Sn类钙钛矿太阳电池薄膜的掺杂改性研究

采用一步法分别制备了Sn类CH3NH3Sn I3和Pb类CH3NH3Pb I3钙钛矿太阳电池薄膜材料,并对其表面形貌、微观结构、吸收光谱和电池器件性能进行了表征和测试。研究结果表明:Sn类钙钛矿材料的吸收光谱相对于Pb类钙钛矿材料发生了明显的红移,吸收截止波长从800 nm上升到950 nm左右,光学带隙由1.45 e V降低至1.21 e V左右;Sn类钙钛矿材料的光谱吸收范围明显扩大,但吸收强度有所降低,相应太阳电池器件的光电转换效率也明显低于Pb类钙钛矿太阳电池,分别为2.05%和6.71%。而Br的掺杂可使Sn类钙钛矿材料带隙变宽,吸收光子能量增大,电池器件的开路电压也相应提高。当Br含量由0增加至完全替代I时,Sn类钙钛矿材料逐渐由黑褐色转变为黄色,光学带隙增大至1.95 e V,但吸收截止波长由950 nm降低至650nm。值得提及的是当Br含量为0.5时,电池器件的光电转换效率可由最初的2.05%提升至2.94%。     

苯乙烯-对叔丁基苯乙烯-间戊二烯三元共聚物制备及表征北大核心CSCD

相对于异戊二烯和丁二烯传统二烯烃,新型间戊二烯单体可以通过阴离子共聚合实现特殊序列结构共聚物,如交替共聚物。本文以间戊二烯、苯乙烯和对叔丁基苯乙烯为共聚单体,通过丁基锂引发聚合合成系列二元及三元共聚物,重点考察了共聚动力学和共聚物的微观结构。实验结果表明:(1)聚合动力学显示共聚合符合经典一级反应特征,共聚单体可以转化完全;(2)核磁氢谱在线分析表明共聚单体等摩尔消耗,核磁氢谱和碳谱证明了二元交替共聚结构;(3)二元及三元共聚均具有明显的活性可控聚合特征,分子量与理论值高度吻合,分子量分布D均小于1.20;(4)示差扫描量热(DSC)结果显示交替共聚物是一类特殊的半结晶聚合物,玻璃化转变温度Tg可以通过调控共聚单体比例微调,Tm在100~120℃范围;(5)基于间戊二烯特殊的二元交替共聚,推测了可能的聚合机理。     

Revisit to frozen-in property of vorticity

Considering some simple topological properties of vorticity vector, the frozen-in property of vorticity herein is revisited. A vortex line, as is analogous to velocity vector along a streamline, is defined as such a coincident material(curve) line that connects many material fluid elements, on which the local vorticity vector for each fluid element is also tangent to the vortex line. The vortex line evolves in the same manner as the material line that it is initially associated with. The vortex line and the material line are both oriented to the same directions, and evolve with the proportional magnitude, just like being ‘frozen' or ‘glued' to the material elements of the fluid under the barotropic assumption. To relax the limits of incompressible and barotropic atmosphere, the frozen-in property is further derived and proved in the baroclinic case. Then two effective usages are given as examples. One is the derivation of potential vorticity conservation from the frozen-in property in both barotropic and baroclinic atmospheres, as a theory application, and the other is used to illuminate the vorticity generation and growth in ideal cases and real severe weather process, e.g., in squall line, tornado, and other severe convection weather with vortex. There is no necessity to derive vorticity equation, and this method is very intuitive to explain vorticity development qualitatively, especially for fast analysis for forecasters. Certainly, by investigating the evolution of vortex line, it is possible to locate the associated line element vector and its development on the basis of the frozen-in property of vorticity. Because it is simple and visualized, it manifests broad application prospects.     

五维自动调整差动共焦间隙测量方法

为精确、快速测量镜组内各透镜间的轴向间隙,提出一种基于五维自动调整的差动共焦间隙测量方法。该方法根据CCD探测器实时获取的光斑信号检测被测镜组光轴的平移偏差与倾斜偏差,依据偏差信息、通过五维自动调整技术实现镜组高精度调整,再利用差动共焦高精度层析定焦和镜组内部光线追迹实现轴向间隙高精度测量。分析和实验表明,本方法可以有效提高姿态调整效率3.4倍,透镜间隙重复测量精度可达到0.53μm。该方法为实现镜组间隙的快速高精度测量提供了有效途径,同时还为透镜的中心厚度、焦距、半径等多种参数快速高精度测量提供了有效方法。     

浅谈大学物理实验教学改革

首先对大学物理实验教学的重要性以及教学实践中出现的问题作了阐述,然后从三个方面提出了对大学物理实验教学的改革思路：一方面在实验内容的安排以及实验时间上作适当的词整,另一方面通过加强网络资源建设提高预习效果,最后是定期开展大学物理实验操作技能大赛。     

