Moderate deviation principle for <Emphasis Type="Italic">m</Emphasis>-dependent random variables<Superscript>*</Superscript>

Let {X _n }_n?≥?1 be a sequence of strictly stationary m-dependent random variableswith EX₁ = 0 and \( \mathrm{E}{X}_1^2<\infty \), and let (b _n ) be an increasing sequence of positive numbers such that b _n ?↑?∞ and \( {b}_n/\sqrt{n}\downarrow 0\kern0.5em \mathrm{as}\kern0.5em n\to \infty \). We establish a moderate deviation principle of \( {\left({b}_n\sqrt{n}\right)}^{-1}{\sum}_{i=1}^n{X}_i \) under the condition

$$ \underset{n\to \infty }{\lim \sup}\frac{1}{b_n^2}\log \left[n\mathbf{P}\left(\left|{X}_1\right|>{b}_n\sqrt{n}\right)\right]=-\infty, $$

which is weaker than the classical exponential integrability condition. The results in the present paper weaken the assumptions of Chen [5] and extend partially the results of Eichelsbacher and Löwe [10].     

Global attractor for a nonlinear thermoviscoelastic model with a non-convex free energy density

This paper is concerned with the existence of a global attractor for a semiflow governed by the weak solutions to a nonlinear one-dimensional thermoviscoelasticity with a non-convex free energy density. The constitutive assumptions for the Helmholtz free energy include the model for the study of martensitic phase transitions in shape memory alloys. To describe physically phase transitions between different configurations of crystal lattices, we work in a framework in which the strain u$u$ belongs to L^∞$L^{\infty }$. New approaches are introduced and more delicate estimates are derived to establish the crucial L^∞$L^{\infty }$-estimate of strain u$u$ in deriving the compactness of the orbit of the semiflow and the existence of an absorbing set.     

核壳结构CdS/ZnS纳米微粒的制备与光学特性

用微乳液法制备CdS纳米微粒 ,以ZnS对其进行表面修饰 ,得到具有核壳结构的CdS/ZnS纳米微粒 .采用X射线衍射 (XRD)、透射电镜 (TEM )表征其结构、粒度和形貌 ,紫外 可见吸收光谱 (UV)、光致发光光谱(PL)表征其光学特性 .制得的CdS近似呈球形 ,直径为 3.3nm ;以XRD和UV证实了CdS/ZnS核壳结构的实现 .研究了不同ZnS壳层厚度对CdS纳米微粒光学性能的影响 ,UV谱表明随着壳层厚度的增加纳米微粒的吸收带边有轻微的红移 ,同时短波吸收增强 ;PL谱表明壳层ZnS的包覆可减少CdS纳米微粒的表面缺陷 ,带边直接复合发光的几率增大 ,具有合适的壳层厚度时发光效率大大提高 .     

天然河流流场数值模拟的预处理方法

提出了求解一种二维原始变量湍流模型方程组的预处理方法。应用此方法对驱动方腔内的涡流及天然河流流场作了数值模拟计算，结果表明预处理方法具有较好的稳定性及较快的收敛速度，对天然河流流场的计算只有实用价值。     

Fabrication and photocatalytic activities of SrTiO3 nanofibers by sol–gel assisted electrospinning

SrTiO₃ nanofibers were successfully prepared by a facile electrospinning method with subsequent calcination in air. These one dimensional nanostructures were characterized for the morphological, structural and optical properties by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and UV–visible diffuse reflectance spectroscopy. The photocatalytic investigations showed that the SrTiO₃ nanofibers possessed enhanced photocatalytic efficiency in photodegradation of rhodamine B and photocatalytic H₂ evolution from water splitting under ultraviolet light irradiation, compared with the SrTiO₃ nanoparticles and P25. The enhanced photocatalytic performance can be ascribed to the beneficial microstructure and more negative conduction band edge compared with P25.     

