain diamond crystals is studied in a China-type SPD6× 1670T cubic high-pressure apparatus with high exact control system. To synthesize high quality coarse-grain diamond crystals, advanced indirect heat assembly, powder catalyst technology and optimized synthesis craft are used. At last, three kinds of coarse- grain diamond (about 0.85 mm) single crystals with hexahedron, hex-octahedron and octahedron are synthesized successfully under HPHT (about 5.4 GPa, 1300-1450℃). The growth characters of different shape crystals are discussed. The results and techniques might be useful for the production of coarse-grain diamonds. 相似文献
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采用高压合成技术,在1.5 GPa,900 K的合成压力和温度条件下成功合成出了系列Fe置换掺杂型方钴矿化合物FexCo4-xSb12 ,其中x= 0,0.2,0.6,0.8. 详细研究了FexCo4-xSb12 样品在300 K ~ 700 K温度范围内的电阻率、Seebeck系数和功率因子(S2σ)随温度和Fe掺杂量的变化关系. 研究结果表明:在测试温度范围内,随着温度的升高,样品的电阻率和Seebeck系数逐渐增大. 随着Fe含量的增加,样品的电阻率和Seebeck系数先增加后减小. 与常压下相同样品比较,高压合成方法制备的样品的电学输运特性有了明显的提高. 上述研究结果表明,高压合成技术在制备热电材料方面能够有效地提高样品的电输运特性. 相似文献
45.
以有限元法为理论分析手段模拟分析了国产六面顶压机配套顶锤内部的温度场和热应力分布.探寻出了XKY-6×2000 MN型六面顶压机顶锤内部的温度场分布以及热应力取值.模拟结果表明加热顶锤内部温度分布不均匀,不均匀的温度分布产生了热剪切应力,热剪切应力峰值达到0.62 GPa,分布在41.5°小斜面上.加热顶锤内部的剪切应力值较非加热锤内部的剪切应力值高出18.0%.模拟分析结果与金刚石的高压合成实验事实相符,在理论上解释了加热顶锤使用寿命较非加热顶锤使用寿命短的原因,此项工作对于提高大顶锤使用寿命,降低生产
关键词:
热应力
顶锤
有限元法
工业金刚石 相似文献
46.
Synthesis of large diamond crystals containing high-nitrogen concentration at high pressure and high temperature using Ni-based solvent by temperature gradient method 下载免费PDF全文
This paper reprots that with Ni-based catalyst/solvent and with a dopant of NaN 3,large green single crystal diamonds with perfect shape are successfully synthesized by temperature gradient method under high pressure and high temperature in a China-type cubic anvil high-pressure apparatus (SPD-6×1200),and the highest nitrogen concentration reaches approximately 1214-1257 ppm calculated by infrared absorption spectra.The synthesis conditions are about 5.5 GPa and 1240-1300 C.The growth behaviour of diamond with high-nitrogen concentration is investigated in detail.The results show that,with increasing the content of NaN 3 added in synthesis system,the width of synthesis temperature region for growth high-quality diamonds becomes narrower,and the morphology of diamond crystal is changed from cube-octahedral to octahedral at same temperature and pressure,the crystal growth rate is slowed down,nevertheless,the nitrogen concentration doped in synthetic diamond increases. 相似文献
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Different effect of NiMnCo or FeNiCo on the growth of type-Ⅱa large diamonds with Ti/Cu as nitrogen getter 下载免费PDF全文
In order to synthesize high-quality type-Ⅱa large diamond, the selection of catalyst is very important, in addition to the nitrogen getter. In this paper, type-IIa large diamonds are grown under high pressure and high temperature(HPHT) by using the temperature gradient method(TGM), with adopting Ti/Cu as the nitrogen getter in Ni_(70)Mn_(25)Co_5(abbreviated as NiMnCo) or Fe_(55)Ni_(29)Co_(16)(abbreviated FeNiCo) catalyst. The values of nitrogen concentration(N_c) in both synthesized high-quality diamonds are less than 1 ppm, when Ti/Cu(1.6 wt%) is added in the FeNiCo or Ti/Cu(1.8 wt%) is added in the NiMnCo. The difference in solubility of nitrogen between both catalysts at HPHT is the basic reason for the different effect of Ti/Cu on eliminating nitrogen. The nitrogen-removal efficiency of Ti/Cu in the NiMnCo catalyst is less than in the FeNiCo catalyst. Additionally, a high-quality type-Ⅱa large diamond size of 5.0 mm is obtained by reducing the growth rate and keeping the nitrogen concentration of the diamond to be less than 1 ppm, when Ti/Cu(1.6 wt%) is added in the FeNiCo catalyst. 相似文献
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结合高能球磨和高温高压实验技术,制备了块体TiN/TiB2纳米复合材料。通过X射线衍射和拉曼光谱对材料的微观结构进行了研究。结果表明,采用金属Ti和六方BN为原料,在球磨过程和高温高压实验过程中,TiN先于TiB2形成,球磨70 h后有少量的纳米晶TiN开始形成。在高温高压实验中,在样品腔的合成温度低于1 300 ℃时,没有TiB2出现;当温度达到1 300 ℃后,合成出了TiN和TiB2的复合材料。对所合成的块状材料的热膨胀性和导电性能进行了测试。 相似文献