动态应力场作用下线性啁啾光栅光谱特性研究

目前柔性结构损伤检测需多个传感器,且需要探测器具有极高的采集频率。光纤光栅具有动态响应快、易实现分布式测量等特点,为解决上述问题提供了有效的途径,提出采用线性啁啾光栅(LCFBG)实现动态应力场探测。首先,用传输矩阵理论建立了LCFBG反射光谱应变传感模型,用衰减正弦函数模拟沿LCFBG分布的动态应力场。通过仿真实验,详细研究了LCFBG反射光谱对不同振幅、不同衰减系数与不同传播速度动态应力场的响应特性。实验结果表明,LCFBG反射光谱的反射率、波长变化与光谱形状均与动态应力场上述参数有关,但是LCFBG反射光谱对动态应力场不同参数的响应规律不同。在一定范围内,LCFBG反射光谱的最大反射率随动态应力场幅值与速度的增大而增大,最终趋于一稳定值,但其随阻尼系数增大而减小。最后,研制了以LCFBG为敏感元件的传感器,并构建了动态应力场实验平台,实验结果与仿真实验数据基本一致。提供了一种通过实时采集LCFBG全光谱信息探测动态应力场的新方法。     

高速摄影成像分析声带振动发声的前后不对称性

高速摄影成像直接观察到声带振动的前后不对称性。将11个离体狗喉声带进行发声实验,设置3组声门下压分别为10 cm H₂O,20 cm H₂O和30 cm H₂O,利用高速摄像仪和传声器,分别记录不同声门下压的声带振动图像和声信号.对高速摄影成像与同步采集的声信号基频进行定量分析和比较,基频均随声门下压的增大而增加。此外,对两种测量方法得到的基频进行相关分析比较,得到在同一声门下压下两种方法的基频相关系数均大于0.9,表明高速摄影成像得到的基频与声信号的基频具有高度相关性。高速摄影成像能直观地测量声带振动行为,对研究声带振动发声机理提供了有价值的测量手段。高速摄影获得的声带线性结构上25%,50%,75%位置处的振动幅度,显示了声带前后振动不对称且声门下压较低时振动不对称较明显。      

Another look at the moist baroclinic Ertel–Rossby invariant with mass forcing

Due to the importance of the mass forcing induced by precipitation and condensation in moist processes, the Lagrangian continuity equation without a source/sink term utilized to prove the Ertel–Rossby invariant(ERI) and its conservation property is re-derived considering the mass forcing. By introducing moist enthalpy and moisture entropy, the baroclinic ERI could be adapted to moist flow. After another look at the moist ERI, it is deployed as the dot product between the generalized velocity and the generalized vorticity in moist flow, which constitutes a kind of generalized helicity.Thus, the baroclinic ERI is further extended to the moist case. Moreover, the derived moist ERI forumla remains formally consistent with the dry version, no matter whether mass forcing is present. By using the Weber transformation and the Lagrangian continuity equation with a source/sink effect, the conservation property of the baroclinic ERI in moist flow is revisited. The presence or absence of mass forcing in the Lagrangian continuity equation determines whether or not the baroclinic ERI in moist flow is materially conserved. In other words, it would be qualified as a quasi-invariant but only being dependent on the circumstances. By another look at the moist baroclinic ERI, it is surely a neat formalism with a simple physical explanation, and the usefulness of its anomaly in diagnosing atmospheric flow is demonstrated by case study.     

利用N粒子纠缠态的量子秘密共享

 为了高效实现多方之间的量子秘密共享,引入了一种纠缠度较高的N粒子纠缠态,并提出了利用该N粒子纠缠态在一方与（N-1）方之间形成共享秘密位串的方案.该方案在建立秘密位串的过程中,Alice对发送的粒子随机选择么正操作I和σx,并选择一部分粒子用于检测信道的安全|之后Alice根据（N-1）方选择的操作又选择了一部分粒子用于对参与者诚实度检测及信道安全检测.通过多次对窃听者的检测,很好地保证了信道的安全性及产生的秘密位串的可用性.最终在Alice及另外（N-1）方之间可形成n[1-(N-1)/2 N-1]/6个共享秘密位.     

快中子辐照直拉硅中受主和施主的研究

通过傅里叶红外光谱、正电子湮没寿命谱和Hall技术研究了高剂量快中子辐照直拉硅的辐照 缺陷、电阻率、载流子迁移率、载流子浓度随退火温度的变化.经快中子辐照，直拉硅样品 的导电类型由n型转变为p型.在450和600℃热处理出现两种受主中心，分别由V2_{2O22，V22O，VO22，V-O-V及V44型缺 陷引起，这些缺陷态的出现使得样品中空穴浓度迅速增加；大于650℃热处理这些受主态 缺陷迅速消失， 关键词： 快中子辐照 空位型缺陷 受主 施主}