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排序方式: 共有260条查询结果,搜索用时 31 毫秒
1.
O. Guselnikova J.P. Fraser N. Soldatova E. Sviridova A. Ivanov R. Rodriguez A.Y. Ganin P. Postnikov 《Materials Today Chemistry》2022
Covalent functionalization of 2D materials provides a tailored approach towards tuning of their chemical, optical, and electronic properties making the search for new ways to graft small molecules important. Herein, the reaction with (3,5-bis(trifluoromethyl)phenyl)iodonium salt is revealed as an effective strategy for functionalization of MoTe2 thin films. Upon decomposition of the salt, the generated radicals graft covalently as aryl-(CF3)2 groups at the surface of both metallic (1T’) and semiconducting (2H) polymorphs of MoTe2. Remarkably, the reactivity of the salt is governed by the electronic structure of the given polymorph. While the functionalization of the metallic MoTe2 occurs spontaneously, the semiconducting MoTe2 requires activation by light. The reaction proceeds with the elimination of oxide from the original films yielding the functionalized products that remain protected in ambient conditions, presenting a viable solution to the ageing of MoTe2 in air. 相似文献
2.
Dr. Jin Su Dr. Tohru Tsuruoka Dr. Takuji Tsujita Dr. Yuu Inatomi Dr. Kazuya Terabe 《Angewandte Chemie (International ed. in English)》2023,62(9):e202217203
Solid-state batteries (SSBs) that use solid electrolytes instead of flammable liquid electrolytes have the potential to generate higher specific capacity and offer better safety. Magnesium (Mg) based SSBs with Mg metal anodes are considered to be one of the most promising energy storage candidates, because it gives high theoretical volumetric capacities of 3830 mAh cm−3. Here, we demonstrate an atomic layer deposition (ALD) process with a double nitrogen plasma process that successfully produces nitrogen-incorporated magnesium phosphorus oxynitride (MgPON) solid-state electrolyte (SSE) thin films at a low deposition temperature of 125 °C. The ALD MgPON SSEs exhibit an ionic conductivity of 0.36 and 1.2 μS cm−1 at 450 and 500 °C, respectively. The proposed ALD strategy shows the ability of conformal deposition nitrogen-doped SSEs on pattered substrates and is attractive for using nitride ion-conducing films as protective or wetting interlayers in solid-state Mg and Li batteries. 相似文献
3.
Taking advantage of large conjugated structure and reductivity of boron-doped graphenethe palladium nanoparticles/boron-doped graphene catalyst was prepared by electroless deposition method using boron-doped graphene as reductant and stabilizer. The average size of palladium nanoparticles highly dispersed on the surface of boron-doped graphene was about 6.5 nm. The electrochemical sensor was prepared by modifying the as-formed catalyst on the surface of glassy carbon electrode. The obtained electrochemical sensor exhibited an excellent electrochemical catalytic activity for H2 O2 . It exhibited high sensitivity with the detection limit as low as 830 nmol/L and good linearity in the range of 2.5-300 μµmol/L for detection of H2 O2 . It could be utilized for the determination of H2 O2 in milk samples. © 2022, Youke Publishing Co.,Ltd. All rights reserved. 相似文献
4.
The properties of vortical structures at high Reynolds number in uniform flows and near rigid boundaries are reviewed. New
properties are derived by analysing the dynamics of the main flow features and the related integral constraints, including
the relations between mean swirl and bulk speed, the relative level of internal fluctuations to bulk properties, and connections
between the steadiness and topology of the structures. A crucial property that determines energy dissipation and the transport
of inertial particles (with finite fall speed) is the variation across the structure of the ratio of the mean strain rate
(Σ) to the mean vorticity (Ω). It is shown how, once such particles are entrained into the vortical regions of a coherent
structure, they can be transported over significant distances even as the vortices grow and their internal structure is distorted
by internal turbulence, swirling motions and the presence of rigid boundaries. However if the vortex is strongly distorted
by a straining motion so that Σ is greater than Ω, the entrained particles are ejected quite rapidly. These mechanisms are
consistent with previous studies of entrained and sedimenting particles in disperse two phase flows over flat surfaces, and
over bluff obstacles and dunes. They are also tested in more detail here through laboratory observations and measurements
of 50–200-μm particles entrained into circular and non-circular vortices moving first into still air and then onto rigid surfaces placed
parallel and perpendicular to the direction of motion of the vortices. 相似文献
5.
