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1.
用准相对论Hartree-Fock方法对Nb XIII离子二电子激发组态3d94s2, 3d94s4p, 3d94p2 的能级结构做了全面系统的理论计算研究.在对已有研究结果分析的基础上, 运用最小二乘方法对径向积分参数进行了优化计算, 得到了与这些组态有关的电偶极允许跃迁的谱线波长和跃迁概率.计算结果与最新的实验值做了对比分析, 表明本文计算结果是准确的. 研究发现, 波长40.92 nm的谱线, 属于3d94s(1D)4p2F7/2–3d9 (2D)4s2 2D5/2 的跃迁谱线, 而不属于3d94s (1D)4p4D7/2–3d9(2D)4s2 2D5/2 的跃迁谱线, 即上谱项能级为2F7/2, 而不是4D7/2.
关键词:
Nb XIII离子
二电子激发组态
谱线波长
跃迁概率 相似文献
2.
Ab initio calculation of the total dielectronic
recombination (DR) rate coefficient from the ground state of Co-like
tantalum is performed using the relativistic distorted-wave
approximation with configuration interaction. The contributions to
the total DR rate coefficients are explicitly calculated from the
complexes of Ni-like tantalum: 3s23p63d3/23 3d5/26
n'l', 3s23p53d10n'l', 3s3p63d10n'l',
3s23p63d84ln'l', 3s23p53d94ln'l' and
3s3p63d94ln'l' with n' ≤ 25, and
3s23p63d85ln'l' with n' ≤ 9. The l' and n'
dependences of partial DR rate coefficients are investigated. The
contributions from higher n'complexes are evaluated by a
level-by-level extrapolation method. The total DR rate coefficients
mainly come from the complex series 3s23p63d84ln'l',
3s23p53d94ln'l' and are fitted to an empirical formula with
high accuracy. Comparison of the present results with those of other
works shows that the previously published data underestimate
significantly the DR rates of Co-like tantalum. 相似文献
3.
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7.
利用“二态矢量模型”详细研究了高电荷态O7+,N6+离子入射Al表面时中间里德伯态的形成过程,给出了电子被俘获至不同量子数(n A=2-7)的几率,以及电子俘获至里德伯态最可能的离子-表面距离.计算结果表明,较大的主量子数nA对应较小的里德伯态几率,因此O7+,N6+离子入射Al表面时辐射的X射线主要来源于较小的n A至基态的退激.为了验证计算结果,测量了O7+,N6+离子入射Al表面的X射线发射谱,并运用FAC程序计算了不同高里德伯态退激到基态的跃迁能(np–1s).实验测量到O,N的K-X射线峰,其特征峰的中心值接近主量子数n=2至n=1的跃迁能,说明发射的X射线主要来源于2p–1s的跃迁,与“二态矢量模型”理论计算的几率一致. 相似文献
8.
9.
应用多组态Dirac-Fock(MCDF)方法,对Xe10+离子进行了理论计算,获得了跃迁波长和概率等数据.通过逐步引入4dn—5pn(n=1, 2, 3)电子相关的相互作用组态,重点研究了电子相关效应对4d8—4d75p跃迁系跃迁概率的影响.结果显示电子相关效应显著,表明了欲得到精确的4d8—4d75p的振子强度(跃迁概率)数据,理论计算中至少要包括到4d2—5p2的电子相关组态的影响.与实验测得的跃迁波长比较发现,理论结果与之有着较好的一致性;同时理论跃迁概率在两种规范下的结果符合得相当精确,显示了计算结果的可靠性.
关键词:
多组态Dirac-Fock(MCDF)方法
电子相关
跃迁概率 相似文献
10.
采用X射线吸收精细结构光谱探索性地研究了多壁碳纳米管束.在多壁碳纳米管束不同入射角的X射线吸收精细结构光谱中,观察到C—H σ*共振峰强度随入射角的变化而发生变化.在常温常压下出现C—H键可能与多壁碳纳米管束中存在缺陷有关,缺陷数量越大C—H σ*共振峰的强度越大.光谱中C—C π*和C—C σ*共振峰强度的变化趋势都不同于C—H σ*共振峰,这有力地证明了在常温常压条件下氢原子是吸附在多壁碳纳米
关键词:
X射线吸收精细结构光谱
碳纳米管
储氢
化学吸附 相似文献
11.
