杯芳烃及其衍生物在色谱和毛细管电泳中的应用

杯芳烃是由多个苯酚在2,6位与亚甲基相连形成的大环化合物,具有分子识别功能,是继环糊精和冠醚之后第三代主体分子,它在现代分离科学中有着广泛的应用,本文综述了近年来杯芳烃及其衍生物在色谱和毛细管电泳中的应用进展。     

以Nitrosulfophenol S为化学模型物研究非氨基偶氮染料的致癌性

以Nitrosulfophenol S作为非氨基偶氮染料致癌性研究的化学模型物,用可见吸收光谱法、毛细管区带电泳法和电分析化学法等研究了该模型物在酶催化系统模型HRP/H₂O₂体系的作用下发生氧化断裂反应的过程,确定了反应的主要产物为致癌的重氮萘离子,并与DNA有效结合.讨论了断裂发生的酸度、温度及浓度条件.同时研究了体内多种生理性物质对断裂反应的抑制和激活影响.     

自治差分方程的稳定性

本文首先给出了文献[2]中关于一次近似系统不稳定性定理的一个反例,然后给出了关于自治差分方程利用其一次近似系统的不稳定性来判别原系统不稳定性的判别定理。     

Intensity tuning characteristics of double-mode He--Ne laser with optical feedback

This paper investigates the intensity tuning characteristics of a double longitudinal modes He--Ne laser subjected to optical feedback. The intensity undulations of the total light and the two modes are observed for different external cavity length. Two modulations of the internal cavity length are performed. One is only for the internal cavity length being modulated and the other is for both the internal and the external cavity length being modulated. The undulation frequency of the total light is found to be determined by the ratio of external cavity length to internal cavity length in both modulations. When the external cavity length is integral times of the internal cavity length, the fringe frequency of the total light could be seven or even more times of that in conventional optical feedback. A simple theoretical analysis is presented, which is in good agreement with the experimental results. The potential use of the experimental results is also discussed.     

External-cavity birefringence feedback effects of microchip Nd:YAG laser and its application in angle measurement

External-cavity birefringence feedback effects of the microchip Nd:YAG laser are presented. When a birefringence element is placed in the external feedback cavity of the laser, two orthogonally polarized laser beams with a phase difference are output. The phase difference is twice as large as the phase retardation in the external cavity along the two orthogonal directions. The variable extra-cavity birefringence, caused by rotation of the external-cavity birefringence element, results in tunable phase difference between the two orthogonally polarized beams. This means that the roll angle information has been translated to phase difference of two output laser beams. A theoretical analysis based on the Fabry--Perot cavity equivalent model and refractive index ellipsoid is presented, which is in good agreement with the experimental results. This phenomenon has potential applications for roll angle measurement.     

同步-偏振-导数荧光法同时测定三种苯二酚异构体的研究

苯二酚的三种异构体, 由于其吸收光谱和荧光光谱均重叠严重, 不能用常规分光光度法和荧光法进行同时测定. 而以λ＝0 nm进行同步扫描时, 在350～500 nm之间具有相似的荧光光谱特征, 其荧光强度有良好的加和性, 可以对三者进行总量测定. 研究还发现三种苯二酚异构体与Cu^2＋和异烟肼形成1∶1∶2的配位合物时, 用Δλ＝30 nm进行同步扫描并采用偏振和一阶导数法, 间苯二酚的导数荧光峰位于260 nm处, 对苯二酚的导数荧光峰位于320 nm处, 两者能很好分开, 而此时邻苯二酚荧光峰消失, 因此可在三者的混合物中分别测定间、对苯二酚, 然后再从总量中减去间、对苯二酚的含量, 从而测到邻苯二酚的浓度, 因此本工作通过上述方法可对三种苯二酚异构体进行同时测定. 其线性范围均在3×10^－6～5×10^－4 mol/L之内, 间苯二酚和对苯二酚的检出限分别是2.5×10^－7 mol/L和3.1×10^－7 mol/L; 其混和物总量的检出限是4.5×10^－7 mol/L, RSD均在5%以下. 该方法简便快速, 有良好的准确性和重复性, 用于环境水样中三种苯二酚的同时测定, 获得满意结果.     

时滞微分方程依照两种测度的稳定性

运用变异Liapunov方法,讨论了时滞微分方程依照两种测度的稳定性。借助于中间测度h*(t,x),在未扰动系统为常微分方程的情形下,得到了关于时滞微分方程非一致和一致稳定性的判定定理。     

Enhanced pulse compression induced by the interaction between the third—order dispersion and the cross—phase modulation in birefringent fibres

In this paper,we report on the enhanced pulse compression due to the interaction between the positive third-order dispersion (TOD) and the nonlinear effect (cross-phase modulation effect) in birefringent fibres.Polarization soliton compression along the slow axis can be enhanced in a birefringent fibre with positive third-order dispersion,while the polarization soliton compression along the fast axis can be enhanced in the fibre with negative third-order dispersion.Moreover,there is an optimal third-order dispersion parameter for obtaining the optimal pulse compression.Redshifted initial chirp is helpful to the pulse compression,while blueshifted chirp is detrimental to the pulse compression.There is also an optimal chirp parameter to reach maximum pulse compression.The optimal pulse compression for TOD parameters under different N-order solitons is also found.     

GaN基紫外探测器的研究与制备

报道了用MOCVD方法在GaAs衬底上制作p-GaN/InGaN/n-GaN结构紫外探测器.我们对器件进行了测试分析.根据器件光伏信号强度和相位的测量结果,我们得到了该器件的能带结构图.我们还发现Ni/Au电极与p-GaN之间的接触表现出肖特基接触的特性.该探测器在入射光波长为375nm处的响应度大约为7.4×10-3A/W.     

色散缓变光纤中宽带调制不稳定性谱的产生

本文报道色散缓变光纤中调制不稳定性效应研究.从非线性Schrodinger方程出发,获得了增益谱与纵向色散变化参量和光纤传输距离的一般关系.研究发现,色散缓变光纤中调制不稳定性的增益谱较常规光纤中的宽得多.调节光纤色散纵向变化参量,可以得到较宽的增益谱.该文的研究结果为光纤中利用调制不稳定性产生超短孤子脉冲提供了理论根据.