非晶态超导合金Zr_(87.7)Si_(12.3)中结构弛豫和结晶化对超导性质的影响

对非易态超导合金 Zr_(87.7)Si_(12.3),在适当的温度下进行了lh等时退火处理.测量了其结构、超导临界参量TC,HC)2及其转变宽度ΔTc,ΔHc_2等的变化.发现 些与金属-金属型非晶态合金不同的变化规律,并结合在结构弛豫过程中所发生的拓扑短程有序化和化学短程有序化,以及相应的结晶化机制,对实验结果作了讨论.     

非晶态合金La72Si28晶化过程中生成的新亚稳超导相

本文报道了在非晶态合金La₇₂Si₂₈晶化过程中生成新亚稳超导相的实验结果。非晶态合金La₇₂Si₂₈是用液态急冷法制备的,该合金经250℃,30min热处理后,得到了一个新的亚稳超导相,该相具有正交结构,其晶格参数为a=9.121?,b=6.821?,c=3.833?,超导临界温度T_c为3.02K,高于目前已知的La-Si系超导相的T_c值。 关键词：     

块体金属玻璃Zr46.75Ti8.25Cu7.5Ni10Be27.5的超导与负电阻温度系数

测量了块体金属玻璃Zr_46.75Ti_8.25Cu_7.5Ni₁₀Be_27.5在退火前后其电阻值随温度的变化,测量的温度范围为1.5—300K.样品在退火前后都发现有超导现象.零磁场下其超导转变温度T_c分别为1.84和3.76K.在5—300K温度范围内,原始样品具有负的电阻温度系数.如果取Zr, Ti, Cu, Ni及Be分别贡献出1.5, 1.5, 0.5, 0.5及两个传导 关键词： 块体金属玻璃 超导 电阻温度系数     

La4Au亚稳超导相的高压合成

本文报道了利用非晶合金的高压变态,合成新亚稳超导相La₄Au的结果,非晶La₈₀Au₂₀交结构,晶格参数为α=6.54?,b=7.71?,C=11.32?,超导临界温度T_c达5.5K,高于所有已知La-Au相的值。 关键词：     

PbBi3低温合金薄膜的制备和超导性质

铋(Bi)和铅(Pb)都是重元素,有很强的自旋-轨道耦合作用,由于原子半径接近,可形成丰富的原子取代合金结构.尽管对高温合金相有了较深入的研究,但对其低温物相的结构和超导物性的认识还很不全面.本文采用低温共沉积和低温退火的方法,在Si(111)-(7×7)衬底上制备了一种基于Bi(110)单晶结构中部分Bi原子被Pb取代的铅铋合金低温相超薄膜新结构,利用扫描隧道显微术(STM)对其结构和电子学性质进行了表征.通过结构表征,确定了合金薄膜表面呈现2^1/2×2^1/2R45°重构的PbBi₃合金相,其母体Bi(110)结构中25%的Bi原子被Pb取代了.通过STM谱学测量,发现合金相PbBi₃为超导相.变温实验表明, PbBi₃相的超导转变温度为6.13 K.在外加垂直磁场下出现的磁通涡旋结构表明PbBi₃薄膜是第Ⅱ类超导体,估算出上临界磁场的下限为0.92 T.测量了由Bi(110)-PbBi₃组成的共面型和台阶型正常金属-超导体异质结中...     

YBa2Cu3O7-δ/LaAlO3和Tl2Ba2CaCu2O8/LaAlO3高温超导薄膜内的应变对其微波表面电阻影响的研究

YBa₂Cu₃O_7-δ/LaAlO₃ (YBCO/LAO) 超导薄膜是通过热蒸发沉积方法制备的,实验中使用的Tl₂Ba₂CaCu₂O₈/LaAlO₃ (TBCCO/LAO) 超导薄膜是通过直流磁控溅射方法制备的.通过分析两片超导薄膜的XRD谱计算出了两片超导薄膜内的应变,ΔC_{关键词： YBCO/LAO TBCCO/LAO 超导薄膜 应变 表面电阻}     

准分子激光扫描消融淀积大尺寸超导薄膜

利用我们设计的一套光学变换传输系统实现了激光束在超导靶上一定范围内扫描消融来淀积高T_c超导薄膜。实验表明用这种激光扫描消融方法可使大尺寸超导薄膜的厚度均匀性得到较大的改善。我们采用激光扫描半径为9mm在12mm×33mm的Y-ZrO₂基片上淀积出零电阻温度T_c≥90K,临界电流密度J_c(零磁场,77K)≥1×10⁶A/cm²,薄膜c轴择优取向,厚度均匀性较好的YBa _关键词：     