《X射线光谱测定》2006,35(2):106-111
Dy2O3 and Dy metal's resonant inelastic x‐ray scattering (RIXS) spectra were measured in the Beijing Synchrotron Radiation Facility. As a bulk sensitive probe and two‐photon process, RIXS provides more information on the electronic structure of matter. In this full RIXS experiment, the 2p64fn→ 2p54fn5d1 (2p54fn + 15d0) → 2p63d94fn5d1 (2p63d94fn + 15d0) channel of two samples (Dy2O3 and Dy metal) was studied. Further comparison shows that there are many differences in the RIXS spectra. Dy metal has only a single resonance and its 5d band is broader than that of Dy2O3. In the resonant regime, it has a lower final state energy, whereas in the non‐resonant regime it exceeds Dy2O3. This causes a broader bandwidth of the main final state B and a narrower bandwidth in the resonant and non‐resonant regime. The pre‐edge structure in Dy L3 absorption spectra was also resolved using RIXS, which cannot be seen in conventional XAS owing to 2p core hole lifetime broadening. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
12.
Masashi Monobe Hiroyuki A. Sakaue Daiji Kato Izumi Murakami Hirohisa Hara Tetsuya Watanabe Nobuyuki Nakamura 《X射线光谱测定》2020,49(4):511-514
We present extreme ultraviolet spectra of 3s3p–3s3d transitions in Fe14+ observed with a compact electron beam ion trap. The contributions of indirect excitation via a metastable state and resonant excitation are studied by observing the electron energy dependence of the spectra for the energy range of 60–210 eV. The results indicate that the 3s3d 1D2 level is directly excited from the 3s2 ground state whereas the 3s3d 3D3 level has a large contribution of the indirect excitation via the 3s3p 3P2 metastable state. Comparisons with the theoretical excitation cross sections including MNn resonant excitations show good qualitative agreement with the experimental results for the electron energy dependent features. 相似文献
13.
A. A. Borovik 《Optics and Spectroscopy》2011,110(5):680-685
We study the energy dependences of electron excitation cross sections of the autoionizing levels (5p
56s
2)2
P
3/2 and (5p
55d(3
P)6s)2
P
3/2, as well as the autoionization cross sections of cesium atoms in the impact energy range from the excitation threshold to
600 eV. It is established that an increase in the excitation cross section of the 2
P
3/2 levels (to 60% of the maximum value) and the deep minimum in the autoionization cross section observed in the energy region
of 17–27 eV are caused by the predominance of the radiative decay channel for autoionizing levels with excitation thresholds
above 17 eV. The high efficiency of the process is mainly related to the resonance excitation of these levels in the near-threshold
energy region. 相似文献
15.
Hongxin Wang Anthony T. Young Jinghua Guo Stephen P. Cramer Stephan Friedrich Artur Braun Weiwei Gu 《Journal of synchrotron radiation》2013,20(4):614-619
X‐ray absorption and scattering spectroscopies involving the 3d transition‐metal K‐ and L‐edges have a long history in studying inorganic and bioinorganic molecules. However, there have been very few studies using the M‐edges, which are below 100 eV. Synchrotron‐based X‐ray sources can have higher energy resolution at M‐edges. M‐edge X‐ray absorption spectroscopy (XAS) and resonant inelastic X‐ray scattering (RIXS) could therefore provide complementary information to K‐ and L‐edge spectroscopies. In this study, M2,3‐edge XAS on several Co, Ni and Cu complexes are measured and their spectral information, such as chemical shifts and covalency effects, are analyzed and discussed. In addition, M2,3‐edge RIXS on NiO, NiF2 and two other covalent complexes have been performed and different d–d transition patterns have been observed. Although still preliminary, this work on 3d metal complexes demonstrates the potential to use M‐edge XAS and RIXS on more complicated 3d metal complexes in the future. The potential for using high‐sensitivity and high‐resolution superconducting tunnel junction X‐ray detectors below 100 eV is also illustrated and discussed. 相似文献
16.
