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1.
In this paper, the preparation process of the tetragonal LaBaCaCu3O7-x (LBCCO) superconductor with Tc=84 K is repored. The superconductivity and structure of the LBCCO superconducting phase are investigated by means of X-ray diffraction (XRD), transmission electron microscope(TEM) and superconductivity measurements, The results indicate that the superconducting phase with Tc=82K in the LBCCO system has a tetragonal structure with a=0.3966nm, c=l.1838nm and space group P4/mmm. About 50% of the Ca and La atoms are located in 1d sites (i.e. Y site in the YBCO structure). It is confirmed that there is in fact no orthorhombic to tetragonal transition in this material. The relationship between the oxygen content and Tc is also presented.  相似文献   

2.
The important feature of the alkali-metal-doped C60 is that the intramolecular high, frequency vibration modes arising from the covalent interaction and the intermolecular lowfrequency vibration modes arising from the weak Van der Wads interaction both play important roles in the properties of superconductivity. We propose a two-peak form for the phonon density of states. By solving the Eliashberg equations we get the formula for the reduced gap 2Δ0/kBTc and the transition temperature Tc whidh are all in accordance with the experimental values.  相似文献   

3.
The determination of Tc in dilute alloys is examined. As an example, magnetization vs field data in a Pd0.95Gd0.05 alloy are presented. For this alloy, it was not possible to determine a value of Tc using Arrott-Belov-Kouvel (ABK) plots; the conditions for the applicability of ABK plots were not satisfied. Results of very-low-field ac and dc magnetization vs T, which depend mainly on the demagnetization factor, yield a more precise measure of Tc. We conclude that the latter procedures are more useful than ABK plots for determination of Tc in dilute alloys.  相似文献   

4.
In this letter, we present an analysis to understand why the McMillan-like Tc fornula: Tc=1.134ωlog(1-1.02μ*+0.476λ)exp{-1+1.604λ/λ-μ*(1+0.604μ)}, proposed in a previous paper by the authcrs,applies to crystalline superconductors satisfactorily but Iess satisfactorily to non-crystalline ones.  相似文献   

5.
通过对FeSe进行化学插层可以将其超导转变温度(Tc)从约8 K提高到40 K以上,实现高温超导电性.最近,我们对两种插层FeSe高温超导材料(Li0.84Fe0.16)OHFe0.98Se和Li0.36(NH3yFe2Se2开展了高压调控研究,发现压力会首先抑制高温超导相(称为SC-I相),然后在临界压力Pc以上诱导出第二个高温超导相(称为SC-Ⅱ相),呈现出双拱形T-P超导相图.这两个体系的Pc分别约为5和2 GPa,两个体系SC-Ⅱ相的最高Tc分别可以达到约52和55 K,比相应SC-I相的初始Tc提高了10 K.对(Li0.84Fe0.16)OHFe0.98Se的正常态电输运性质分析表明,SC-I和SC-Ⅱ相的正常态分别具有费米液体和非费米液体行为,意味着这两个超导相可能存在显著差异.此外,还发现这两个体系的SC-Ⅱ相的Tc与霍尔系数倒数1/RH(∝载流子浓度ne)具有很好的线性依赖关系.对(Li0.84Fe0.16)OHFe0.98Se的高压X射线衍射测量排除了其在10 GPa以内发生结构相变的可能,因此Pc以上SC-Ⅱ相的出现和载流子浓度的增加很可能起源于压力导致的费米面重构.  相似文献   

6.
熊光成  尹道乐 《物理学报》1982,31(9):1176-1182
本文研究了C-15结构化合物(Zr0.5Hf0.5-xTax)V2(x≤0.2)和(Hf0.5Zr0.5-xNbx)V2(x≤0.2)的超导转变温度Tc及其压力效应?Tc/?P。报道了实验方法与结果。与(Hf1-xTax)V2和(Zr1-xTax)V2的情况不同,在(Zr0.5Hf0.5-xTax)V2中Ta的引入使常压下的Tc下降,然而(?)Tc/(?)P却大为提高。因此高压下Zr0.5Hf0.45Ta0.05V2的Tc反而比Hf0.5Zr0.5V2更高。导出了一个基于角动量分波表象能带论方法的描述压力效应的新关系式。它指出导带电子波函数中的高角动量成分变化对Tc的压力效应影响比较重要。这个公式有助于理解上述复杂的实验现象,并能合理地解释某些元素(如Cs,Ba,La等)的Tc随压力剧增的事实。 关键词:  相似文献   