Fabrication of Two‐Dimensional Lateral Heterostructures of WS2/WO3⋅H2O Through Selective Oxidation of Monolayer WS2

Two‐dimensional (2D) lateral heterostructures have emerged as a hot topic in the fast evolving field of advanced functional materials , but their fabrication is challenging. The layer‐structured WS₂ was theoretically demonstrated to be inert to oxidation except for the monolayer, which can be selectively oxidized owing to the simultaneous interaction of oxygen with both sides. Combined with the theoretical calculations, a new method was developed for the successful construction of 2D lateral heterostructures of WS₂/WO₃?H₂O in an ambient environment, based on a simple liquid‐phase solution exfoliation. These lateral heterostructures of WS₂/WO₃?H₂O have interesting properties, as indicated by enhanced photocatalytic activity toward the degradation of methyl orange (MO).     

X‐ray Radiation‐Controlled NO‐Release for On‐Demand Depth‐Independent Hypoxic Radiosensitization

Multifunctional stimuli‐responsive nanotheranostic systems are highly desirable for realizing simultaneous biomedical imaging and on‐demand therapy with minimized adverse effects. Herein, we present the construction of an intelligent X‐ray‐controlled NO‐releasing upconversion nanotheranostic system (termed as PEG‐USMSs‐SNO) by engineering UCNPs with S‐nitrosothiol (R‐SNO)‐grafted mesoporous silica. The PEG‐USMSs‐SNO is designed to respond sensitively to X‐ray radiation for breaking down the S N bond of SNO to release NO, which leads to X‐ray dose‐controlled NO release for on‐demand hypoxic radiosensitization besides upconversion luminescent imaging through UCNPs in vitro and in vivo. Thanks to the high live‐body permeability of X‐ray, our developed PEG‐USMSs‐SNO may provide a new technique for achieving depth‐independent controlled NO release and positioned radiotherapy enhancement against deep‐seated solid tumors.     

一种新型造纸施胶增效剂的合成及其应用

:探讨了丙烯酸 -苯乙烯 -甲基丙烯酸甲酯水溶性三元共聚物的合成条件 ,研究了这种水溶性三元共聚物的性质及其在造纸过程中的可能应用。研究发现 ,在适当的条件下 ,丙烯酸 -苯乙烯 -甲基丙烯酸甲酯可以按一定的摩尔比发生共聚合形成能溶于水的共聚物。这种水溶性的共聚物在高温下 (大于 80℃ )发生固化后而形成具有抗水性的膜 ,因而适合于造纸工业作施胶剂 ,但是 ,由于其分子量不高留着率低 ,要与松香配合使用 ,使松香施胶剂发挥更大的效果 ,实验证明 ,可以把乳化松香的施胶效果提高一倍以上     

Arene Control over Thiolate to Sulfinate Oxidation in Albumin by Organometallic Ruthenium Anticancer Complexes

Arene control : Anticancer complexes [Ru(arene)Cl(en)]⁺ (arene=p‐cymene or biphenyl; en=ethylenediamine) bind to surface histidine (His128, His247, His510) and methionine (Met298) residues in human albumin, but only the p‐cymene complex can gain entry to the crevice containing the free cysteine thiolate (Cys34) and induce oxidation to sulfinate.

     

Two-photon autofluorescence spectroscopy and second-harmonic generation of epithelial tissue

A spectroscopy system is developed for studying the two-photon excited fluorescence (TPEF) and second-harmonic generation (SHG) of epithelial tissue in backscattering geometry. Our findings show that TPEF signals from epithelial and underlying stromal layers exhibit different spectral characteristics, providing information on the biomorphology and biochemistry of tissue. The SHG signal serves as a sensitive indicator of collagen to separate the epithelial layer from underlying stroma. The polarization dependence of the SHG signal reveals a well-ordered orientation of collagen fibers in the stromal layer. The results demonstrate the potential of depth-resolved TPEF and SHG in determining the pathology of epithelial tissue.