Sr原子|M|=1电场标度能谱

通过同步改变激光扫描波长和外加电场大小,保持标度能为常量,将Sr原子从基态激发到|M|=1的激发态,得到了标度能ε=-3.00,-2.50,-1.88时的常数标度能谱.实验傅里叶变换回归谱与氢原子闭合轨道理论计算进行了比较,峰值位置符合较好,峰值强度则受Sr原子实效应影响较大.     

电场中Rydberg原子的常数标度能谱方法

标度能谱理论能够简化外场谱及可以经典方法理解原子外场谱而倍受关注。本文报道了用于电场中Rydberg原子常数标度能谱实验研究的装置以及有关的计算机控制、采集及处理系统。该系统对能量E和电场F进行同步控制以保持标度能谱ε=E/F为常数，并成功地得到Rydberg态Sr原子在标度能ε=-3.0时的标度能谱，经过傅里叶变换，获得了电场中Sr原子的电子回归谱。     

Ba Rydberg原子M = 0电场常数标度能谱

选择激光偏振方向，同步改变激发激光的波长(即原子的激发能量E）和外加电场强度 F，使标度能ε=E/F保持为常数，得到了原子束中Ba Rydberg原子在标度 能ε=-300时M=0激发的常数标度能谱.由实验标度能谱的Fourier变换得到的回 归谱与氢的均匀化近似后的闭合轨道理论计算相比较，发现实验回归谱的峰值位置与理论计 算符合较好，而峰值强度则与理论相差较大，分析认为是由于受到核散射和双电子微扰态的 影响所致. 关键词： 标度能谱 闭合轨道理论     

Sr原子的电场标度能谱

利用原子束 -激光束 -电场相互垂直交叉的实验构型 ,通过同步改变激光激发波长和外加电场强度 ,得到了Sr原子在标度能为 - 3.0时的常数标度能谱。通过对实验谱进行傅里叶变换得到的电子回归谱的分析 ,发现在分岔附近回归峰强度增大。均匀化近似闭合轨道理论计算谱与实验回归谱进行了比较 ,发现在低作用量处两者较好符合。     

(La0.7Sr0.3MnO3)m(BiFeO3)n超晶格间隔的La0.7Sr0.3MnO3三明治结构制备及表征

采用射频磁控溅射的方法在SrTiO3(001,基片上制备了(La0.7Sr0.3MnO3)m(BiFeO3)n超晶格间隔的La0.7Sr0.3MnO3三明治结构.X射线衍射分析证明(La0.7Sr0.3MnO3)m(BiFeO3)n具有明显的超晶格结构.电流垂直于薄膜表面测得的电阻-温度关系表明.La0.7Sr0.3MnO3)m(BiFeO3)n超晶格薄膜在290 K有金属-绝缘体转变,略低于单层La0.7Sr0.3MnO3薄膜的转变温度.电流在0.01-10 mA范围内,观察到薄膜的峰值电阻随电流增大而减小,峰值变化率远大于单层La0.7Sr0.3MnO3薄膜,且随着超晶格周期厚度的增加而增大.低温下,电流-电压曲线表明其导电机制应主要为空间载子限制,且显示较大的电压偏置,表现出肖特基结的特性.     

La0.9Sr0.1MnO3薄膜中电流效应研究

用直流磁控溅射法在(100)LaAlO3衬底上制备了La0.9Sr0.1MnO3薄膜.经退火处理后薄膜的原子力显微镜形貌观测和X射线衍射分析显示具有比较好的质量.电阻率-温度关系表明La0.9Sr0.1MnO3薄膜在281 K处发生金属绝缘体转变.电流在0.01-4 mA范围内,薄膜的峰值电阻率随电流增大而减小,在4 mA下获得了30.5%的峰值电阻率变化率,并从相分离图像给出了简单解释.     

(Pr,Nd)_(2/3)Sr_(1/3)MnO_3体系中的低温比热反常现象

主要研究了(Pr1-yNdy)2/3Sr1/3MnO3体系多晶样品在低温下的比热反常现象.Pr2/3Sr1/3MnO3在低温下没有比热反常现象,但随着Nd替代Pr,比热反常开始出现,峰值逐渐增加,峰值出现温度逐渐减小;在磁场的作用下,峰值减小,峰值出现温度逐渐增加;经分析,该低温比热反常现象与Schottky效应相关.     

