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利用溶胶-凝胶法制备了纳米多晶La0.7Sr0.3MnO3-δ(LSM)块体样品.详细研究了在不同烧结温度下的LSM样品电阻率随测量温度的变化关系和磁电阻效应.随着测量温度从室温降低,电阻率ρ都在250K附近存在最大值,低于该温度后,样品表现为金属导电特性,随后在50K左右存在一极小值.即随着温度从50K左右降低到4.2K,ρ反而逐渐升高,表现为绝缘体性的导电特性.研究表明,在低温下(<50K),ρ随温度降低而升高的现象与隧穿效应的理论模型(lnρ∝T1/2)符合得很好,表明这种现象是由于传导电子在通过邻近LSM晶粒间表面/界面层时的隧道效应所致.而在50—250K的温度范围内,其电阻率与T2成正比,表现为LSM本征的金属导电特性.因此这种低温下电阻率的极小值现象来源于隧穿效应和LSM晶粒本征的金属导电特性的相互竞争.本文还详细研究了相应的隧道磁电阻效应.
关键词:
0.7Sr0.3MnO3-δ')" href="#">多晶La0.7Sr0.3MnO3-δ
隧道效应
隧道磁电阻效应 相似文献
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利用磁控溅射和Sr成分的调制以及原位热处理方法,在10mm×10mm大小的(001) 取向SrTiO3单晶衬底上制备出三明治结构为La0.7Sr0.3MnO3(100nm)/La0.96Sr0.04MnO3 (5nm)/ La0.7Sr0.3MnO3 (100nm) 的隧道结外延薄膜,然后再次 利用磁控溅射方法,在三层单晶膜上方继续沉积Ir22Mn78(15n m)/Ni79Fe21(5nm)/Pt(20nm)等金属三层膜.最后利用深紫外曝 光和Ar离子束刻蚀等微加工技术,制备出长短轴分别为12和6μm或者8和4μm大小的椭圆形L a1-xSrxMnO3成分调制的复合磁性隧道结.在4.2K和 外加磁场8 T的测试下,La1-xSrxMnO3成分调制的复 合磁性隧道结其隧穿磁电阻(TMR)比值达到3270%, 直接从实验上证实了铁磁性La0.7 sub>Sr0.3MnO3金属氧化物的自旋极化率(97%)可接近100%,具 有很好的半金属性质.
关键词:
1-xSrxMnO3')" href="#">La1-xSrxMnO3
半金属
成分调制
复合磁性隧道 结
隧穿磁电阻 相似文献
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详细研究了由纳米晶粒组成的块体多晶La0.7Sr0.3MnO3(LSM)的电阻率和磁电阻效应,以及它们的温度依赖性.随着温度从室温降低,电阻率(ρ)在250K附近存在一最大值,低于该温度后,样品表现为金属导电特性,随后在50K附近存在一极小值.也就是说在低于50K的温度范围内,随着温度降低ρ反而升高,表现为绝缘体性的导电特性.经研究发现,这种随温度降低ρ反而增加的现象与隧穿效应的理论模型(lnρ∝T-1/2)符合得很好
关键词:
0.7Sr0.3MnO3')" href="#">多晶La0.7Sr0.3MnO3
隧道效应
隧道磁电阻效应 相似文献
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通过对La0.8Sr0.2Mn1-yCoyO3(y≤02)饱和磁矩和输运的测量,研究了Co对La0.8Sr0.2MnO3的磁电阻影响机制.结果表明,在La0.8Sr0.2Mn1-yCoyO3(y≤02)中Co3+离子是低自旋态.由于Mn3+—O—Co3+—O—Mn3+类型的磁交换与Mn3+-Mn4+离子间双交换作用相比较弱,Curie温度TC附近的磁电阻随着Co掺杂量的增加而降低.与此相反,由于Co2+离子与eg巡游电子的反铁磁交换耦合作用,低温区间的磁电阻随着Co掺杂量的增加而升高.
