偶氮染料掺杂高分子薄膜的光谱和光存储性质研究

利用旋涂法,制备了以二乙基胺基〖Ｎ（ＣＨ２ＣＨ３）２〗作为推电子基因、以具有强电负性的羧基（ＣＯＯＨ）作为拉电子基团的推－拉型偶氮染料掺杂的高分子（ＰＭＭＡ）薄膜。在室温下测试了该偶氮染料在溶液和薄膜态的吸收光谱、薄膜态的反射光谱和透过光,发现该薄膜在４００～５５０ｎｍ波长范围内具有强的吸收。在５１４．５ｎｍ光盘静脉测试仪上测试了膜片的静脉光存储性能,结果表明,用低功率Ａｒ＾＋激光（５１４．５ｎ     

Nonlinear optical properties of composites based on conductive metal-alkanoate liquid crystals

The dynamic holography in new composite materials based on a novel class of metal-alkanoate ionic liquid crystals (ILCs) is studied experimentally and theoretically. The composites are formed as a dielectric dye film covered by lyotropic metal-alkanoate ILC and ionic smectic glasses with doped dye molecules. The dynamic gratings are created by nanosecond pulses of double frequency Nd:YAP laser, the recording demonstrates fast erasure time of residual thermal gratings. The nonlinear optical properties are determined by the resonance nonlinearity in photosensitive centres of ILC. Note, that permanent relief gratings will be formed on a dielectric dye film only as well as in composite cells either with nematic LC or with polymers under action of pulsed laser radiation. Lyotropic ILC layer applied over the dye film provides the dynamic regime of grating recording in composite cells. We found a secondary thermal grating is much smaller, the conductive ILC matrix provides effective heat dissipation and erasure of this thermal grating. A theory of Raman-Nath self-diffraction holography on thin films followed from the wave equation and the nonlinear mechanism of absorption saturation is developed to explain experimental results.     

Thermal and Optical Properties of Cyanine Dye for High Density Digital Versatile Disc-Recordable (DVD-R)

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可用于光存储的氧化物、次氧化物薄膜材料的研究及发展

介绍了可用于可录、可擦除、全息光存储及超分辨掩膜层的氧化物、次氧化物薄膜材料的种类、制备方法、光存储特性和存储机制。这类薄膜材料由于具有种类多、应用范围广、制备方法多样、写入灵敏度高和记录稳定性好等优点 ,正受到各国研究者越来越多的关注。分析总结了这类材料的研究现状、存在的主要问题和未来发展方向     

TeSeIn相变记录薄膜的微观特性研究

TeSeIn是一种可逆光存贮介质.分别用单源热蒸发和磁控溅射制备TeSeIn膜.利用透射电镜(TEM)研究了膜的结构和微观形貌.利用俄歇剖面技术(AES-PRO)给出了膜的组分深度剖面,分析了TeSeIn记录介质膜与ZnS保护膜界面间的互扩散大小.利用X光电子能谱(XPS)分析了组元深能级结合能的化学位移.最后根据上面实验结果简要讨论了制备稳定的多元记录介质膜的方法.     

染料敏化TiO2/WO3薄膜电池的光电变色

用光电化学方法研究了染料Ru(П) (4, 4′di COOEt 2, 2′bpy)2 (2, 2′bpy 4, 4′di CONH L tyrosineethylester) (PF6)2 (简写为Ru4)敏化TiO2 纳米结构电极的光电转换过程,同时,在导电玻璃上电沉积得到WO3 薄膜.结果表明,染料敏化的TiO2 多孔膜具有光电转换性能, WO3 薄膜具有良好的电致变色效应,将前者与电沉积得到的WO3 薄膜组成电池,在白光照射下可产生显著的颜色变化,有望用于自供电源的电色灵巧窗(Self poweredsmartwindow).     

A nano-porous TiO2 thin film coating method for dye sensitized solar cells (DSSCs) using electrostatic spraying with dye solution

The dye coloring process on a nano-porous TiO₂ thin film for DSSCs was studied using an electrostatic spraying (ESS) method. In this study, dye coating experiments were performed using homemade ESS equipment. The coating patterns on the TiO₂ thin film are changed by adjusting the applied voltages of the ESS system. The geometry of the coating patterns is observed by a charge-coupled device (CCD) camera. The TiO₂ thin film is fabricated by controlling the electric field which allows a uniform color distribution to be obtained with a high dyeing capacity. The colored TiO₂ thin films are compared with those obtained using a conventional immersed dye solution by means of an UV–vis spectrometer. The performance of this novel coloring process was confirmed by measuring I–V curve characteristics.     

