水的热膨胀的特点演示的探讨

初中物理:“水的热膨胀的特点”的演示在我数年的教学中一直没有做过,这主要是因为:当堂演示太费时间又和讲课配合不好,如让学生等着看实验结果,则大部同学感到索然无味,如不等结果而先讲其他内容,则又打乱了课堂的系统性。加以有些学校根本没有水的最大密度演示器,因之过去讲这一节时,往往只用挂图一讲了事。但后来在物理通报上看到一些老师对这个演示采取了各种不同的方法,从而取得了较好的成绩。为了提高教学质量,我把通报上前后所介绍的几种方法都做了几遍,从不断变换着的操作中给了我新的启示,我又用了     

核物质的物态方程的研究

在相对论σ–ω模型的单圈图近似下,详细推导了核物质的能量密度和压强密度表达式,数值计算了核物质的结合能和压强随核密度的变化,并分别在热力学和流体力学的理论框架下,计算了核物质的压强密度,结果表明这两种方法得到的压强密度相同.     

氧的超导性的发现

氧是生物体和生命过程中的一种重要化学元素,也是大气的重要组成部分．氧的化学式为Ｏ２．从较早的科学研究中已经知道［１］,氧具有很强的顺磁性,随着温度的降低,不但氧的顺磁性增强,而且在一定的低温度下会从气态氧转变为液态氧,在一定的低温和压力条件下,还会从...     

气体的压强跟体积的关系的演示

初中物理学上册第三章第35节大气压的一个实验是:水由喷嘴向压强较低的玻璃管中喷入(见原书图55)。这个实验如果没有抽气机,就很难做。我     

铝的激发光谱的测量

用１２０ｋｅＶ的Ａｌ＋离子与１０μｇ／ｃｍ２的碳箔相互作用，研究ＡｌⅠ、ＡｌⅡ和ＡｌⅢ的激发光谱，其结果与其它实验进行了比较。     

光的干涉的应用

在科学和技术領域中,人們不断地利用着光的干涉原理解决了許多复杂的实际問題。例如在技术中对于光学表面磨光的检驗,光学部件质量的精密检定,长度微小改变的精密測定(干涉膨胀仪),增透光薄膜的制作,干涉滤光片的制作,軸承滾珠的分类和检驗等等。此外,对于光譜譜线精細結构的研究,物貭折射率的精密测定等也都逐渐轉入利用光的干涉方法来进行。由于光的干涉的应用是如此之广,因而对光干涉应用的各个方面作一全盘介紹显然是很难作到的,故仅就几个重要应用方面作一初步介紹。一、利用光的干涉检定螺旋測微器(千分尺) 在測微器的待量度的平面之間夹入一已知其厚度     

稳定的驻极体的制备

本文以实验资料和新近理论为依据,论述了稳定的驻极体的制备。在常温下工作的驻极体最好用聚四氟乙烯(PTFE)或聚全氟乙丙烯(FEP)制作;而长期在高温环境中(80—90℃)工作的驻极体,最好用聚二氯对苯撑二甲基(PDCPX)制作。稳定的驻极体的制备,不管用什么方法,极化后的热处理对其稳定性是必要的。     

光的衍射的应用

光波也正如其他类型的波动(例如声波)一样,在其自由传播过程中,当受到某种形式的障碍物的阻挡或限制,都将产生与自由传播方向相偏离的传播現象。这种現象通常借呈现出的一套明暗相间的花样而被我們发觉到。这种現象通常被称作“衍射”。     

力的分解的演示

在高中力学部份讲到力的分解时,学生是很不容易体会出分力的方向。为了使学生能直接而明显的观察分力的方向,我装置了一个演示高一课本(1956年版)第68图的塔式起重机底悬梁和钢索上的分力的一个实验。整个装置如图1,M是一片从蓝球胆上剪下来的胶皮,用按钉固定在竖板上,K处挖一缺口,也用按钉     

气体的压强与体积的关系的实验设计

气体的压强与体积的关系的实验设计陈银潭（江苏兴化市合塔中学２２５７４２）实验目的探索气体的压强与体积的关系．方法一实验器材５０ｍｌ玻璃注射器一只，彩色橡皮膜一块（或小气球）．器材装置（图１）图１实验步骤ｈ用橡皮膜做成直径约Ｚｅｍ的小气球，扎紧口后放人...     

