共查询到17条相似文献,搜索用时 109 毫秒
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电场中Rydberg原子的常数标度能谱方法 总被引:2,自引:0,他引:2
标度能谱理论能够简化外场谱及可以经典方法理解原子外场谱而倍受关注。本文报道了用于电场中Rydberg原子常数标度能谱实验研究的装置以及有关的计算机控制、采集及处理系统。该系统对能量E和电场F进行同步控制以保持标度能谱ε=E/F为常数,并成功地得到Rydberg态Sr原子在标度能ε=-3.0时的标度能谱,经过傅里叶变换,获得了电场中Sr原子的电子回归谱。 相似文献
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利用原子束 -激光束 -电场相互垂直交叉的实验构型 ,通过同步改变激光激发波长和外加电场强度 ,得到了Sr原子在标度能为 - 3.0时的常数标度能谱。通过对实验谱进行傅里叶变换得到的电子回归谱的分析 ,发现在分岔附近回归峰强度增大。均匀化近似闭合轨道理论计算谱与实验回归谱进行了比较 ,发现在低作用量处两者较好符合。 相似文献
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半经典闭合轨道在外场和激光参数的某些值附近发生分岔,导致波函数的发散,使原有的半经典闭合轨道理论失效-计算了高激发的Li原子在标度能量为ε=-2-94,标度电场在135 -86-1/4<160-11范围内光吸收谱的Fourier变换,分析了轨道分岔现 象及其影 响,并采用了一种适用于不同能域的统一近似方法修正了分岔点附近波函数-计算中考虑了 原子实多重散射组合回归效应,并把所得回归谱与用标准半经典闭合轨道理论对Li原子及H 原子的计算结果相比较,证明了轨道分岔效应的重要性-
关键词:
分岔
统一近似
半经典闭合轨道理论
回归谱 相似文献
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利用包括实散射的闭合轨道理论和分区自洽迭代的计算方法,研究了在标度能量~ε=-0.03和标度电场~f=0.01的情况下He(M=1)原子在平行电磁场中的闭合轨道和光吸收的回归谱.与相同条件下的He(M=0)原子的回归谱相比较,由于z轴处的排斥势,减小了原子实短程衍射效应和电子的关联,使谱变得简单,这与实验的结果一致. 相似文献
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利用全实加关联的方法计算类锂体系(Z=11~20) 1s23p-1s2nd(4≤n≤9)的跃迁能, 将相对论效应(电子动能的相对论修正,Darwin项,电子电子接触项以及轨道轨道相互作用)和质量极化效应作为微扰,计算了它们对体系能量的修正.计算得到的结果,与现有的实验数据比较,结果符合得很好.依据量子亏损理论,确定Rydberg系列1s2nd的量子数亏损,由此实现对任意激发态(n≥10)能量的理论预言. 相似文献
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利用包括实散射的闭合轨道理论和分区自洽的迭代算法,计算了标度能量为ε =- 0 .0 3,标度电场F =0 .0 1时的平行电磁场中n≈ 4 0 ,m =0的Li原子闭合轨道以及光吸收谱.介绍了谱的标度特性 ,它对理解量子与经典之间的对应关系具有非常重要的意义.并与同样情况下的氢原子谱作了比较 .验证了离子实对光吸收过程的重要作用. By employing the semiclassical closed-orbit theory including core-scattering and region-splitting consistent iterative method, we calculate the closed-orbits and the recurrence spectra of n≈40, m=0 Li Rydbergatom in parallel electric and magnetic fields at scaled energy ε=-0.03. The constant scaled electric field is =0.01 . The novel spectral structures are compared with those of hydrogen obtaines by standard closed orbit theory. The effect of the core-scattering has been discussed. 相似文献
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用代数能量方法研究氢化物双原子分子的完全振动能谱和离解能 总被引:1,自引:5,他引:1
本文用研究双原子分子振动能谱的新方法-代数方法(AM),研究了KH-X1Σ+,RbH-X1Σ+,DF-X1Σ+和DCl-X1Σ+等四个氢化物双原子分子的电子基态的振动光谱常数和振动能谱;用代数能量方法(AEM)研究了相应电子态的分子离解能.研究结果表明:使用实验获得的少数精确的振动能级[Eυ],由AM方法得到的振动能谱不仅能够重复这些电子态的已知实验能级,还能够得到用现代实验方法或精确的量子理论方法很难得到的所有高振动激发态的能级.由AEM方法能够得到比用文献发表的振动光谱常数计算获得的离解能值更准确的分子离解能. 相似文献
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Recurrence spectra of non—hydrogen Rydberg atoms in paralled electric and magnetic fields 总被引:2,自引:0,他引:2 下载免费PDF全文
We present a new method for computing the recurrence spectra of n≈40, m=0 lithium Rydberg atoms in strong parallel external electric and magnetic fields. This method is based on an extended closed-orbit theory allowing the computation of the scattering of the electron by the ionic core. We pay particular attention to the scaling properties, which are extremely important for understanding the correspondence between classical and quantum mechanics. The spectra with a constant scaled electric field \tilde F=0.01 and a scaled energy ε=-0.03 are recorded and compared with those of hydrogen obtained by the standard closed-orbit theory. The result shows that the additional strong resonance structures can be interpreted in terms of the core-scattered classical closed orbits. 相似文献
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We observe strong energy-dependent quantum defects in the scaled-energy Stark spectra for |M| = 1 Rydberg states of barium atoms at three scaled energies: ε = 2.000,ε = 2.500 and ε = 3.000.In an attempt to explain the observations,theoretical calculations of closed orbit theory based on a model potential including core effect are performed for non-hydrogenic atoms.While such a potential has been uniformly successful for alkali atoms with a single valence electron,it fails to match experimental results for barium atoms in the 6snp Rydberg states with two valence electrons.Our study points out that this discrepancy is due to the strong perturbation from the 5d8p state,which voids the simple approximation for constant quantum defects of principle quantum number n. 相似文献
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Based on the closed orbit theory framework together with the quantum defect theory and time-independent scattering matrices
theory, we calculate the recurrence spectra of diamagnetic Cs atoms at several different scaled energies near the second ionization
threshold. It is revealed that the new extra peaks in spectra are attributed to the combination recurrences of semiclassical
closed orbits arising from core-scattered events. This method considers the dynamic states of the Rydberg electron in the
core region and long-range region and can be analytically resumed to include all orders of core-scattering automatically.