Determination and analysis of the optical constants of thin films of nickel(II) and copper(II) hydrazone complexes by spectroscopic ellipsometry

Thin films of four nickel(II) and copper(II) hydrazone complexes, which will hopefully be used as recording layers for the next-generation of high-density recordable disks, were prepared by using the spin-coating method. Absorption spectra of the thin films on K9 optical glass substrates in the 300–700 nm wavelength region were measured. Optical constants (complex refractive indices N) and thickness d of the thin films prepared on single-crystal silicon substrates in the 275–675 nm wavelength region were investigated on a rotating analyzer-polarizer scanning ellipsometer by fitting the measured ellipsometric angles (Ψ(λ) and Δ(λ)) with a 3-layer model (Si/dye film/air). The dielectric functions ε and absorption coefficients α as a function of the wavelength were then calculated. Additionally, a design to achieve high reflectivity and optimum dye film thickness with an appropriate reflective layer was performed with the Film Wizard software using a multilayered model (PC substrate/reflective layer/dye film/air) at 405 nm wavelength. PACS 81.05.L; 78.20.Ci; 78.20.-e     

染料LB膜吸收光谱和光学存储效应的研究

通过对新型的染料LB膜(花氰-花生酸复合LB膜)的吸收光谱的测试,说明了LB膜中染料分子H-聚体结构的存在,而在立体简并四波混频实验中观察到这种LB膜具有可逆的光学记录与擦除效应,实验表明,在其中建立一个稳定的光栅,所用的记录光脉冲强度为30MW/cm~2,需要的累积记录时间为80ns(10个脉冲).最后在简化的三能级系统中,以分子处于各态的布居光栅模型说明了光致H-聚体,单体之间的转化是这种光学记录效应的主要原因.     

抗水性光致聚合物的体全息存储研究

提出了基于酞菁染料的全息记录材料,与目前已报道的基于丙烯酞胺基单体光聚合型全息记录介质相比,该聚合体系显示了优良的全息特性：全“干”热后处理,良好的抗水性和环境稳定性,制备过程简单和低毒性,并可制备成较厚的感光膜层。针对存储过程的页间和页内串扰做了理论分析和MTALAB仿真,采用自主研制的抗水性光致聚合物材料记录多幅不同图像的实验方案,分析了本抗水性全息材料的角度复用性能。     

新型AgInSbTe相变薄膜的光学及记录性能

利用直流磁控溅射法制备了一种新型AgInSbTe相变薄膜。示差扫描量热(DSC)实验测定的结晶峰温度为193．92℃。X射线衍射(XRD)表明未经热处理的沉积态薄膜是非晶态,而经过200℃热处理,X射线衍射图出现衍射峰,薄膜从非晶态转变到晶态。同时,研究了晶态和非晶态相变薄膜的吸收率、透射率和反射率随波长的变化。测定了650nm激光作用下的相变薄膜的记录性能,分析了记录功率、记录脉宽对薄膜反射率衬比度的影响,在同一记录脉宽条件下,记录功率越大,反射率衬比度也越大;在同一记录功率条件下,随记录脉宽的增加,反射率衬比度也增大。结果表明,新型AgInSbTe相变薄膜在激光作用下具有较高的反射率衬比度,可获得良好的记录性能。     

The nonlinear refraction sign turned to reverse by intercalating cresyl violent dye into layered titanate nanosheets

Solid-state dye-doped materials are an attractive alternative to conventional liquid dye solution. In this study, the spectral characteristics of dye cresyl violet before and after intercalating into layered titanate nanosheets and forming a nanohybrid thin film were investigated by measuring absorption and fluorescence spectra. In addition, their nonlinear optical properties were studied using single beam z-scan technique under irradiation of low power continuous wave (CW) produced by DPSS laser with a wavelength of 532 nm. The nonlinear studying results reveal that the dye cresyl violet in solution has a negative nonlinear refractive index, but it reverses to positive after the dye is intercalated into layered titanate nanosheets with a negative nonlinear refractive index forming CV/HTO nanohybrid thin film. This method can provide a way to turn to reverse nonlinear refraction sign of the materials.     

Thin film properties by facing targets sputtering system

In this study, film thickness distribution and c-axis crystalline orientation of deposited thin films were studied after preparing Co–Cr thin films, a promising ultra-high density perpendicular magnetic recording media, with a facing targets sputtering (FTS) apparatus. Electrical discharge characteristics needed for the optimum operation of sputter device was also studied in order to prepare thin films of superior c-axis crystalline orientation with FTS method (apparatus) in which thin film of fine quality can be formed because temperature increase of substrate due to the bombardment of high-energy particles can be restrained.As a result of the study, it is confirmed that the FTS method can give stable working under broad magnetic field and range of gas pressure and stable electrical discharge under low Ar gas pressure. Film thickness of prepared thin film shows fairy regular distribution and could obtain good thin films whose dispersion angle of c-axis crystalline orientation is about 3.5°.     