CL20/BTF共晶高温热分解ReaxFF/lg分子动力学模拟

用ReaxFF/lg反应力场模拟CL20/BTF共晶在2000~3000 K高温条件下的热分解过程,获得了势能和物种数的演化、初始反应路径及热分解产物等详细信息。通过指数函数对势能的演化曲线进行拟合得到反映特征时间等参数,采用经典的Arrhenius反应速率方程描述总包反应,获得CL20/BTF共晶的活化能E_a=60.8 kcal/mol。研究得到CL20/BTF共晶热分解的初始路径,CL20分子中N-NO₂首先断裂,在热分解起始阶段占主导作用。在不同温度条件下,CL20分子均在BTF分子前完全分解。CL20/BTF共晶的主要产物为NO₂、NO、NO₃、HNO、N₂、H₂O、CO₂、O₂、N₂O、HONO 等。温度对产物均产生一定程度的影响.     

Computational study of the decomposition mechanisms of ammonium dinitramide in the gas phase

CBS-QB3 method has been employed to determine the geometries, the vibrational frequencies of the reactants, the products and the transition states involved in intramolecular hydrogen-transfer and decomposition reactions of the free gas-phase H₃N···HN(NO₂)₂ (ADN^*). The results show that the intramolecular hydrogen-transfer reaction of ADN^* is more feasible than that of HDN. ADN^* and its hydrogen-transfer isomers ADN^*-IIa,b,c decompose along four channels to form NH₃ + HONO + 2NO (P_I), ?H + ?O₃ + N₂ + NH₃ (P_II), ?H + ?O₂ + N₂O + NH₃ (P_III), and HNO₃ + N₂O + NH₃ (P_IV), respectively. It has been found that the dominant decomposition channels are P_I and P_III. The hydrogen-transfer reaction can reduce the barrier of elimination of NO₂ and forming N₂O reactions in ADN^* and HDN. The decomposition of ADN^*-IIc to form NO₂ and N₂O is more feasible than that of the gas-phase HDN. The rate constants (k) of rate-determining step of ADN^* show that k_PI and k_PIII are higher than k_PIV and k_PII. Compared with HDN-IIc → N₂O+?H+?O₂, k_PIII of ADN^*-IIc is significantly higher than that of k^HDN-IIc. These results reveal that NH₃ (as a chaperon) has a certain influence on the decomposition mechanisms and kinetics of ADN^*.     

Infrared Spectra of trans-nitrobis (2, 4-pentanediono) Aniline-Cobalt(III) Complexes

The infrared spectra of eighteen complexes of general formula trans-[Co(NO₂) (acac)₂ (R-C₆H₄NH₂)] (acac = acetylacetonate anion, R = 3- or 4-aniline substituent) are discussed. ¹⁵N-Labelling of the complexes containing aniline and p-toluidine yields assignments of the N-H, C-N and Co-N stretching frequencies and the N-H bending frequencies. These assignments receive support from the observed frequency shifts induced by varying the substituent R which also permits the assignment of the Co-o stretching frequencies.     