Giinter Sorbe 《Journal of Dispersion Science and Technology》2013,34(3):287-302
Changes in composition of household washing detergents are reviewed, with emphasis on the importance of STPP As by law or voluntary agreement the STPP content in detergents has dropped during the last years in some countries, it will be shown that the quality of the used phosphates is of great influence on the quality of the final product In manufacturing detergents with low phosphate content it is important to use special STPP-types for every process The process technology of the manufacture of phosphate-containing powdered detergents can be divided into processes in which the individual components are worked up Into agglomeration products (spray mixing plants) and processes In which the individual components are combined to form a slurry of several substances (spray drying plants). 相似文献
6.
C.D. Dritselis I.E. Sarris D.K. Fidaros N.S. Vlachos 《International Journal of Heat and Fluid Flow》2011,32(2):365-377
The effect of Lorentz force on particle transport and deposition is studied by using direct numerical simulation of turbulent channel flow of electrically conducting fluids combined with discrete particle simulation of the trajectories of uncharged, spherical particles. The magnetohydrodynamic equations for fluid flows at low magnetic Reynolds numbers are adopted. The particle motion is determined by the drag, added mass, and pressure gradient forces. Results are obtained for flows with particle ensembles of various densities and diameters in the presence of streamwise, wall-normal or spanwise magnetic fields. It is found that the particle dispersion in the wall-normal and spanwise directions is decreased due to the changes of the underlying fluid turbulence by the Lorentz force, while it is increased in the streamwise direction. The particle accumulation in the near-wall region is diminished in the magnetohydrodynamic flows. In addition, the tendency of small inertia particles to concentrate preferentially in the low-speed streaks near the walls is strengthened with increasing Hartmann number. The particle transport by turbophoretic drift and turbulent diffusion is damped by the magnetic field and, consequently, particle deposition is reduced. 相似文献
7.
8.
Synthesis of titanium nitride thin films deposited by a new shielded arc ion plating 总被引:2,自引:0,他引:2
Yanhui Zhao Guoqiang LinJinquan Xiao Wenchang LangChuang Dong Jun GongChao Sun 《Applied Surface Science》2011,257(13):5694-5697
Thin films of titanium nitride (TiN) were deposited on stainless steel substrates by a modified deposition technique, double-layered shielded arc ion plating with vicarious circular holes (DL-SAIP). The results show that the TiN film with the distance of 10 mm between the double-layered shield plates had the least droplets. The deposition rate of the films prepared with the new technique was more homogeneous than that of all the other shielded arc ion plating. The film/substrate adhesion and microhardness values of the TiN films were higher than 40 N and 18 GPa, respectively. Thus such TiN thin films can be expected in applications. 相似文献
9.
10.
ALD氧化铝单层膜1 064 nm激光损伤特性研究 总被引:2,自引:2,他引:0
采用原子层沉积技术(atomic layer deposition,ALD)在熔石英和BK7玻璃基底上镀制Al2O3单层膜。利用小口径损伤在线测试平台对膜层的1 064 nm激光损伤特性进行了实验测量,获得膜层损伤阈值约为10.3 J/cm2,对比了其与BK7基底损伤阈值之间的差异;利用Nomarski显微镜和原子力显微镜分析讨论了损伤形态的特点,结果表明损伤主要表现为膜层脱落和基片小孔烧蚀,其中小孔深度集中在70 nm~95 nm范围;讨论了损伤发生的诱因,得出膜基界面可能存在吸收源先驱的推断。 相似文献