7.
The gap equation at finite temperature in the top-quark condensate scheme of electroweak symmetry breaking is proven to have the identical form in both the imaginary and real time formalisms of thermal field theory. By means of the gap equation, combined with the basic relation to define the vacuum expectation value v of the effective Higgs field, we analyze the dependence on temperature T and chemical potential p of the dynamical top-quark mass as the order parameter characteristic of symmetry breaking, and obtain the p-T criticality curve for symmetry restoration. We find out that the critical temperature Tc = 2υ for μ = 0 and the critical chemical potential μc = 2 π υ / √3 for T = 0. When μ = 0, the top-quark mass near Tc has the leading (Tc2 - T2)1/2 behavior with an extra factor dependent on temperature T and the momentum cutoff Λ. However, it is generally argued that the symmetry restoration at T ≥ Tc is still a second-order phase transition.  相似文献   

8.
This paper presents systematically the doping effects of halogens in YBa2Cu3O7-δ polycrystalline samples, with a series of concentrations of fluorine, chlorine, bromine or iodine. All samples were prepared by chemical method of citrate pyrolysis, which makes the halogen concentration in the samples more uniform. Samples doped with F have Tc as high as 94.5K, Cl, Br and I dopings also raise Tc to a certain extent. In addition, the influence of halogen doping on critical current density, morphology, constitution and so forth is discussed.  相似文献   

9.
For both BiSrCaCuO and TlBaCaCuO samples, internal frictions (Q-1) in the kHz range reveal a plateau (Q-1p) above Tc and a rapid drop below Tc with the turning points located just at Tc for various samples with different Tc. This anomaly cannot be observed in non-superconducting samples. The ultrasonic attenuation (α) in TlBaCaCuO displays similar results to the internal friction. Moreover, it is discovered that the Q-1p is nearly proportional to the carrier density for Y(Pr)BaCuO and Gd(Pr)BaCuO with different Pr contents. These results show that the drop of Q-1 and a below Tc is closely related to superconducting condensation. The Q-1p and αp can be explained using coupling-model of carriers with local dynamic distortion because high Tc superconductors are strong-correlation systems. Furthermore, by taking account of the smearing of superconducting gap structure resulting from the recombination of quasi-particles and by modifying the BCS relative jump rate as S(E, E', Γ) = Re{1-Δ2/[(E-iΓ)(E'-iΓ)]}, the calculated results of internal friction and ultrasonic attenuation below Tc are in good agreement with the experimental data. The superconducting gap Δ and the damping rate Γ for both BiSrCaCuO and TlBaCaCuO have also been obtained, they are in accordance with those got by tunneling spectrum and NMR methods, etc.  相似文献   

10.
This paper gives methods to calculate the pairing temperature T*,at which a pseudogap is opened,and the superconducting temperature Tc,at which superconductivity appears,in the high-Tc cuprates,and demonstrates directly that at Tc < T < T* the pseudogap is the gap of Cooper pair without long-range phase coherence,and at T < Tc there is long-range phase coherence between Cooper pairs.Based on the above clear physical picture on the pseudogap state and our mechanism for the ac Josephson effect,this paper proposes that there should be a novel oscillatory current in P-I-P junction,induced by a constant bias on the junction.Here,P represents the high-Tc curates in the pseudogap state,where Cooper pairs do not have long-range phase coherence,and I represents the thin insulating barrier.This paper conjectures that there is a possible high-temperature superconductivity in the heavily underdoped high-Tc cuprates.  相似文献   

11.
Explicit expressions and results for Tc(n) of the layer compounds of Bi and T1 are obtained within the generalized soliton pairing framework, in which Tc, is raised by the cooperation l i of the two couplings, intralayer and interlayer. The calculated values are in good agreement I with the observed Tc's. The maximum possible Tc(∞) is predicted at≈ 200 K.  相似文献   

12.
刘宜华  马小丁  梅良模 《物理学报》1990,39(12):2005-2010
成功地制成了FeSi/Si非晶态成分调制膜,固定Si层厚度,系统改变FeSi层厚度dm发现,随dm下降,饱和磁化强度Ms单调减小,这主要是死层效应的贡献,OK下死层厚度约为5.8?,随dm减小,调制膜逐渐由三维磁性转变为二维磁性,表现为出现低磁滞和无磁滞效应,线性的Ms(T)-T关系和Curie温度Tc的单调下降,Tc满足如下关系:△Tc关键词:  相似文献   