15N-Labelled Ammonium and Nitrate Uptake by the Grass Calamagrostis villosa

Abstract

Calamagrostis villosa dominates the understory vegetation in declining spruce forests at higher elevations of the Central European mountain areas which show symptoms of needle yellowing and associated magnesium (Mg) deficiency. It was hypothesized that grasses would preferentially take up nitrate-nitrogen (NO₃-N) over ammonium-nitrogen (NH₄-N) which would support the cation balance in Mg deficient soils. In order to test this hypothesis, growth experiments were carried out in the greenhouse using plants which were cultivated in sand for nine weeks with full nutrient solution containing 0.2 or 2 mmol of N with different NH₄ ⁺ to NO₃ ^? ratios (1:0, 0.5:0.5, 0:1). In a short term experiment with labelled ¹⁵NH₄ ⁺ and ¹⁵NO₃ ^?, uptake of NH₄ ⁺ and NO₃ ^? was measured. When NO₃ ^? was the only N source it was taken up at similar rate per g dry mass as in the experiment in which NH₄ ⁺ was the only N source. However, at high supply pure NO₃ ^? nutrition resulted in higher biomass. In contrast, supply of only NH₄ ⁺ caused accumulation of N in the roots but growth remained restricted. If NH₄ ⁺ and NO₃ ^? were supplied at equal amounts, NH₄ ⁺ was the preferred form for N uptake. Biomass of the plants with mixed supply did not differ from the plants with pure NO₃ ^? nutrition.

The results point to an interesting interaction of carbon and nitrogen relation, but they do not support the initial hypothesis that grasses may prefer NO₃ ^? over NH₄ ⁺.     

Surface science studies of selective catalytic reduction of NO: Progress in the last ten years

Selective catalytic reduction (SCR) of NO_x is one of the important strategies in regulating NO_x emissions. In the past several decades, the reactions of NO_x (mainly NO) with H₂, CO, NH₃ and hydrocarbons have been extensively investigated under ambient conditions and have been summarized in numerous reviews. Nonetheless, many questions appear to be difficult to answer under ambient conditions, e.g., the pathways through which the reactions proceed. The introduction and development of modern surface science technology has played an indispensable role and is widely employed in the studies of the SCR of NO_x, greatly helping to elucidate the mechanisms of the reactions with CO, H₂, and NH₃. However, so far, there are few review papers systematically summarizing the progress of such studies.Recently, systematic surface science studies have been conducted on the mechanisms of SCR of NO with organic molecules including ethylene, benzene, and ethanol, which are much more complicated than those with H₂, CO and NH₃ and have drawn much less attention before. It is confirmed that these reactions can be reliably and most importantly, reproducibly probed by surface science technology, but a great deal of work remains to be done.Since Delmon et al. have provided a very thorough review of the researches on catalytic removal of NO (reactions with H₂, CO and NH₃) up to 1998, in which the reactions conducted both under ambient and UHV conditions were included, this review mainly concentrates on the progress made since 1998.     

An experimental and modeling study on auto-ignition of ammonia in an RCM with N2O and H2 addition

Deep insights into the combustion kinetics of ammonia (NH₃) can facilitate its application as a promising carbon-free fuel. Due to the low reactivity of NH₃, experimental data of NH₃ combustion can only be obtained within a limited range. In this work, nitrous oxide (N₂O) and hydrogen (H₂) were used as additives to investigate NH₃ auto-ignition in a rapid compression machine (RCM). Ignition delay times for NH₃, NH₃/N₂O blends, and NH₃/H₂ blends were measured at 30 bar, temperatures from 950 to 1437 K. The addition of N₂O and H₂ ranged from 0 to 50% and 0 to 25% of NH₃ mole fraction, respectively. Time-resolved species profiles were recorded during the auto-ignition process using a fast sampling system combined with a gas chromatograph (GC). An NH₃ combustion model was developed, in which the rate constants of key reactions were constrained by current experimental data. The addition of N₂O affected the ignition of NH₃ primarily through the decomposition of N₂O (N₂O (+M) = N₂ + O (+M), R1) and direct reaction between N₂O and NH₂ (N₂H₂ + NO = NH₂ + N₂O, R2). The rate constant of R2 was constrained effectively by experimental data of NH₃/N₂O mixtures. Two-stage ignition behaviors were observed for NH₃/H₂ mixtures, and the corresponding first-stage ignition delay times were reported for the first time. Experimental species profiles suggested the first-stage ignition resulted from the consumption of H₂. The oxidation of H₂ provided extra HO₂ radicals, which promoted the production of OH radicals and initiated first-stage ignition. Reactions between HO₂ radicals and NH₃/NH₂ dominated the first-ignition delay times of NH₃/H₂ mixtures. Moreover, the first-stage ignition led to the fast production of NO₂, which acted as a key intermediate and affected the following total ignition. Consequently, the reaction NH₂ + NO₂ = H₂NO + NO (R3) was constrained by total ignition delay times.     