熔融织构的YBCO超导体的交流磁化率频率响应

在涡漩玻璃理论的基础上,我们推导出了交流磁化率的虚部峰值温度和频率的标度方程,可表示为Tp=Cf1/(v(z-1)).实验结果表明我们的标度方程和实验符合得很好.利用标度方程可以确定样品在磁场下的涡漩玻璃转变温度Tg和指数v(z-1)的数值.     

复合胶体喷雾自组装Sr2Al2SiO7:Eu2+荧光体及其发光特性

采用AlOOH/Sr(NO3)2/SiO2/Eu复合胶体喷雾工艺制备了D50=3.83μm球形Sr2Al2SiO7:Eu2 梯次结构荧光粉.复合胶体喷雾过程形成雾滴,雾滴中纳米粒子组分在表面张力及毛细管力作用下自组装形成梯次结构干凝胶粉.干凝胶粉经1300 ℃灼烧得到梯次结构Sr2Al2SiO7:Eu2 荧光粉.X射线衍射(XRD)分析及晶格常量计算结果表明,Eu2 离子部分取代Sr2 格位进入Sr2Al2SiO7晶格.Sr2Al2SiO7:Eu2 荧光体激发谱由峰值位于326 nm附近的宽带构成,属于Eu2 的4f→5d跃迁吸收带;发射光谱峰值波长位于约500 nm处,属于Eu2 离子4f65d到4f7跃迁导致的宽带发射.     

Bi_2Sr_2CaCu_2O_(8+δ)单晶的钉扎力标度和磁通钉扎机制

测量了 Bi2 Sr2 Ca Cu2 O8+δ单晶不同温度下的磁化曲线。根据 Bean临界态模型得到了不同温度下的钉扎力密度 FP 对磁场的依赖关系 ,发现在不同温度下的钉扎力密度可以标度在同一条曲线上。标度函数和最大钉扎力所对应的磁场与不可逆场 Hirr的比值都表明 Si2 Sr2 Ca Cu2 O8+δ单晶在磁通玻璃态的钉扎机制主要是正常相面钉扎。     

Electronic structure and optical properties of crystalline strontium azide and barium azide by ab initio pseudopotential plane-wave calculations

Detailed ab initio studies on the electronic structure and optical properties of crystalline strontium azide and barium azide have been performed using density functional theory (DFT) within the generalized gradient approximation (GGA). Relaxed crystal structures compare well with experimental data. An analysis of electronic structure, charge transfer, and bond order shows that the two azides are mainly ionic compounds. Our calculated optical properties are found to be in good agreement with available experimental data. The absorption spectra of the two azides show a number of absorption peaks in the fundamental absorption region. The photoconductivity spectra display a broad photocurrent response in the fundamental absorption region. The density of states of the two azides reveal the effects of the metal states on the valence electron of the azide group, and so are correlated with their thermal decomposition.     

Rydberg spectroscopy in an optical lattice: blackbody thermometry for atomic clocks

We show that optical spectroscopy of Rydberg states can provide accurate in situ thermometry at room temperature. Transitions from a metastable state to Rydberg states with principal quantum numbers of 25-30 have 200 times larger fractional frequency sensitivities to blackbody radiation than the strontium clock transition. We demonstrate that magic-wavelength lattices exist for both strontium and ytterbium transitions between the metastable and Rydberg states. Frequency measurements of Rydberg transitions with 10(-16) accuracy provide 10 mK resolution and yield a blackbody uncertainty for the clock transition of 10(-18).     