With this approach a convergent recurrence spectrum can be reasonably achieved. It is found that the spectral complexity depends
highly sensitively on the scaled energy. With the increase of the scaled energy, the spectral structure changes from simple
to complicate and the dynamic feature from regular to chaotic. The comparison of the recurrence spectra with Dando’s result
under the same conditions demonstrates that there exist some similarities and differences between them, and furthermore, the
feasibility of the scattering matrix method is explained.
Supported by the National Natural Science Foundation of China (Grant Nos. 10774093 and 10374061) 相似文献
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Recurrence spectra of He atoms in strong external fields 总被引:1,自引:0,他引:1
LIN Shenglu LI Hongyun WANG Dehua ZHAO Wenli & GAO Feng . Department of Physics Shandong Normal University Jinan China . Department of Mathematics Physics Shandong Institute of Architecture Engineering Jinan China 《中国科学G辑(英文版)》2004,47(4):477-484
1 Introduction The photo-absorption phenomenon of high Rydberg atoms in strong external fields has attracted much attention in recent years. The semiclassical closed-orbit theory[1,2] developed by Du and Delos has been extensively used to explain this phenomenon. This theory has successfully calculated and interpreted the photo-absorption spectra of H- in various external fields[3,4] and has been applied to describe the photo-excitation, wave packet dynamics of some atoms and molecules such… 相似文献
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Courtney M 《Chaos (Woodbury, N.Y.)》1996,6(1):63-66
A method is presented for determining the initial conditions of classical orbits from the quantum spectra of the diamagnetic hydrogen atom. Each classical trajectory which is closed at the nucleus produces a sinusoidal fluctuation in the photoabsorption spectrum. The amplitude of each orbit's contribution appears in the Fourier transform of a spectrum computed at constant scaled energy. For a given initial state, closed-orbit theory gives the dependence of this recurrence amplitude on the initial angle of an orbit. By comparing the recurrence amplitudes for different initial states, the initial conditions of closed classical orbits are determined from quantum spectra. (c) 1996 American Institute of Physics. 相似文献
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H. Y. Li X. Zhao S. Gao X. Y. Xu H. Zhou S. L. Lin 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,49(1):1-6
By using the closed-orbit theory including the effect of Coulomb scattering together with an electrical image potential approach,
the recurrence spectra and the dynamical behaviours of the Rydberg hydrogen atom near a metal surface are presented. Theoretical
analysis and numerical simulation reveal that the impacts of the image potential contributing to the recurrence spectrum are
qualitatively analogous to that of the parallel electrical and magnetic fields on the Rydberg atom. The recurrence spectra
are computed for a few selected scaled energies and the results demonstrate that the scaled energy dominates the dynamical
properties of system. With the increase of the scaled energy e from small to large, the whole trend of spectral structure
is from simple to complex,and then simple. 相似文献
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M. Hanif M. Salik Nek M. Sheikh M. A. Baig 《Applied physics. B, Lasers and optics》2013,110(4):563-571
We present the optical emission characteristics of the barium plasma produced at the surface of barium hydroxide Ba(OH)2, also known as baryta, generated by the first harmonic (1,064 nm) of a Q-switched Nd:YAG laser. The laser beam was focused on target material by placing it in air at atmospheric pressure. The experimentally observed line profiles of neutral barium have been used to extract the electron temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadening. The electron temperature is calculated by varying distance from the target surface along the line of propagation of plasma plume and also by varying the laser energy. Besides, we have studied the variation of number density as a function of laser energy as well as its variation with distance from the target surface. It is observed that electron temperature and electron number density increase as laser energy increases. 相似文献