Tuning the electronic and magnetic properties of germanene by surface adsorption of small nitrogen-based molecules

The structural, energetic and electronic properties of germanene adsorbed with small nitrogen-based molecules, including N₂, NH₃, NO₂ and NO, have been investigated by using first-principles calculations. The results show that all nitrogen-based molecules considered bind much stronger to germanene than to graphene due to the hybridized sp²-sp³ bonding of Ge atoms. The N₂, NO and NO₂ molecules all act as an acceptor, while the NH₃ molecule donates electrons to germanene. We also found sizable band gaps (2–158 meV) are opened at the Dirac point of germanene through N₂, NH₃, and NO₂ adsorptions, but with only slightly destroying its Dirac cone shape. The NO₂ molecule also shows a heavy p-type doping character and makes germanene to be metallic. Moreover, when adsorbed by NO molecule, the germanene can change to be a ferromagnetic half-metal with 100% spin-polarization at the Fermi level. Overall, the different adsorption behaviors of small nitrogen-based gas molecules on germanene provide a feasible way to exploit chemically modified germanene for a wide range of practical applications, such as field-effect transistors, gas sensors and spintronic devices.     

Shock tube study of the interaction between ammonia and nitric oxide at high temperatures using laser absorption spectroscopy

The interaction between ammonia (NH₃) and nitric oxide (NO) at high temperatures is studied in this work using a shock tube combined with laser absorption diagnostics. The system simultaneously measured the NH₃ and NO time-histories during the reaction processes of the shock-heated NH₃/NO/CO/Ar mixtures (NH₃:NO ≈ 0.9:1.0 and 1.4:1.0). The absorption cross-sections of NH₃ near 1122.10 cm^–1 and NO at 1900.52 cm^–1 (characterized in this study) were used for measuring NH₃ and NO time-histories with the temperature measured by two CO absorption lines. The measured NH₃ and NO time-histories at 1614–1968 K and 2.4–2.8 atm were compared with predictions of seven recent kinetics models. The predictions that based on different mechanisms are very different and the measured profiles are within the range of the predictions. The Glarborg, NUI Galway Syngas-NOx, and Mathieu mechanisms give the closest predictions to the measurements. Kinetics analyses indicate that the NH₃ and NO consumption rates are extremely sensitive to the rate constants and branching ratio of NH₂ + NO = N₂ + H₂O and NH₂ + NO = NNH + OH, which are more reliably represented in the Glarborg and NUI Galway Syngas-NOx mechanisms. The performances of Glarborg mechanisms at lower initial temperatures can be apparently improved by revising the rate constants and branching ratio of NH₂ + NO = N₂ + H₂O and NH₂ + NO = NNH + OH. These two reactions are also the primary pathways for NO reduction and NH₃ is mainly consumed via NH₃ + OH = NH₂ + H₂O and NH₃ + H = NH₂ + H₂. Trace amounts of NO₂ and N₂O impurities decompose to form O radical followed by the generation of OH radical via H-abstraction reactions, which significantly affects the predictions of NH₃ and NO according to kinetics analyses.     

Conductivity studies of starch-based polymer electrolytes

A proton-conducting polymer electrolyte based on starch and ammonium nitrate (NH₄NO₃) has been prepared through solution casting method. Ionic conductivity for the system was conducted over a wide range of frequency between 50 Hz and 1 MHz and at temperatures between 303 K and 373 K. Impedance analysis shows that sample with 25 wt.% NH₄NO₃ has a smaller bulk resistance (R _b) compared to that of the pure sample. The amount of NH₄NO₃ was found to influence the proton conduction; the highest obtainable room temperature conductivity was 2.83 × 10⁻⁵ S cm⁻¹, while at 100 °C, the conductivity in found to be 2.09 × 10⁻⁴ S cm⁻¹. The dielectric analysis demonstrates a non-Debye behavior. Transport parameters of the samples were calculated using the Rice and Roth model and thus shows that the increase in conductivity is due to the increase in the number of mobile ions.