反相高效液相色谱法同时测定姜黄药材中3个组分的含量

建立了一种反相高效液相色谱方法,同时测定中药材姜黄块根中3组分的含量。采用KromasilTMC18柱(5μm,200mm×4.6mm),以磷酸水溶液(pH=2.5)和乙腈溶剂为流动相,梯度洗脱,流速0.9mL/min,柱温40℃,检测波长为425nm,10min内即可将3种组分分离测定。该方法快速、简便、准确,可为评价不同产地的姜黄质量提供依据。     

MOF衍生碳基电催化剂限域催化O2还原和CO2还原反应

化石燃料的大量消耗和环境的逐渐恶化导致迫切需要开发和探索有效的能源转换和存储技术. 电化学是各种能源转换装置的基础和关键. 设计和合成具有高催化活性的非贵金属基和非金属基催化剂是最好的选择. 金属有机骨架(MOF)衍生的碳基材料具有比表面积大、 孔隙率高的特点, 可以选择性地限制不同类型的金属. 因此, MOF衍生碳作为催化剂载体使用时具有良好的限域效应, 有利于提高催化剂的活性和稳定性. 本文综合评述了MOF衍生材料在催化反应中的限域效应, 并介绍了MOF衍生碳基材料在氧还原反应(ORR)和二氧化碳还原反应(CO₂RR)电催化方面的最新进展, 揭示了MOF碳基材料在电催化反应中的构效关系. 最后, 讨论了MOF衍生的碳基材料在ORR和CO₂RR电催化中的挑战和机遇, 以及未来可能的解决方案.     

天然河流流场数值模拟的预处理方法

提出了求解一种二维原始变量湍流模型方程组的预处理方法。应用此方法对驱动方腔内的涡流及天然河流流场作了数值模拟计算，结果表明预处理方法具有较好的稳定性及较快的收敛速度，对天然河流流场的计算只有实用价值。     

Fabrication of Two‐Dimensional Lateral Heterostructures of WS2/WO3⋅H2O Through Selective Oxidation of Monolayer WS2

Two‐dimensional (2D) lateral heterostructures have emerged as a hot topic in the fast evolving field of advanced functional materials , but their fabrication is challenging. The layer‐structured WS₂ was theoretically demonstrated to be inert to oxidation except for the monolayer, which can be selectively oxidized owing to the simultaneous interaction of oxygen with both sides. Combined with the theoretical calculations, a new method was developed for the successful construction of 2D lateral heterostructures of WS₂/WO₃?H₂O in an ambient environment, based on a simple liquid‐phase solution exfoliation. These lateral heterostructures of WS₂/WO₃?H₂O have interesting properties, as indicated by enhanced photocatalytic activity toward the degradation of methyl orange (MO).     

Grafted antimicrobial cotton fabrics with N-halamine groups via atom transfer radical polymerization

Cellulose - An N-halamine precursor 2-(3-(6-methyl-4-oxo-1,4-dihydropyrimidin-2-yl)ureido)ethyl methacrylate (SCMHBMA) was synthesized and grafted on cotton fabrics via atom transfer radical...     

用工业固体废料合成沸石分子筛的研究进展

系统总结了以工业固体废料为原料合成沸石分子筛材料的最新研究进展, 讨论了以粉煤灰、 珍珠岩工业废料、 煤矸石、 流体催化裂化(FCC)废催化剂、 锂矿渣、 铝土矿渣、 废瓷料和废弃玻璃等工业固体废料为原料, 合成LTA, FAU, MFI, CHA, GIS, SOD, ANA和KFI沸石分子筛材料的工艺方法, 及其在污水中重金属离子的脱除、 空气中CO₂的捕获、 氮氧化物的选择性还原等实际应用中的性能, 并对未来工业固体废料合成沸石分子筛的发展趋势进行了展望.     

求解二维不可压缩Navier-Stokes方程的混合型微分求积法

微分求积法（ＤＱＭ）能以较少的网格点求得微分方程的高精度数值解,但采用单纯的微分求积法求解二维不可压缩Ｎａｖｉｅｒ＿Ｓｔｏｋｅｓ 方程时,只能对低雷诺数流动获得较好的数值解,当雷诺数较高时会导致数值解不收敛·　为此,提出了一种微分求积法与迎风差分法混合求解二维不可压缩Ｎａｖｉｅｒ＿Ｓｔｏｋｅｓ 方程的预估＿校正数值格式,用伪时间相关算法以较少的网格点获得了较高雷诺数流动的数值解·　作为算例,对１∶１ 和１∶２ 驱动方腔内的流动进行了计算,得到了较好的数值结果·     

Lag synchronization of a class of chaotic systems with unknown parameters

Research on chaos synchronization of dynamical systems has been largely reported in literature. However, synchronization of different structure—uncertain dynamical systems—has received less attention. This paper addresses synchronization of a class of time-delay chaotic systems containing uncertain parameters. A unified scheme is established for synchronization between two strictly different time-delay uncertain chaotic systems. The synchronization is successfully achieved by designing an adaptive controller with the estimates of the unknown parameters and the nonlinear feedback gain. The result is rigorously proved by the Lyapunov stability theorem. Moreover, we illustrate the application of the proposed scheme by numerical simulation, which demonstrates the effectiveness and feasibility of the proposed synchronization method.     

A novel polypropylene microporous film

The structure and properties of a polypropylene microporous film prepared by biaxial stretching of non-porous polypropylene film of high β-crystal content were investigated. The porosity of these films can be as high as 30–40%, and the average pore size was around 0.05 μm. The films were found to have the structure of a two-phase interpenetrating network; both the polypropylene and the pore regions were three-dimensionally continuous. The advantages of the biaxially stretched microporous films are the combination of high permeability to fluids with good mechanical properties and almost circular pore shape with narrow pore size distribution. The application of this microporous film for battery separators, filtration membranes and substrates of functional polymer composites is discussed.     

铜（II）化合物作用下2-綦胺的氧化偶合反应

2-萘胺（1）在甲醇中与铜胺络合物[x(CuCl_2):x(苄胺或乙醇胺）=2：1]室温 下反应得到产率为74%的1,1'-联-2-萘胺（2）。在醋酸铜、硝酸铜或高氯酸铜的催 化下,1在甲醇中被氢气氧化为2-氨基-1,4-萘醌-4-2'-萘亚胺（3）,产率86%。 用X-ray单晶衍射证实3的乙酰化产物结构为2-乙酰氨基-1,4-萘醌-E-4-2'-萘亚胺 （4）。循环伏安研究表明,铜（II）化合物的氧化反应选择性与其还原峰电位有 关。电喷雾质谱的分析表明1,2-萘醌-2-亚胺（6）是生成3的中间体。