激光二极管泵浦Nd：YVO4／LBO腔内倍频瓦级连续波绿光激光器

报道一种激光二极管端面泵浦ＮｄＹＶＯ４晶体、ＬＢＯ腔内倍频的全固态瓦级连续波（ＣＷ）绿光激光器。对ＬＢＯ采用Ｉ类非临界相位匹配（ＮＣＰＭ）、温度调谐，当泵光功率为５．５Ｗ时，获得了１．２ＷＴＥＭ００模５３２ｎｍ连续波绿光输出，光－光转换效率达２２％，电－光转换效率达３％。     

YVO_4∶Eu~(3+)@SiO_2核壳结构纳米复合材料的合成与表征

用沉淀法制备了尺寸约为8 nm的YVO4∶Eu3+纳米粒子,然后用反相微乳液法在YVO4∶Eu3+纳米粒子的表面包覆了一层Si O2壳。利用XRD、TEM、UV-Vis吸收光谱和光致发光光谱对合成的样品进行了表征。得到的复合物具有较好的核壳结构,通过改变硅酸四乙酯的用量可以改变Si O2壳的厚度。研究了Si O2壳对YVO4∶Eu3+发光性质的影响,结果表明:包覆和未包覆的样品在紫外光激发下都有Eu3+的特征发射;随着Si O2壳厚度的增加,发光强度和量子效率越来越低,Eu3+格位对称性越来越高。     

半导体激光泵浦的Nd:YVO4激光器的1.064 μm高效率连续输出

报道了半导体激光端面泵浦的Nd:YVO4激光器获得线偏振的1.064 μｍ激光高效率连续稳定输出。在半导体激光功率为1.5 W时，获得连续输出功率为837 kW的TEM00模，激光器泵浦阈值功率为140 kW，斜率效率达61.5％，光-光转换效率达56％，电-光转换效率达15％。     

A novel orthogonally linearly polarized Nd:YVO4 laser

<正>We presented a novel orthogonally linearly polarized Nd:YVO₄ laser.Two pieces of a-cut grown-together composite YVO₄/Nd:YVO₄ crystals were placed in the resonant cavity with the c-axis of the two crystals orthogonally.The polarization and power performance of the orthogonally polarized laser were investigated.A 26.2-W orthogonally linearly polarized laser was obtained.The power ratio between the two orthogonally polarized lasers was varied with the pump power caused by the polarized mode coupling.The longitudinal modes competition and the corresponding variable optical beats were also observed from the orthogonally polarized laser.We also adjusted the crystals with their c-axis parallele to each other,and a 40.7-W linearly polarized TEMoo laser was obtained,and the beam quality factors were M_x²=1.37 and M_y² =1.25.     

输出镜反射相移对倍频效率的影响

利用Macleod反射相移理论,模拟V-型腔457 nm Nd:YVO4蓝光激光器输出镜多层膜反射相位偏移。结合I类匹配LBO倍频晶体的倍频特性,讨论了输出镜反射膜对腔内基光偏振特性造成的影响,及其对I类相位匹配倍频效率的影响。研究发现,当基频光在输出镜处,入射角不大于15° 的情况下,造成的反射相移小于2° 。在近似相位匹配下,倍频效率相对于理想情况降低幅度不超过6%。     

New red Y0.85Bi0.1Eu0.05V1−yMyO4 (M=Nb, P) phosphors for light-emitting diodes

The Y_0.85Bi_0.1Eu_0.05V_1−yM_yO₄ (M=Nb, P) as new near-ultraviolet excited phosphors were synthesized and their luminescence properties under 365 nm excitation were investigated in detail. It indicated that by doping small amount of P⁵⁺ into V⁵⁺ sites, the excitation intensity of charge transfer (CT) band of Bi–O (330–400 nm) was greatly improved. By substituting Nb⁵⁺ for V⁵⁺, both the CT bands of Bi–O and Eu–O (240–320 nm) were significantly enhanced. As a result, the emission intensity of Y_0.85Bi_0.1Eu_0.05V_1−yM_yO₄ (M=Nb, P) could be improved about 90% by doping 5 mol% P⁵⁺ and 110% by doping 5 mol% Nb⁵⁺. Comparing with the commercial Y₂O₂S:Eu³⁺ phosphors, the Y_0.85Bi_0.1Eu_0.05V_0.95M_0.05O₄ (M=Nb, P) phosphors exhibited excellent color purity and much higher brightness. The results showed that these Y_0.85Bi_0.1Eu_0.05V_1−yM_yO₄ (M=Nb, P) phosphors could be considered as promising red phosphors for application in LED.     

YVO4:Eu发光材料的合成、结构与荧光性——推荐一个大学综合实验

This comprehensive experiment is recommended for the synthesis, structure and fluorescence properties of YVO₄:Eu photoluminescent materials. The main purpose of this experiment is to introduce the research of fluorescent materials, including the synthesis of materials, structure characterization and fluorescence measurement. Students can master the basic principle and operation of instruments, the method for material synthesis, and luminescence properties of the materials. While mastering the basic theory and the basic experimental skills, the experimental ability and creative consciousness, especially their ability to use knowledge comprehensively, can be cultivated and improved. The distance between teaching and scientific research is shortened.     

YVO4：Eu荧光纳米粒子的合成及表征

随着纳米材料的迅速发展及在生物科学领域的应用,近十年,以荧光纳米材料作为荧光标记物进行生物分子的标记和细胞成像受到了广泛的关注,相关的研究使生物标记技术有了长足的发展和进步[1～3].     

高功率准连续激光二极管抽运的Nd：YVO4激光器

对高功率准连续激光二极管端面抽运的Nd:YVO4固体激光器进行了实验研究。研究了抽运功率、温度、重复率及输出镜的透过率对激光器输出功率的影响。当激光二极管重复率达到720Hz、抽动功率33.2W时,激光输出最大平均功率为11W。     

基于水、风混合型冷却系统的LD端面泵浦全固态连续绿光激光器

为了简化激光器冷却系统,减小体积,降低成本,设计出一种基于水、风混合型的冷却系统,具有水冷和风冷的优点,可以实现稳定的绿光激光输出.采用结构简单、紧凑的平-凹腔设计,其端镜为平面镜,输出镜为凹面镜,曲率半径R=1 m,腔长L=165 mm,获得较稳定的单端泵浦Nd:YVO4腔内倍频KTP连续绿光激光输出.当晶体吸收的泵浦功率为24.3 W时,532 nm激光功率达到4.2 W,光-光转换效率达到17.2%.在绿光输出功率为3 W的情况下,观测到的变化范围在2.5%左右,温度变化范围在0.1°左右.实验结果表明,该冷却系统能够较好地转移晶体热效应产生的热量,实现转化效率较高的绿光输出,有利于实现高功率激光器的微型化.