关键词:
低自旋
磁电阻
磁交换作用 相似文献
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采用传统的高温固相烧结法制备了双层钙钛矿锰氧化物(La1-xGdx)4/3Sr5/3Mn2 O7 (x=0, 0.025)多晶样品. 通过X射线衍射仪研究发现样品为Sr3Ti2O7型四方结构, 空间群为I4/mmm; 磁性测量表明, Gd3+掺杂后的样品(La0.975Gd0.025)4/3Sr5/3Mn2O7的三维磁有序转变温度(TC13D)、磁化强度(M)均降低, 这是由于Gd3+的掺杂引起晶格的畸变, 从而使得晶格常数发生改变, 减弱了铁磁耦合而导致的; 通过电子自旋共振谱测量发现, 在TC3D<T<300 K温度范围内, 两样品在顺磁的基体上均有短程的铁磁团簇存在, 出现了相分离现象. 电性测量表明: 两样品分别在TC13D (La4/3Sr5/3Mn2O7 样品的三维磁有序转变温度, TC03D)<T<300 K温度范围内均以三维变程跳跃的方式导电, 分析得出Gd3+的掺杂使得载流子局域长度的减小. 这表明载流子需要吸收更多的能量才能克服晶格的束缚进行跳跃, 因此(La0.975Gd0.025)4/3Sr5/3Mn2 O7 样品的电阻较高. 相似文献
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采用改进的溶胶-凝胶方法在单晶Si(100)衬底上制备了介电性能优异的(Ba0.7Sr0.3)TiO3/LaNiO3异质薄膜.实验发现,在750 ℃下 、O2气氛中晶化的LaNiO3薄膜的电阻率最小.C-V与I-V特性测量表明(Ba0.7Sr0.3)TiO3薄膜具有优异的介电性能,在频率为50kHz、零偏压下的相对介电常数εr>300,偏压为6V时漏电流密度JL<1.2×10-6A/cm2.
关键词:
xSr1-x)TiO3铁电薄膜')" href="#">(BaxSr1-x)TiO3铁电薄膜
3底电极')" href="#">LaNiO3底电极
溶胶-凝胶法 相似文献
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采用脉冲激光沉积技术制备了Ti/Pr0.7Ca0.3MnO3/Pt和Ti/Pr0.7Ca0.3MnO3/La0.67Sr0.33MnO3/Pt异质结并研究了La0.67Sr0.33MnO3功能插层对异质结电致电阻特性的影响. 实验结果表明La0.67Sr0.33MnO3功能层的引入有效提高了器件的电阻转变特性,尤其是电阻转变率和疲劳性得到了极大的改善. 对La0.67Sr0.33MnO3插层改善电致电阻转变特性的机理进行了定性的分析.
关键词:
电致电阻效应
电阻转变比率
疲劳特性 相似文献
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研究了钙钛矿型锰氧化物La2/3Ca1/3Mn1-xTixO3(0≤x≤0.3)的结构、磁性和输运性质.发现Ti替代Mn强烈地抑制了La2/3Ca1/3MnO3的铁磁性和金属电导,并很大地提高了磁电阻值.在低掺杂情况下(x≤0.04),1%的Mn被Ti替代,居里温度TC和金属-绝缘体转变温度Tp分别平均下降了31和26.5K.当x=0.06时,铁磁态过渡为团簇玻璃态,并在x=0.20时完全变为自旋玻璃态.指出由于Ti的掺入而引起的磁稀释作用以及局域晶格畸变是产生上述结果的主要原因.
关键词: 相似文献
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Magnetic interaction in Mg, Ti, Nb doped manganites 总被引:4,自引:0,他引:4
I.O. Troyanchuk M.V. Bushinsky H. Szymczak K. Bärner A. Maignan 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(1):75-80
An effect of Mn substitution with Me=Mg2+, Ti4+, Nb5+ in manganites has been investigated by preparing La0.7Sr0.3(Mn1-xMex)O3 and La1-xSrx(Mn1 - x/2Nbx/2)O3 series. It was established that substitution of manganese with magnesium up to x = 0.16 leads to a collapse of a long-range ferromagnetic order whereas La0.7Sr0.3(Mn 3 +
0.85Nb 5 +
0.15)O3 is ferromagnet with T
C = 123 K and exhibits a large magnetoresistance below Curie point despite an absence of four-valent manganese. Hypothetical
magnetic phase diagrams are constructed for La0.7Sr0.3(Mn1-xMex)O3 and La1-xSrx(Mn1 - x/2Nbx/2)O3. Our results show that Mn3+-O-Mn3+ exchange interaction is ferromagnetic in the orbitally disordered manganites as well as an increase of Mn4+ content above 50% from a total amount of manganese ions leads to formation of a spin glass state due to a competition between
antiferromagnetic Mn4+-O-Mn4+ and ferromagnetic Mn3+-O-Mn4+(Mn3+) superexchange interactions.