In nickel-phthalocyanine a resonant enhancement at the 3p?Ni photo-absorption maximum () of a peak approximately 6 eV below the maximum of the Ni 3d derived states is observed in photoemission experiments with variable excitation energy (synchrotron radiation). Our observation of this resonance, explained by configuration interaction of Ni 3p→3d and 3d-continuum transitions, gives direct evidence for the atomic nature of the 6 eV resonance structure in photoemission from bulk Ni. 相似文献
17.
The multiconfiguration Hartree-Fock (MCHF) method is used to calculate the excitation energies and oscillator strengths, of
both the length (f
L) and velocity (f
V) forms, for 1s22s22p63s23p63d2
D→1s22s22p63s23p53d2
2
P
0,2
D
0,2
F
0 transitions in Cr5+, Mn6+ and Fe7+ ions of the potassium isoelectronic sequence. Comparison is made with our earlier relevant results obtained by employing
the configuration interaction (CI) method which is closely related to the MCHF method. Our present investigation demonstrates
that the MCHF method is more accurate than the CI method in all ions of present consideration. 相似文献
18.
采用三台可调谐激光实施孤立实激发,分三步将处于基态的Ba原子激发到6p1/2nd(J=1,3)和6p3/2nd(J=1,3)自电离态上,获得了分别从6snd1D2(n=7—15)和6snd3D2(n=7—12) 激发而得到的6p1/2nd(J=1,3)和6p3/2nd (J=1,3)自电离光谱,重点对主量子数n较低的自电离态进行了实验研究. 通过光谱的线形拟合得到了上述能级的位置和宽度等数据,进而获得了量子亏损和约化宽度等信息. 通过对不同系列的自电离光谱的分析和比较,详细讨论了这些自电离态的光谱特征及其复杂光谱结构的成因.
关键词:
孤立实激发
组态相互作用
自电离态 相似文献
19.
A. Kotani K. O. Kvashnina S. M. Butorin P. Glatzel 《The European Physical Journal B - Condensed Matter and Complex Systems》2012,85(8):1-13
We study both theoretically and experimentally the photon-in and photon-out spectra of CeO2, which are caused by the Ce 2p to Ce 5d excitation followed by the three different de-excitation channels: (i) Ce 3d to Ce 2p (denoted by 3d-RXES), (ii) O 2p to Ce 2p (v-RXES), and (iii) Ce 5d to Ce 2p (RIXS). In 3d- and v-RXES, the 5d electron plays a role of a spectator, but in RIXS it is a participator. By extending our single impurity Anderson model (SIAM), which was used recently for our calculations of v- and 3d-RXES spectra of CeO2, we study the polarization dependence in the spectator and participator spectra, and we perform more detailed calculations for 3d- and v-RXES spectral features, as well as new calculations for the RIXS spectrum with charge transfer excitations. The polarization dependence is different for the spectator and participator spectra; we have no polarization correlation between the incident and emitted photons for the spectator spectra but a strong polarization correlation for the participator spectrum. The theoretical calculations predict that the charge transfer excitations in RIXS occur in the transfer-energy range overlapped with v-RXES, but the RIXS and v-RXES spectra can be discriminated by taking advantage of the different polarization dependence. The overlapped RIXS and v-RXES spectra are observed successfully by our experiments and well reproduced by our SIAM calculations. 相似文献
20.
利用相对论扭曲波方法和新发展的研究电子碰撞激发过程的计算程序REIE06,系统计算了电子碰撞激发高离化态类镍Gd36+和Rn58+—U64+(Z=86—92)离子从基态到4l(l=s,p,d,f)次壳层精细结构能级的碰撞强度和截面.研究了随等电子系列变化时,从基态到与X射线激光有关的3d94p和3d94d激发态能级的电子碰撞激发截面随Z的变化,讨论了强的组态相互作用对高离化态类镍离子截面的影响.通过对Gd36+离子涉及X射线激光跃迁的相关能级电子碰撞激发速率系数的计算,分析了等离子体中电子温度对碰撞过程的影响.同时,目前部分计算结果与以往的理论结果进行了比较,得到了很好的一致性.
关键词:
电子碰撞激发
相对论扭曲波方法
高离化态类镍离子 相似文献