原子力显微镜对TeOx薄膜中短波长静态记录点结构的分析

以真空蒸镀法在K9基底上制备了TeOx单层薄膜,采用特定的定位方法,使用原子力显微镜对不同记录功率下薄膜中短滤长静态记录点（514．5nm)的结构进行了分析。实验结果表明薄膜具有良好的记录灵敏性,在记录功率1．5mW时就可产生较高的反射率对比度,记录点具有明显的凹陷和凸起结构,随着记录功率的提高,凹陷和凸起增强,记录点增大。记录点的形态结构和记录前后反射率对比度是直接相关的。研究揭示了原子力显微镜在提高薄膜存储特性如信噪比,存储密度等方面的分析功能。     

甲基蓝-钛酸盐纳米聚合物薄膜的光谱和光学非线性研究

 为了满足光学非线性器件设备对工作材料的要求,探究具有高阶非线性效应的固态薄膜材料的制备方法,并对其光学特性进行表征,采用化学插入法,将甲基蓝染料分子插入到具有纳米量级的层状钛酸盐片间,制备了甲基蓝-钛酸盐纳米聚合物薄膜,通过吸收光谱和荧光光谱的测定,发现薄膜的吸收峰相对于染料溶液发生了明显的蓝移,表明染料分子在纳米片间是H-聚集排列。进一步应用单光束连续He-Ne激光Z-扫描技术研究了样品的非线性光学特性,结果显示：插入染料分子的钛酸盐纳米MB/HTO聚合物薄膜具有“负”的非线性折射率,在低功率连续激光作用下聚合物薄膜的非线性折射率系数n2的量级为10-10 m2/W。     

White-light spectral interferometric technique to measure a nonlinear phase function of a thin-film structure

We present a new two-step white-light spectral interferometric technique to measure a nonlinear phase function of a thin-film structure. The technique is based on recording of channeled spectra at the output of a Michelson interferometer and their processing by using a windowed Fourier transform to retrieve the phase functions. First, the phase function including the effect of a thin-film structure is retrieved. Second, the structure is replaced by a reference sample of known phase change on reflection and the corresponding phase function is retrieved. From the two functions, the nonlinear phase function of the thin-film structure is obtained. The feasibility of this simple method is confirmed in processing the experimental data for a SiO₂ thin film on a Si wafer of known optical constants. Four samples of the thin film are used and their thicknesses are determined. The thicknesses obtained are compared with those resulting from reflectometric measurements, and a good agreement is confirmed.     

有机薄膜光盘的微区结构

通过光学显微镜（ＯＭ）扫描电镜（ＳＥＭ）和扫描隧道显微镜（ＳＴＭ）观察了光记录有机薄膜的微区结构，从微区结构的形貌可以看出光记录后酞菁薄膜上产生了鼓泡，通过这些观察方法的比较发现扫描隧道显微镜可以提供更加详细，精确的三维参数，薄膜的微区结构研究对于分析光盘的性能，了解记录机理具有重要意义。     

Optical recording using hydrogen phthalocyanine thin films

Vacuum sublimed thin films of the blue dye hydrogen phthalocyanine (H₂Pc) were incorporated into various optical recording structures. The dye was shown to be thermally, hydrolytically, and oxidatively stable. In all cases, the writing mechanisms are dependent on the sublimation of H₂Pc. Several recording structures which take advantage of the sublimation property of H₂Pc are demonstrated, including pit forming and bubble forming media. These H₂Pc-based optical recording structures show very high optical contrast and low writing threshold energies. In addition, very thin films (50–75Å) of H₂Pc were incorporated into a tellurium-based medium, which significantly enhanced the writing contrast observed in that medium.     

Vanadyl phthalocyanine: An organic material for optical data recording

Vanadyl Phthalocyanine (VOPc) is a stable organic dye which absorbs in the spectral range of currently available injection lasers. The applicability for high density optical storage of single, double and triple layer structures containing a thin film of this dye, is investigated. It is concluded that if VOPc is used in combination with a tellurium film, some power reduction relative to single Te films can be achieved.     

Modeling and recording characteristics of a dye-doped polymer bilayer film

The optical, thermal, and structural behavior of a laser-irradiated dye-in-polymer bilayer film consisting of an elastic and a plastic layer was investigated by a computer modeling and recording experiment. The results of numerical calculations describe absorption of optical energy in the recording layers, the heat flow, and the resultant bump formation throughout the multilayer. Recording performance of the material is strongly affected by the dye concentration and the thickness of the plastic layer. The calculated and measured properties of the media are compared, and the relationship between the dye concentration, thickness of plastic layer, and thermal, structural, and recording performance are described. Received: 9 March 1999 / Revised version: 10 May 1999 / Published online: 29 July 1999