The role of defect states in the creation of photoluminescence in SrTiO<Subscript>3</Subscript>

We discuss the nature of visible photoluminescence at room temperature in amorphous strontium titanate in the light of the results of a recent experimental and quantum mechanical theoretical study. Our calculation of the electronic structure involves the use of first-principles molecular calculations to simulate the variation of the electronic structure in the strontium titanate crystalline phase, which is known to have a direct band gap, and we also make an in-depth examination of amorphous strontium titanate. The results of our simulations of amorphous strontium titanate indicate that the formation of five-fold coordination in the amorphous system may introduce delocalized electronic levels in the highest occupied molecular orbital and the lowest unoccupied molecular orbital. These delocalized electronic levels are ascribed to the formation of a tail in the absorbance-spectrum curve. Optical absorption measurements experimentally showed the presence of a tail. The results are interpreted by the nature of these exponential optical edges and tails associated with defects promoted by the disordered structure of the amorphous material. We associate them with localized states in the band gap. Received: 15 January 2002 / Accepted: 7 August 2002 / Published online: 4 December 2002 RID="*" ID="*"Corresponding author. Fax: +55-16/2615-215, E-mail: derl@power.ufscar.br     

Relativistic coupled cluster method

Relativistic coupled cluster method (CCM) is applied to compute the low lying excited and ion states of strontium and ytterbium atom. The resulting excitation and ionization energies are in excellent agreement with experimental data and with other correlated calculations. The nuclear magnetic dipole hyperfine constants (A) and electric quadrupole hyperfine constants (B) of excited states are also evaluated and are in accord with experiment. We further address the basis set dependency of the computed properties.     

An ab initio study of the vibrational properties of alkaline-earth metal nitrates and their crystallohydrates

The vibrational frequencies and corresponding intensities have been calculated ab initio for the center of the Brillouin zone of crystalline magnesium, calcium, strontium, and barium nitrates; magnesium nitrate hexahydrate; and calcium nitrate tetrahydrate. The calculation has been performed within the electron- density functional theory using the PBE exchange-correlation functional in the basis of localized atomic orbitals with the aid of the CRYSTAL14 software. The calculated values and the experimental IR and Raman spectral data on strontium and barium nitrates are shown to be in satisfactory agreement. The frequencies of normal long-wavelength vibrations in the nitrates become red-shifted with an increase in the cation atomic mass. The occurrence of several peaks due to the vibrations of hydrogen atoms in water molecules with different dynamic charges is predicted in the IR spectrum of hexahydrate magnesium in the frequency range above 3430 cm^–1.     

Second-harmonic generation in quasi-periodically domain-inverted Sr(0.6) Ba(0.4) Nb(2)O(6) optical superlattices

One-dimensional Fibonacci-type quasi-periodically domain-inverted structures have been successfully fabricated in a strontium barium niobate crystal by electric field poling. With a single such structure, type I phase-matched second-harmonic generation (SHG) has been demonstrated at several wavelengths from red to near ultraviolet. The spectral positions of the observed SHG peaks are in good agreement with theoretical predictions. The range of measured conversion efficiencies is 2-10%.     

钒电池电解液中不同价态钒的分光光度分析

采用先还原后络合的方法,利用草酸将V(V)离子还原并形成络合物,使得全钒氧化还原液流电池(钒电池)电解液的四种价态离子在紫外可见光范围内均具有不同的特征吸收峰.基于此建立了钒电池电解液中不同价态钒离子的光度分析方法,实现对钒离子定性、定量测定.不同价态钒离子标准曲线线性相关系数都大于0.999 0,线性范围分别为0.3...     

强场中NO分子回归谱的长程散射矩阵的理论研究

采用半经典散射矩阵方法研究外磁场中高里德伯态双原子分子在能量范围为77010—77050cm^-1的回归谱.通过引进模型势简化强磁场中NO分子的高里德伯电子的势函数,找出其在核转动量子数分别为N=1,3,5的三个通道中的闭合轨道,重点分析了强磁场中NO分子的长程散射矩阵元实部的傅里叶变换谱与闭合轨道之间的一一对应关系.     

复合氧化物SrEu2O4的合成与光谱特性

以SrCO3和Eu2O3为原料,采用高温固相反应法在空气气氛中合成了一种Eu和Sr的复合氧化物.利用XRD,TG/DTA和荧光光谱等测试手段对该种新物相的组成、结构和发光性质进行了研究.XRD结果显示,该物相的分子式组成为SrEuO4,与BaEu2O4同构.荧光光谱表明,SrEu2O4存在一个双峰结构的Eu3 -O2-电荷迁移带,峰值分别位于257和280 nm;在紫外光激发下,SrEu2O4以5D0→7F2电偶极发射跃迁(618 nm)最强,发出强的红光.