(Bi,Pb)2Sr2Ca2Cu3Oy单相样品的超导电性与载流子浓度

对(Bi,Pb)₂Sr₂Ca₂Cu₃O_y单相样品进行不同条件下的热处理,通过X射线衍射、电阻-温度关系、交流磁化率,以及Hall系数等测量,发现样品均具有较好的单相性,随着热处理条件的变化,其超导转变中点温度(T_c)有规律地分布在100—110K之间,T_c随载流子浓度(n_H)的增加而升高。实验结果表明,热处理条件对样品的相结构、超导 关键词：     

Y1-xCaxBa2Cu3-xMxO7-δ (M=Fe,Ni)体系的超导电性

本文报道,通过对Y_1-xCa_xBa₂Cu_3-xMxO_7-δ(M=Fe,Ni)体系样品的晶体结构、氧含量、正常态电阻率与温度的关系,以及超导转变温度等测量,并与YBa₂Cu_3-xMxO_7-δ(M=Fe,Ni)体系进行比较,发现Y_1-xCa_xBa₂Cu_3-xFe_xO_7-δ体系的T_c显著地高于相应x值的YBa₂Cu_3-xFe_xO_7-δ体系,而Y_1-xCa_xBa₂Cu_3-xNi_xO_7-δ体系则相反,T_c低于仅Ni替代的体系,表明Ca和Fe同时替代时两者引起的载流子浓度(n_H)变化相互补偿,抑制了仅Fe替代时引起的n_H和T_c急剧下降;而作Ca和Ni同时替代时主要的不是两者引起载流子浓度变化的相互补偿,Ca和Ni替代效应之间的关联较弱。作者认为,对Y_1-xCa_xBa₂Cu_3-xFe_xO_7-δ体系属于CuO₂平面外的元素替代,这时载流子浓度是决定Tc的主要因素;而对Y_1-xCa_xBa₂Cu_3-xNi_xO_7-δ体系,由于Ni²⁺离子主要占据Cu(Ⅱ)位,它导致磁拆对效应,Ni²⁺离子的拆对效应是引起T_c下降的直接原因。 关键词：     

Lifshitz时空s波超导模型的关联长度和穿透深度

在D=d+2维各向异性的Lifshitz黑洞时空背景中, 在探子极限下, 用解析方法研究了临界温度附近引力系统的微扰, 计算出超导的关联长度ξα(1/T_c)(1-(T/T_c)^-1/2, 这与平均场论的结果一致. 进一步, 考虑在该系统中加一个均匀外磁场, 计算出穿透深度λα(T_c-T)^-1/2, 该结果与Ginzburg-Landau理论相符.     

用原位x射线小角散射研究块体非晶合金Zr55Cu30Al10 Ni5的结构弛豫

应用同步辐射x射线小角散射法在原位对块体非晶合金Zr₅₅Cu₃₀Al ₁₀Ni₅在等温退火过程中的微结构变化进行研究.实验表明：在等温退火过程中电子 密度涨落反映了晶化之前的结构弛豫过程；在一定的退火温度下、随退火时间的增加，拓扑短程序弛豫与化学短程序弛豫之间存在一个电子密度均匀化的过程；导致这两种弛豫过程转变的退火时间与退火温度有关，温度越高，所需的退火时间越短. 关键词： 原位x射线小角散射 块体非晶合金 等温退火 结构弛豫     

Annealing effect on soft magnetic properties and magnetoimpedance of Finemet Fe73.5Si13.5B9Nb3Au1 alloy

Effect of annealing on the soft magnetic properties of Fe_73.5Si_13.5B₉Nb₃Au₁ amorphous ribbon has been investigated by means of structure examination, magnetoimpedance ratio (MIR) and incremental permeability ratio (PR) spectra measured in the frequency range of 1–10 MHz at a fixed current of 10 mA X-ray diffraction analysis showed that the as-cast sample was amorphous and it became nanocrystalline under a proper heat treatment. When annealing amorphous alloy at 530 °C for 30, 60, 90 min, soft magnetic properties have been improved drastically. Among the samples investigated, the sample annealed at 530 °C for 90 min showed the softest magnetic behavior. The MIR and PR curves revealed the desirable changes in anisotropy field depending upon annealing.     

Microstructure and magnetic properties of bulk amorphous and nanocrystalline Fe61Co10Zr2.5Hf2.5Nb2W2B20 alloy