Received 24 January 2002 Published online 9 July 2002 相似文献
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Pedro A. Montano Yinwan Li J.F. Mitchell P.E. Mijnarends S. Kaprzyk A. Bansil 《Journal of Physics and Chemistry of Solids》2004,65(12):1999-2004
Magnetic Compton profiles have been measured for the colossal magnetoresistance manganites La1.2Sr1.8Mn2O7 and La0.7Sr0.3MnO3, and for magnetite Fe3O4, along various crystallographic directions, over a wide range of temperatures and magnetic fields. The experimental results are interpreted via first-principles computations for the double layer manganite, La1.2Sr1.8Mn2O7, and by using a simple model involving atomic d-orbitals and free electrons for the other two compounds. For all three materials a preference for the occupation of eg orbitals is found, particularly, for orbitals of dx2−y2 symmetry. An itinerant electron contribution is adduced at all temperatures in magnetite; such a contribution also appears in La1.2Sr1.8Mn2O7, but it is present only at low temperatures in La0.7Sr0.3MnO3. 相似文献
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Sonia Ben Abdelkhalek Sami Kallel Octavio Peña 《Journal of magnetism and magnetic materials》2010,322(21):3416-4067
The structural, magnetic and electrical properties of Cr and Fe simultaneously substituted in the perovskite La0.6Sr0.4Mn1−2xCrxFexO3 have been studied. The presence of Cr and Fe had no significant effect on the structural properties. Curie temperature and saturation magnetization decrease with increase in Cr and Fe contents. For x=0.20 and 0.25, a steep drop of zero field-cooled (ZFC) magnetization at low temperature signifies the formation of cluster- or spin-glass state. A weak hysteresis at low fields seems to be an indication of phase separation. All the resulting magnetization curves can be explained by a superposition of both ferromagnetic and antiferromagnetic components. All the samples are semiconducting throughout the temperature range studied. Resistivity can be described by the adiabatic small polaron hopping and the variable range hopping model. It was found that the transport mechanism is dominated by the VRH model with an increase of Mott localization energy, which explains the increase of resistivity. 相似文献
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The magnetic and transport properties in the perovskite Sr1−xLaxFe1−xMnxO3 have been explored. As x rises, the systemic ferromagnetism increases gradually and cluster-spin-glass state occurs in the low-temperature region. For 0.3?x?0.7, the ferromagnetic phase separation from the paramagnetic phase was observed from the results of electron-spin-resonance measurement. Although all samples show a semiconducting behavior, their transport properties are dominated by two different mechanisms, namely, the electronic transport of x?0.5 samples is realized by thermal activation but the variable-range hopping is applied in x?0.7 ones. The different transport mechanism can be understood from the Mn/Fe ions interaction. 相似文献
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《Journal of magnetism and magnetic materials》2001,225(3):331-336
The single crystals of La0.7Ba0.3(Mn1−xFex)O3 (x⩽0.28) and La0.7Ba0.3(Mn1−xAlx)O3 (x⩽0.15) compositions were grown using flux method and characterized by X-ray, electrical and magnetization measurements. The Fe-doping above x=0.2 destroys a long range ferromagnetic order thus leading to a spin glass state. It is found that insulating spin glasses exhibit a large magnetoresistance in the paramagnetic region which is comparable to that for ferromagnetic crystals showing metal–insulator transition close to TC. The magnetic behavior of La0.7Ba0.3(Mn1−xMex)O3 (Me=Fe, Cr, Al) ceramics is in agreement with superexchange magnetic interactions via oxygen. 相似文献
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通过对La0.3Ca0.7Mn1-xWxO3(x=0.00,0.04,0.08,0.12,0.15)多晶样品M-T曲线、M-H曲线及ESR谱的测量,研究了Mn位W掺杂对电荷有序体系La0.3Ca0.7MnO3磁结构的影响.结果表明,当掺杂量为0.00≤x≤0.08时,体系存在电荷有序(CO)相,AFM/CO态共存于相变温度以下,电荷有序温度TCO随着W掺杂量的增加而增加;x=0.04时,样品在低温下为FM相与AFM/CO相共存,在CO相建立前、后均有FM从PM中分离出来;当x≥0.12时,CO态融化,在极低温度下存在顺磁-铁磁(PM-FM)相变.