13.
In this paper the influence of γ-radiation on the dielectric constants of Rb2ZnCl4 crystal at incommensurate-commensurate phase transition (hereafter abbreviated as INC-C transition) are studied. The thermal hysteresis occurs upon both cooling and heating runs, irrespective of whether the samples have been treated with γ-radiation or not. For the γ-irradiated sample, its transition point, Tc, between the INC and C phases is not changed, but the peak value of the dielectric constant at Tc increases abruptly, compared with that before γ-irradiation, When this sample is annealed at 40℃, the peak value restores to the incipient value for the sample free from γ-irradiation. The origin of the phenomenon of the thermal hysteresis of the dielectric constant may be due to the pinning effect of dejects or impurities in the samples.  相似文献   

14.
a—Fe—(Co,Cr)—Zr系列合金的穆斯堡尔谱研究   总被引:2,自引:0,他引:2       下载免费PDF全文
黄志高 《物理学报》1989,38(10):1698-1703
本文研究了a-Fe90-xCoxZr10(x=4,10,20,…,70)和Fe90-yCryZr10(y=0,4,7,16,20)系列合金的M?ssbaner谱。实验结果表明a-Fe90-yCoyZr10和富Fe区(x<30)的a-Fe90-xCoxZr10 关键词:  相似文献   

15.
It is shown that in a strongly correlated system there exists multiple exchange-mediated interaction (MEIW). From the numerical calculations of Tc, (Tc vs. x and y for La2-xSrxCuO4 and Y1Ba2Cu3O7-y), the small isotope effect, the large gap and some explanations for the observed phenomena, this paper affirms that the high-T, superconductivity is caused by the MEIW, the phonon-mediated interaction and the tunneling coupling. The heavy-fermion superconductivity is mainly caused by the MEMI, and, in the meantime, the phonon-mediated interaction h h also some contributions. The extremely large gap below TN in AF Chevrel phase, some AF materials come from the MEMI. The organic superconductivity might be caused mainly by the MEMI.  相似文献   

16.
We describe the molecular ferromagnet decamethylchromocenium tetracyanoethanide [CrCp2*] [TCNE] by a quasi-one-dimensional alternating-spin model with ferromagnetic exchange interaction. The spin-wave theory is used to discuss the magnetic excitation of the molecular ferromagnet. We obtain the magnetizations corresponding to different external magnetic fields without interchain exchange interaction which is consistent with the experimental results. The formula of the Curie temperature Tc is obtained by using the thermodynamic Green's function method. It is found to be related to the spin of donors, to the intrachain exchange interaction and to the spatial anisotropic parameter. The result obtained by this Tc formula is consistent with the experimental result Tc = 3.6 K for [CrCp2*][TCNE].  相似文献   

17.
杨卓群  吴亚波  鲁军旺  张成园  张雪 《物理学报》2016,65(4):40401-040401
在D=d+2维各向异性的Lifshitz黑洞时空背景中, 在探子极限下, 用解析方法研究了临界温度附近引力系统的微扰, 计算出超导的关联长度ξα(1/Tc)(1-(T/Tc)-1/2, 这与平均场论的结果一致. 进一步, 考虑在该系统中加一个均匀外磁场, 计算出穿透深度λα(Tc-T)-1/2, 该结果与Ginzburg-Landau理论相符.  相似文献   

18.
Measurements of upper critical field as a function of temperature and Fe-concentration are reported for the amorphous superconductors ((Mo.6Ru.4).80G.20)1−cFec, where G is a glass-former. The linear shapes of the Hc2 vs. T curves near Tc agree well with predictions made by Matsura, Ichinose, and Nagaoka, for TKondo > Tc.  相似文献   

19.
Based on a simple semi-empirical energy density, the free energy density for a hot nucleon system is derived, from which the equations of state P(T, p) and chemical potentials μq(T, p) for both finite nucleus and infinite nuclear matter are acquired. The liquid-gas phase transition and the instability of hot nuclei are analysed with these ingredients within the framework of thermodynamic's. Both critical temperature Tc for infinite nuclear matter and limiting temperature Tlim, for finite nuclei are predicted and compared with previous calculations.  相似文献   

20.
Using the free carrier-negative U center interacting model, we have investigated the superconducting transitionr,temperature Tc, the specific heat jump at Tc, the coherence length, the penetration depth, the thermodynamic critical field and the isotope effect for the high-Tc oxide superconductor. The theoretical values of these physical quantities are consistent with the experimental values. Further, the residual electronic specific heat in the superconducting state is explained as the result of the inherent instability in this superconductive mechanism.  相似文献   

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