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以N-十二烷基二甲基铵基乙酸为增敏剂催化光度法测定锰 总被引:13,自引:0,他引:13
基于存在增敏剂N-十二烷基二甲基铵基乙酸(DDMAA)和活化剂氨三乙酸,锰(Ⅱ)催化高碘酸钾氧化萘酚绿B的反应,拟定了测定痕量锰的新催化光度法。本法在两性表面活性剂DDMAA存在下,灵敏度提高10.3倍(Mn~(2+)量为0~6.0μg/L)和5.3倍(Mn~(2+)量为6.0~14μg/L),相对标准偏差为0.5%,检出限为5.6×10~(-8)g/L,可用于酒样和谷物制品中锰的测定。 相似文献
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以十二烷基硫酸钠为增敏剂催化光度法测定痕量锰 总被引:5,自引:0,他引:5
报道了以阴离子表面活性剂十二烷基硫酸钠(SDS)为增敏剂,高碘酸钾氧化茜素绿催化之度法测定衣量锰的方法。方法中添加了阴离子表面活性剂SDS,灵敏度提高4.3涪(锰含量0-0.6ns·ml-1)和5.7倍(锰含量0.6-1.6ng·ml-1),相对标准偏差为2.6%(n=11),检出限为4.06×10-11g·ml-1。 相似文献
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研究了测定痕量锰的新催化光度法,在pH11.90的条件下,锰(Ⅱ)催化高碘酸钾氧化酸性铬蓝K的反应。测定锰的线性范围为0—8.0ng/mE,检出限为0.05ng/mL。用于饮用水中锰的测定,方法的回收率在94.3%-102.7%范围内,结果令人满意。 相似文献
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催化过氧化氢氧化铬黑T褪色光度法测定痕量锰(Ⅱ) 总被引:3,自引:0,他引:3
朱国辉 《分析测试技术与仪器》2002,8(4):226-228
在pH11.0的Na2B4O7-NaOH缓冲溶液中十二烷基磺酸钠(DBS)可增敏Mn(II)催化过氧化氢氧化铬黑T(EBT)的褪色反应,据此建立了催化褪色光度法测定痕量锰(Ⅱ)的新方法,锰(Ⅱ)浓度在5.0-12.0ug/L范围内服从比耳定律,回归方程ΔA=-0.014 0.32CMn(Ⅱ)(μg/L),r=0.9999检出限0.5ng/mL,应用该法测定人发和茶叶中的Mn(Ⅱ),测定结果满意。 相似文献
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Reactions in droplets in microfluidic channels 总被引:5,自引:0,他引:5
Fundamental and applied research in chemistry and biology benefits from opportunities provided by droplet-based microfluidic systems. These systems enable the miniaturization of reactions by compartmentalizing reactions in droplets of femoliter to microliter volumes. Compartmentalization in droplets provides rapid mixing of reagents, control of the timing of reactions on timescales from milliseconds to months, control of interfacial properties, and the ability to synthesize and transport solid reagents and products. Droplet-based microfluidics can help to enhance and accelerate chemical and biochemical screening, protein crystallization, enzymatic kinetics, and assays. Moreover, the control provided by droplets in microfluidic devices can lead to new scientific methods and insights. 相似文献
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The toxicity of inorganic trivalent arsenic for living organisms is reduced by in vivo methylation of the element. In man, this biotransformation leads to the synthesis of monomethylarsonic (MMA) and dimethylarsinic (DMA) acids, which are efficiently eliminated in urine along with the unchanged form (Asi). In order to document the methylation process in humans, the kinetics of Asi, MMA and DMA elimination were studied in volunteers given a single dose of one of these three arsenicals or repeated doses of Asi. The arsenic methylation efficiency was also assessed in subjects acutely intoxicated with arsenic trioxide (As2O3) and in patients with liver diseases. Several observations in humans can be explained by the properties of the enzymic systems involved in the methylation process which we have characterized in vitro and in vivo in rats as follows: (1) production of Asi metabolites is catalyzed by an enzymic system whose activity is highest in liver cytosol; (2) different enzymic activities, using the same methyl group donor (S-adenosylmethionine), lead to the production of mono- and di-methylated derivatives which are excreted in urine as MMA and DMA; (3) dimethylating activity is highly sensitive to inhibition by excess of inorganic arsenic; (4) reduced glutathione concentration in liver moderates the arsenic methylation process through several mechanisms, e.g. stimulation of the first methylation reaction leading to MMA, facilitation of Asi uptake by hepatocytes, stimulation of the biliary excretion of the element, reduction of pentavalent forms before methylation, and protection of a reducing environment in the cells necessary to maintain the activity of the enzymic systems. 相似文献
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Electrochemistry is one of the most advanced techniques for monitoring neurochemical activities in the living brain because electrochemical approaches bear the advantageous features of high spatial and temporal resolutions, which facilitate its tremendous potential in investigating the highly spatially heterogeneous brain system and the fast dynamics of neurochemical activities. On the other hand, since brain is the most complicated organ in the sense of its numerous kinds of neurochemical species, high selectivity is always required for any analytical methods that approach the brain. In this review, we will discuss various electrochemical methodologies to achieve selective detection of neurochemicals in mammalian brain and the strategies developed mainly by our group towards selective monitoring of both electrochemically active and inactive neurochemicals. At the end, we will discuss possible solutions towards brain mapping of neurochemical species and combination of neurochemical detection strategy with electrophysiology as the direction of future development of electroanalysis in living brain. 相似文献
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G. den Boef 《Fresenius' Journal of Analytical Chemistry》1981,305(2):127-129
Summary At the session of the WPAC of Fechem on education in analytical chemistry it was concluded that it is now essential to include chemometrics and basic knowledge of computers in all courses on analytical chemistry.
Tendenzen in der analytisch-chemischen Ausbildung
Zusammenfassung Bei einer Tagung der WPAC über die Lehre auf dem Gebiet der analytischen Chemie wurde bei der Betrachtung neuer Aspekte festgestellt, daß vor allem Chemometrie und Grundkenntnisse in Computertechnik in die Ausbildung aufgenommen werden sollten.相似文献
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Ke Min Wojciech Jakubowski Krzysztof Matyjaszewski 《Macromolecular rapid communications》2006,27(8):594-598
Summary: The recently developed initiation system, activators generated by electron transfer (AGET), is used in atom transfer radical polymerization (ATRP) in the presence of a limited amount of air. Ascorbic acid and tin(II ) 2‐ethylhexanoate are used as reducing agents in miniemulsion and bulk, respectively. An excess of reducing agent consumes the oxygen present in the system and, therefore, provides a deoxygenated environment for ATRP. ATRP of butyl acrylate is successfully carried out in miniemulsion and in the presence of air. During polymerization the radical concentration remains constant. The polymerization reaches over 60% monomer conversion after 6 h, which results in polymers with a predetermined molecular weight = 14 000 g · mol−1 and a low polydispersity ( = 1.23). AGET ATRP of styrene is also successful in bulk in the presence of air, as evidenced by linear semi‐logarithmic kinetics, which leads to polystyrene with an of 13 400 g · mol−1 and a low polydispersity index ( = 1.14).