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采用光致发光谱、光致发光激发谱以及拉曼光谱对GaN基量子阱材料进行了实验观察和分析 .实验结果表明样品中量子点结构不均匀及InGaN层中In成分分布不均匀 ,且其光致发光谱的波峰是由自由激子辐射复合发光引起的 .同时由室温下InGaN/GaN量子阱的拉曼谱可得知InGaN/GaN多量子阱的结构特征 相似文献
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研究了GaN/AlGaN异质结构中的双带(中、远)红外探测及光子频率上转换特性.通过光致发光光谱确认GaN/AlGaN探测器结构中AlGaN本征层的Al组分,讨论了不同Al组分GaN/AlGaN异质结的导带带阶界面功函数差.在拟合单周期GaN/AlGaN探测器中红外和远红外波段响应谱的基础上,研究多周期GaN/AlGaN探测器与GaN/AlGaN发光二极管集成结构的中红外和远红外光子频率上转换效率与GaN发射层厚度、AlGaN本征层厚度、紫光光子出射效率、内量子效率、空间频率和发射层掺杂浓度间的关系,优化
关键词:
双带红外探测
光子频率上转换
响应谱
GaN/AlGaN 相似文献
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利用离子注入方法和光致发光技术系统研究了注入离子对n型GaN宽黄光发射带的影响.实验采用的注入离子为:N,O,Mg,Si和Ga,剂量分别为1013,1014,1015和1016/cm2,注入温度为室温.注入后的样品在900 ℃流动氮气环境下进行热退火,退火时间为10 min,并对退火前后的样品分别进行室温光致发光测量.通过实验数据的分析,独立提出了提取注入离子对晶体黄光发光特性影响的半经验模型.利用该模型导出的公式,可以确定注入的N,O,Ga,Mg和Si离子对黄光发射带的影响随注入剂量的变化关系以及该影响的相对强弱.
关键词:
氮化镓
光致发光谱
离子注入 相似文献
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GaN垒层厚度渐变的双蓝光波长发光二极管 总被引:2,自引:0,他引:2
针对单蓝光波长芯片与Y3Al5O12∶Ce3+黄光荧光粉封装白光发光二极管存在显色性不足的问题,提出了采用双蓝光波长芯片激发Y3Al5O12∶Ce3+黄光荧光粉实现高显色性白光发射法,并分析了其可行性.利用金属有机化学气相沉积系统在(0001)蓝宝石衬底上顺序生长两个In0.18Ga0.82N/GaN量子阱和两个In0.12Ga0.88N/GaN量子阱的双蓝光波长发光二极管,并对不同GaN垒层厚度的双蓝光波长发光二极管的光电性能进行分析,结果表明沿n-GaN到p-GaN方向减小GaN垒层厚度能实现双蓝光发射,并有较好的发光效率.交流阻抗谱结果显示相关双蓝光波长发光二极管可以用一个电阻Rp与电容Cp并联后与一个Rs串联电路来模拟,GaN垒层变化能调节并联电阻和电容,对串联电阻没有影响.此外,基于垒层减小的双蓝光波长芯片激发Y3Al5O12∶Ce3+荧光粉实现了高显色指数的白光发射. 相似文献
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二氧化钛胶体及其自组装薄膜的光谱分析 总被引:3,自引:1,他引:2
水解钛酸四丁酯制备了二氧化钛胶体;采用静电自组装技术制备了聚电解质与二氧化钛胶体的复合薄膜;采用吸收光谱和荧光光谱对二氧化钛胶体及其复合薄膜进行了表征。吸收光谱显示,胶体的吸收带边蓝移,显示出量子尺寸效应,胶体的荧光光谱出现了多个发光带,最短发光波长位于371nm,发光主要集中在蓝光区域内;在252nm光源激发下。复合薄膜的发射谱带具有二氧化钛水溶胶的发射谱带的特征,荧光发射主要来源于二氧化钛,聚电解质的引入对复合薄膜的光致发光特性有一定影响。 相似文献
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研究了Er1.0P5O14铒非晶玻璃的红外量子剪裁现象. 从吸收谱和激发光谱的计算比较中肯定了Er1.0P5O14非晶 玻璃的1537.0 nm红外荧光为多光子量子剪裁荧光. 从Er1.0P5O14非晶玻璃的可见和红外荧光发射光谱中发现激发2H11/2, 4G11/2和4G9/2能级所导致的4I13/2→4I15/2量子剪裁红外荧光很强;基于自发辐射速率、无辐射弛豫速率和能量传递速率等参数的计算,对其量子剪裁机理进行了分析.发现起源于基态的强下转换能量传递{2H11/2→4I9/2,4I15/2→4I13/2},{4G11/2→4I13/2, 4I15/2→2H11/2},{4G9/2→4F7/2,4I15/2→4I13/2}和{4G9/2→4I13/2, 4I15/2→2H11/2}是导致Er1.0P5O14非晶玻璃具有强的三光子和四光子量子剪裁红外荧光的原因.研究结果对改善太阳能电池效率有一定意义. 相似文献
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We study the discrete Painlevé equations associated to the affine Weyl group which can be obtained by the implementation of a special limits of -associated equations. This study is motivated by the existence of two -associated discrete both having a double ternary dependence in their coefficients and which have not been related before. We show here that two equations correspond to two different limits of a -associated discrete Painlevé equation. Applying the same limiting procedures to other -associated equations we obtained several -related equations most of which have not been previously derived. 相似文献
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An attempt is made to synthesize Nd2Co14C compound by mechanical alloying Nd16Co76B8−xCx (0x8) alloys and subsequent annealing. Phase formation and magnetic properties of Nd2Fe14B-type Nd16Co76B8−xCx alloys and their hydrides are investigated. The Nd2Co14(B,C) phase with Nd2Fe14B-type structure is formed for Nd16Co76B8−xCx (0x7) alloys, while NdCo7Cδ phase with TbCu7-type structure is observed in Nd16Co76C8 alloy. The lattice parameter c of the Nd2Co14(B,C) phase decreases with increasing the carbon content. A limit volume of the unit cell to form the Nd2Fe14B-type structure is estimated to be 0.870 nm3. The spin-reorientation temperature TSR increases with increasing the carbon content, due to an enhancement of magnetocrystalline anisotropy caused by carbon substitution for boron. After hydrogenation, the lattice expansion is observed for Nd16Co76B8−xCx (0x7) alloys. The spin-reorientation temperature of Nd16Co76B8−xCxHy (0x7) is much lower than that of the host alloys. Some structural and magnetic properties of hypothetic Nd2Co14C and Nd2Co14CHy compounds are estimated by extrapolation. 相似文献
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Abstract Earlier, when investigating H-complexes of the RO-H…BR1 type in solutions 1–3 and crystalline state 4, the isotopic shift for frequencies of the stretching vibrations (OH) at substitution of H for D was shown to systematically decrease with increased strength of the H-bond. In strong H-complexes, the (OH) and (OD) bands in the i.r. spectra have a complex structure: depending on the strength of the H-complex in a wide range of frequencies (3000–1000 cm?1), several submaxima caused by a Fermi-resonance interaction of the fundamental tone of (OH) with combinations and overtones in the bending vibrations of R-O-H were observed 1–5. Hence, the frequencies and intensities of the (OH) and (OD) bands in strong H-complexes should be considered as corresponding to the gravity centre (°) and overall intensity (A°) of all the 相似文献