The microstructure and magnetic properties, i.e. the initial magnetic susceptibility, its disaccommodation, core losses and approach to ferromagnetic saturation of the bulk amorphous and partially crystallized Fe₆₁Co₁₀Zr_2.5Hf_2.5Nb₂W₂B₂₀ alloy are studied. From X-ray, Mössbauer spectroscopy and electron microscopy studies we have stated that all samples in the as-quenched state are fully amorphous. However, after annealing the samples at 850 K for 30 min the crystalline α-FeCo grains embedded in the amorphous matrix are found. Moreover, from Mössbauer spectra analysis we have stated that the crystalline phase in those samples exhibits the long-range order. The alloy in the as-quenched state shows good thermal stability of the initial magnetic susceptibility. Furthermore, the intensity of the magnetic susceptibility disaccommodation in the rod is lower than in the ribbon. It is due to low quenching rate during the rod preparation which involves the reduction of free volumes. From the analysis of the isochronal disaccommodation curves, assuming the Gaussian distribution of relaxation times, we have found that activation energies of the elementary processes responsible for this phenomenon range from 1.2 to 1.4 eV. After the annealing of the samples the initial susceptibility slightly enhances and disaccommodation drastically decreases. From high-field magnetization studies we have learned that the size of structural defects depends on the quenching rate (the shape of the samples) and changes after annealing.     

块体非晶合金Zr55Cu30Al10Ni5 结构弛豫的研究

应用同步辐射小角x射线散射和差示扫描量热分析对块体非晶合金Zr55₅₅Cu 30₃₀Al10₁₀Ni5₅结构弛豫进行了研究.实验结果表 明：经340℃、不同时间退火后的非晶内 部的电子密度涨落随退火时间的延长先增大而后减小；玻璃转变温度附近焓弛豫峰的表观激 活能则随退火时间的延长先减小而后增大.结果反映了随退火时间的延长，块体非晶合金内 部类液体区不断减少及类固体区不断增加的过程. 关键词： 小角x射线散射 块体非晶合金 结构弛豫     

非晶态Cu56Zr44合金的结构及其等温退火晶化过程的研究

利用X射线衍射技术、差示扫描量热分析技术和透射电子显微镜研究了非晶态Cu₅₆Zr₄₄合金的结构及其等温退火条件下的晶化过程.实验结果表明,非晶态Cu₅₆Zr₄₄合金在室温下的短程结构类似于硬球无规密堆积分布.在703K过冷液相区内等温退火时发现,当退火时间为3min时,晶化产物主要为Cu₈Zr₃相;当退火时间为6min时,Cu₈Zr₃关键词： 非晶态 56Zr₄₄合金')" href="#">Cu₅₆Zr₄₄合金 结构 等温退火     

Kinetics of induced magnetic directional order in a Fe40Ni40P14B6 amorphous alloy

The amorphous Fe₄₀Ni₄₀P₁₄B₆ alloy (Metglas 2826) has been annealed under magnetic field at several temperatures. The kinetics of induced magnetic anisotropy exhibits a broad spectrum (β = 4) of time constants; it obeys exactly an Arrhenius law with an activation energy of 1.74 ± 0.04 eV. These values are identical to those determined by resistivity measurements. This suggests the formation of short range directional order.     

On the structure of amorphous sputtered Zr76Cu24 alloy

X-ray diffraction experiments have been performed on amorphous sputtered Zr₇₆Cu₂₄ alloy in order to investigate the structural relaxation induced by thermal annealing below the crystallization temperature. Contrary to the low-temperature thermal properties which are very sensitive to heat treatments, only weak modifications affect the short-range structural order as defined by the total radial distribution function.     

Magnetic after-effects of hydrogen in amorphous Co75Si15B10 alloys

The magnetic after-effect spectrum of hydrogen-charged amorphous Co₇₅Si₁₅B₁₀ and its annealing behaviour was measured in the temperature range between 2.1 and 450 K. A hydrogen related relaxation peak was observed at 190 K with a mean activation energy of 0.42 eV.     

穆斯堡尔谱学研究非晶TM80M20合金的微观结构

在室温下和4.2K下测定了非晶Fe₈₀B_20-xM_x合金(M=P,C)的穆斯堡尔吸收谱。利用分布参数拟合程序得到了超精细内场H_i和同质异能移IS同类金属成份的变化关系。利用这些结果考察了非晶合金的微观结构,比较了两类结构模型:Bernal-Polk模型和微晶模型。对比非晶合金和它们的相应晶相的行为得知,这类非晶合金中不存在微晶近程序,Bernal-Polk模型对描述TM-M类非晶合金的微观结构优于微晶模型。 关键词：     

Effect of annealing on TiO2 nanoparticles

TiO₂ nanoparticles have been prepared by simple chemical precipitation method and annealed at different temperatures. The as-prepared TiO₂ are amorphous, and they transform into anatase phase on annealing at 450 °C, and rutile phase on annealing at 900 °C. The X-ray diffraction results showed that TiO₂ nanoparticles with grain size in the range of 21–24 nm for anatase phase and 69–74 nm for rutile phase have been obtained. FESEM images show the formation of TiO₂ nanoparticles with small size in structure. The FTIR and Raman spectra exhibited peaks corresponding to the anatase and rutile structure phases of TiO₂. Optical absorption studies reveal that the absorption edge shifts towards longer wavelength (red shift) with increase of annealing temperature.