关键词:
磁结构
电荷有序
融化
Mn位掺杂 相似文献
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S.K. BarikC. Krishnamoorthi R. Mahendiran 《Journal of magnetism and magnetic materials》2011,323(7):1015-1021
We have studied the effect of Fe substitution on magnetic and magnetocaloric properties in La0.7Sr0.3Mn1−xFexO3 (x=0.05, 0.07, 0.10, 0.15, and 0.20) over a wide temperature range (T=10-400 K). It is shown that substitution by Fe gradually decreases the ferromagnetic Curie temperature (TC) and saturation magnetization up to x=0.15 but a dramatic change occurs for x=0.2. The x=0.2 sample can be considered as a phase separated compound in which both short-range ordered ferromagnetic and antiferromagnetic phases coexist. The magnetic entropy change (−ΔSm) was estimated from isothermal magnetization curves and it decreases with increase of Fe content from 4.4 J kg−1 K−1 at 343 K (x=0.05) to 1.3 J kg−1 K−1 at 105 K (x=0.2), under ΔH=5 T. The La0.7Sr0.3Mn0.93Fe0.07O3 sample shows negligible hysteresis loss, operating temperature range over 60 K around room temperature with refrigerant capacity of 225 J kg−1, and magnetic entropy of 4 J kg−1 K−1 which will be an interesting compound for application in room temperature refrigeration. 相似文献
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H. Gamari-Seale I.O. Troyanchuk K.L. Stefanopoulos 《Physica B: Condensed Matter》2008,403(17):2924-2929
In this paper we report the study of the perovskites La0.7Ca0.3Mn0.5Co0.5O3 and La0.8Sr0.2Mn0.5Co0.5O3 by neutron powder diffraction at various temperatures and magnetization measurements in zero applied field and at low cooling regimes. The replacement of half Mn by Co in La0.7Ca0.3MnO3 and La0.8Sr0.2MnO3 destroys their long-range ferromagnetism exhibiting a cluster glass ferromagnetic order similar to the one observed in many cobaltites. 相似文献
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Á. Cziráki I. Gerőcs M. Köteles A. Gábris L. Pogány I. Bakonyi Z. Klencsár A. Vértes S.K. De A. Barman M. Ghosh S. Biswas S. Chatterjee B. Arnold H.D. Bauer K. Wetzig C. Ulhaq-Bouillet V. Pierron-Bohnes 《The European Physical Journal B - Condensed Matter and Complex Systems》2001,21(4):521-526
A structural study has been performed on the La0.8Sr0.2FexCo1-xO3 (x = 0.025 to 0.3) system displaying large magnetoresistance (MR) at room temperature. A detailed analysis of the crystal structure and microstructure was done by X-ray diffraction (XRD),
transmission and scanning electron microscopy (TEM and SEM). The atomic resolution TEM images and the appearing superreflections
in the corresponding SAED patterns revealed that a superstructure is formed due to the presence of iron. The correlation between
the ordered microstructure and the observed large MR ratio is discussed. 57Fe M?ssbauer spectroscopy was utilized to gain information on the valence state of iron in the sample with x = 0.3. The lattice parameters of Fe- doped La0.8Sr0.2FexCo1-xO3 compounds were found to increase monotonously with increasing Fe content. The valence state of iron was found to be Fe3+.
Received 22 January 2001 相似文献